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PLZT

PLZT is a lanthanum-doped lead zirconate titanate (Pb,La)(Zr,Ti)O₃ ceramic densified to optical transparency and used for its strong electro-optic effect as well as for piezoelectric actuation.

High cost $$$$

Reference datasheet — PLZT is not in the instant-quote catalog. Upload your part and an engineer will quote it in this grade or suggest the closest stocked equivalent.

Values for the 9/65/35 condition

PLZT tempers and conditions

PLZT is supplied in 4 conditions, soft to hard. 9/65/35 is the default FabDigit quotes; the values on this page are for it.

Compare all 4 conditionsHide
Condition · open for datasheetBest forYield MPaTensile MPaElong. %HardnessConductivity
9/65/35Default
PLZT 9/65/35
Choose the hot-pressed relaxor composition for optical shutters, modulators and goggles: relaxor at room temperature, no residual birefringence and a large Kerr effect, but limited to 80 °C.400.05380 HV1 W/m·K
PLZT 8/65/35
Choose when a latchable remanent polarization is needed at room temperature — optical and image storage, bistable light shutters — with the ferroelectric phase retained only to 110 °C.400.05385 HV1 W/m·K
PLZT 9/65/35 HIP
Specify the hot isostatically pressed version when maximum transmission, minimum scattering and larger optical window sizes are needed, at 7.92 g/cm³ density and the highest cost.450.05390 HV1 W/m·K
PLZT 2/95/5
Pick for field-induced antiferroelectric–ferroelectric switching: low permittivity, high withstand voltage and large volume strain for energy storage, explosive-electric transduction and high-strain actuation to 180 °C.450.05400 HV2 W/m·K

What is PLZT?

PLZT is a lanthanum-doped lead zirconate titanate (Pb,La)(Zr,Ti)O₃ ceramic densified to optical transparency and used for its strong electro-optic effect as well as for piezoelectric actuation. Compositions on file are 9/65/35, 9/65/35-HIP, 8/65/35 and 2/95/5, normally supplied as polished plates, windows and wafers with transparent ITO or Cr/Au electrodes. Maximum service temperature is 80 °C, and the material is lead-bearing, brittle and dependent on optical polishing plus AR coating, so cost and lead time are high. Where transparency is not required, conventional PZT is the cheaper actuator choice. PLZT has a density of 7.85 g/cm³ (0.284 lb/in³), heavier than 76% of ceramic grades. It melts at 1,300°C (2,372 °F). PLZT has a tensile strength of 40 MPa (5.8 ksi), weaker than 70% of ceramic grades. Elongation at break is 0.05% and the elastic modulus is 68 GPa (9.86 Msi).

What is PLZT used for?

  • optical shutters
  • electro-optic modulators
  • flash-blindness goggles
  • actuators

Advantages

  • Polishes to a fine finish — 90/100, better than 78% of ceramic grades

Limitations

  • Limited service temperature — 80°C (176 °F), worse than 100% of ceramic grades
  • Poor heat conductor — 1.3 W/m·K (0.751 BTU/hr·ft·°F), worse than 94% of ceramic grades
  • Low fracture toughness — 1 MPa·√m (0.91 ksi·√in), worse than 84% of ceramic grades
  • Low stiffness — 68 GPa (9.86 Msi), worse than 80% of ceramic grades
  • Heavy — 7.85 g/cm³ (0.284 lb/in³), worse than 76% of ceramic grades

PLZT properties

Typical room-temperature values for PLZT-9/65/35; bars are the position among ceramic grades.

Physical5

PLZT has a density of 7.85 g/cm³ (0.284 lb/in³), heavier than 76% of ceramic grades. It melts at 1,300°C (2,372 °F).

Density7.85 g/cm³0.28 lb/in³
Melting Point (Solidus)1,300°C2,372 °F
Refractive Index2.5
Light Transmission65%
Porosity0.05%

Mechanical13

PLZT has a tensile strength of 40 MPa (5.8 ksi), weaker than 70% of ceramic grades. Elongation at break is 0.05% and the elastic modulus is 68 GPa (9.86 Msi).

Elastic (Young's) Modulus68 GPa9.9 Msi
Shear Modulus27 GPa3.9 Msi
Bulk Modulus47 GPa6.8 Msi
Poisson's Ratio0.26
Tensile Strength (Ultimate)40 MPa5.8 ksi
Elongation at Break0.05%
Compressive Strength600 MPa87 ksi
Flexural Strength80 MPa11.6 ksi
Shear Strength55 MPa8 ksi
Fracture Toughness (K_IC)1 MPa·√m0.91 ksi·√in
Hardness, Vickers380 HV
Hardness, Knoop360 HK
Hardness, Mohs5.5

Thermal5

PLZT is rated for continuous service to 80°C (176 °F). It conducts heat at 1.3 W/m·K (0.751 BTU/hr·ft·°F), worse than 94% of ceramic grades. Thermal expansion is 5 µm/m·K (2.78 µin/in·°F).

Thermal Conductivity1.3 W/m·K0.75 BTU/hr·ft·°F
Specific Heat Capacity350 J/kg·K0.08 BTU/lb·°F
Thermal Expansion (CTE, 20–100 °C)5 µm/m·K2.8 µin/in·°F
Max Service Temperature (continuous)80°C176 °F
Min Service Temperature-50°C-58 °F

Electrical5

PLZT is an electrical insulator with a dielectric strength of 10 kV/mm (254 V/mil) and a resistivity of 1×10¹⁰ Ω·m.

Electrical Resistivity1×10¹⁰ Ω·m3.94×10¹⁷ µΩ·in
Dielectric Strength10 kV/mm254 V/mil
Dielectric Constant (1 MHz)3,000
Dissipation Factor (1 MHz)0.04
Volume Resistivity1×10¹² Ω·cm

Chemical & Environmental2

Corrosion resistance is good (60/100), worse than 71% of ceramic grades.

Corrosion ResistanceGood60/100
Chemical Resistance Summary—

Sustainability4

Producing a kilogram of PLZT takes about 100 MJ of energy and emits 9 kg of CO₂ — less than 55% of ceramic grades. Typical recycled content is 0%.

Embodied Energy (primary production)100 MJ/kg42,992 BTU/lb
Embodied Carbon (primary production)9 kg CO₂/kg
Embodied Water150 L/kg18 gal/lb
Typical Recycled Content0%

Manufacturability3

PLZT's machinability is not recommended (8/100, better than 69% of ceramic grades).

MachinabilityNot recommended8/100
PolishabilityExcellent90/100
Sintering / Firing Temperature1,250°C2,282 °F

Common Calculations4

Specific Strength (UTS / density)calculated5 kN·m/kg
Specific Stiffness (E / density)calculated8.7 MN·m/kg
Thermal Diffusivitycalculated0.5 mm²/s
Thermal Shock Resistance Indexcalculated0

Values are nominal handbook figures for design screening. Certified mill or lot data ships with every FabDigit order on request.

Strength versus weight in the ceramic family

Yield strength against density for every ceramic grade FabDigit runs. PLZT is highlighted; hover a dot for its name, or open the interactive family chart.

501002005001,000234567Density (g/cm³)Yield strength (MPa) — log scale

Working with PLZT

Is PLZT easy to machine?

Machine only with diamond wheels or wire saws followed by lapping and polishing; sintered PLZT cannot be turned or milled. Thin plates chip readily, so use low feed rates and water cooling.

Can PLZT be welded?

Not weldable. Assemble to metals or optics with epoxy adhesive, glass solder, or by brazing to a metallised layer (Cr/Ni/Au or electroless Ni).

Can PLZT be formed, bent or molded?

Formed from co-precipitated or mixed-oxide powder by cold isostatic pressing, then densified by hot pressing or hot isostatic pressing in a PbO atmosphere; lead volatilisation and stoichiometry must be closely controlled.

PLZT chemical composition (wt %)

Limits by weight percent from the governing specification, written the way the spec states them — a single maximum for impurities, a range for alloying elements, and the base element as balance. Nominal is the typical mid-range value.

ElementSpec limit (wt %)Nominal
PbA-site host; (Pb0.91La0.09) for 9/65/3555 – 6158.3
Ladopant level = first digit of grade (at% A-site substitution)1 – 53.9
ZrB-site; Zr/Ti = 65/3514 – 2517.9
TiB-site1 – 65.1
Ooxygen site of the perovskite ABO3 latticebalance

What surface finishes work on PLZT?

Lap and polish both faces to λ/4 flatness and apply AR coatings; electrodes are usually sputtered transparent ITO or evaporated Cr/Au, and poled parts are aged below the Curie temperature to stabilise properties.

How much does PLZT cost?

PLZT is a high-cost ceramic ($$$$), pricier than about 78% of the materials FabDigit quotes. Part price depends far more on geometry, tolerance and quantity than on the raw stock — upload a CAD file for a live quote.

PLZT — frequently asked

What is PLZT used for?

PLZT is typically used for optical shutters, electro-optic modulators, flash-blindness goggles and actuators. In short: transparent electro-optic PZT; optical-grade piezo ceramic; low 80 °C service limit.

What is the tensile strength of PLZT?

PLZT has a typical tensile strength of 40 MPa (5.8 ksi) — weaker than 70% of ceramic grades. Strength varies by condition: see the 4 listed tempers.

Is PLZT easy to machine?

Not especially — machinability is rated not recommended (8/100, better than 69% of ceramic grades). Machine only with diamond wheels or wire saws followed by lapping and polishing; sintered PLZT cannot be turned or milled. Thin plates chip readily, so use low feed rates and water cooling.

Can PLZT be welded?

Not weldable. Assemble to metals or optics with epoxy adhesive, glass solder, or by brazing to a metallised layer (Cr/Ni/Au or electroless Ni).

What surface finishes work on PLZT?

Lap and polish both faces to λ/4 flatness and apply AR coatings; electrodes are usually sputtered transparent ITO or evaporated Cr/Au, and poled parts are aged below the Curie temperature to stabilise properties.

Can PLZT be formed, bent or molded?

Formed from co-precipitated or mixed-oxide powder by cold isostatic pressing, then densified by hot pressing or hot isostatic pressing in a PbO atmosphere; lead volatilisation and stoichiometry must be closely controlled.

What is the maximum service temperature of PLZT?

PLZT is rated for continuous use to about 80°C (176 °F). Strength falls off well before that limit — check the elevated-temperature data for load-bearing parts.

How much does PLZT cost?

PLZT is a high-cost ceramic ($$$$), pricier than about 78% of the materials FabDigit quotes. Part price depends far more on geometry, tolerance and quantity than on the raw stock — upload a CAD file for a live quote.

Sources

  1. Engineered Materials Handbook Vol. 4: Ceramics and Glasses — Electro-optic ceramics — ASM International (1991)
  2. Haertling, 'Ferroelectric Ceramics: History and Technology', J. Am. Ceram. Soc. 82[4] — American Ceramic Society (1999)

Property data is compiled from published supplier and standards handbooks and normalised for comparison; hardness values on non-Brinell scales are converted approximately for charting only. Manufacturability limits are FabDigit quote-engine defaults and may be relaxed by engineering review. Nothing on this page is a certification — request mill certs, CoC or material test reports with your order.