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Refractory Metal Zr 704C-F (As fabricated)

Temper · default condition

ASTM B752 Grade 704C

Standard supply condition for corrosion-service valve bodies and pump casings; meets ASTM B752 Grade 704C minima without further heat treatment.

High cost $$$$

Values for the F condition

Other Zr 704C tempers and conditions

Zr 704C is listed in 3 conditions; see the grade overview at Zr 704C.

Compare all 3 conditionsHide
Condition · open for datasheetBest forYield MPaTensile MPaElong. %HardnessConductivity
Stress relieved
Choose when residual casting or weld-repair stresses must be removed to minimise stress-corrosion cracking risk in chloride-bearing service.27543516180 HB2.6 % IACS
FDefaultThis page
As fabricated
Standard supply condition for corrosion-service valve bodies and pump casings; meets ASTM B752 Grade 704C minima without further heat treatment.30045013190 HB—
Hot isostatic pressed
Specify for pressure-containing or fatigue-loaded castings where internal shrinkage porosity must be closed and property scatter reduced.31047017188 HB2.5 % IACS

What is Zr 704C-F?

Zr 704C-F is Zr 704C in the F temper — standard supply condition for corrosion-service valve bodies and pump casings; meets ASTM B752 Grade 704C minima without further heat treatment. Zr 704C-F has a yield strength of 300 MPa (43.5 ksi) and a tensile strength of 450 MPa (65.3 ksi) — weaker than 60% of refractory metal grades. Elongation at break is 13% and the elastic modulus is 99 GPa (14.4 Msi). Zr 704C-F has a density of 6.56 g/cm³ (0.237 lb/in³), lighter than 71% of refractory metal grades. It melts at 1,800°C (3,272 °F).

Limitations

  • Poor heat conductor — 13 W/m·K (7.51 BTU/hr·ft·°F), worse than 95% of refractory metal grades
  • Low electrical conductivity — 2.5 % IACS, worse than 86% of refractory metal grades
  • Low stiffness — 99 GPa (14.4 Msi), worse than 79% of refractory metal grades

Zr 704C-F properties

Typical room-temperature values for Zr 704C-F; 10 are specific to this condition. Other listed values are Zr 704C reference data and may not represent this condition. Bars are the position among refractory metal grades.

Physical3

Zr 704C-F has a density of 6.56 g/cm³ (0.237 lb/in³), lighter than 71% of refractory metal grades. It melts at 1,800°C (3,272 °F).

Density6.56 g/cm³0.24 lb/in³
Melting Point (Solidus)1,800°C3,272 °F
Liquidus Temperature1,845°C3,353 °F

Mechanical16

Zr 704C-F has a yield strength of 300 MPa (43.5 ksi) and a tensile strength of 450 MPa (65.3 ksi) — weaker than 60% of refractory metal grades. Elongation at break is 13% and the elastic modulus is 99 GPa (14.4 Msi).

Elastic (Young's) Modulus99 GPa14.4 Msi
Shear Modulus36 GPa5.2 Msi
Bulk Modulus97 GPa14.1 Msi
Poisson's Ratio0.34
Tensile Strength (Ultimate)450 MPa65.3 ksi
Yield Strength (0.2% offset)300 MPa43.5 ksi
Elongation at Break13%
Reduction in Area20%
Compressive Strength320 MPa46.4 ksi
Shear Strength300 MPa43.5 ksi
Fatigue Strength (Endurance Limit)200 MPa29 ksi
Fracture Toughness (K_IC)50 MPa·√m45.5 ksi·√in
Charpy V-Notch Impact (RT)20 J14.8 ft·lbf
Hardness, Brinell190 HB
Hardness, Rockwell B89 HRB
Hardness, Vickers200 HV

Thermal6

Zr 704C-F is rated for continuous service to 400°C (752 °F). It conducts heat at 13 W/m·K (7.51 BTU/hr·ft·°F), worse than 95% of refractory metal grades. Thermal expansion is 6 µm/m·K (3.33 µin/in·°F).

Thermal Conductivity13 W/m·K7.5 BTU/hr·ft·°F
Specific Heat Capacity285 J/kg·K0.07 BTU/lb·°F
Thermal Expansion (CTE, 20–100 °C)6 µm/m·K3.3 µin/in·°F
Latent Heat of Fusion155 J/g66.6 BTU/lb
Max Service Temperature (continuous)400°C752 °F
Min Service Temperature-75°C-103 °F

Electrical3

Zr 704C-F conducts electricity at 2.5 % IACS, worse than 86% of refractory metal grades.

Electrical Conductivity2.5 % IACS
Electrical Resistivity6.8×10⁻⁷ Ω·m26.8 µΩ·in
Magnetic Responsenon-magnetic (paramagnetic, µr ≈ 1.000)

Chemical & Environmental3

Corrosion resistance is excellent (90/100), better than 75% of refractory metal grades.

Galvanic Potential (seawater, vs SCE)-0.15 V
Corrosion ResistanceExcellent90/100
Chemical Resistance SummaryOutstanding in HCl (all concentrations to boiling), H2SO4 up to ~70%, nitric acid, organic acids, and hot caustic; attacked by HF, wet chlorine, FeCl3/CuCl2 oxidizing chlorides, and aqua regia; risk of hydrogen pickup and stress-corrosion cracking in strong oxidizing chloride media.

Sustainability4

Producing a kilogram of Zr 704C-F takes about 1,200 MJ of energy and emits 75 kg of CO₂ — less than 51% of refractory metal grades. Typical recycled content is 25%.

Embodied Energy (primary production)1,200 MJ/kg515,908 BTU/lb
Embodied Carbon (primary production)75 kg CO₂/kg
Embodied Water900 L/kg108 gal/lb
Typical Recycled Content25%

Manufacturability8

Zr 704C-F's machinability is poor (30/100, better than 54% of refractory metal grades); weldability good (65/100); formability poor (20/100).

MachinabilityPoor30/100
Machinability Rating (AISI 1212 = 100 %)28%
WeldabilityGood65/100
Formability (cold)Poor20/100
CastabilityGood55/100
Brazeability / SolderabilityPoor20/100
PolishabilityGood60/100
Anodizing Responsen/a for engineering use — Zr self-passivates; anodic oxide colouring is possible but not a standard treatment for castings

Common Calculations5

Specific Strength (UTS / density)calculated69 kN·m/kg
Specific Stiffness (E / density)calculated15.1 MN·m/kg
Modulus of Resiliencecalculated455 kJ/m³
Thermal Diffusivitycalculated7 mm²/s
Thermal Shock Resistance Indexcalculated10

Values are nominal handbook figures for design screening. Confirm any required mill or lot documentation when quoting.

Working with Zr 704C-F

Is Zr 704C easy to machine?

Use slow speeds, heavy positive-rake carbide tooling and flood coolant to avoid galling and work hardening; collect chips wet — fine Zr swarf is pyrophoric.

Can Zr 704C be welded?

GTAW weld repair is routine but must be done with full argon/helium shielding or in a chamber (<50 ppm O2/N2); avoid oxide, oil and hydrogen sources, then stress relieve.

Can Zr 704C be formed, bent or molded?

Vacuum or inert-gas induction melting into graphite or rammed-graphite moulds; generous risers and controlled interstitial pickup are essential, HIP optional to close porosity.

What surface finishes work on Zr 704C?

Grit blast plus nitric-hydrofluoric pickle to remove alpha case and mould reaction layer; the self-formed oxide is the working corrosion barrier — no coating or plating required.

Zr 704C chemical composition (wt %)

Limits by weight percent from the governing specification, written the way the spec states them — a single maximum for impurities, a range for alloying elements, and the base element as balance. Nominal is the typical mid-range value.

ElementSpec limit (wt %)Nominal
Snsolid-solution strengthener1 – 21.5
Fe+Crcombined iron plus chromium per ASTM B7520.2 – 0.40.3
Hfhafnium not removed (non-nuclear grade)≤ 4.5—
Ointerstitial limit; controls ductility≤ 0.180.12
C≤ 0.05—
N≤ 0.03—
H≤ 0.01—
ZrZr + Hf ≥ 97.5 % typicalbalance—

Zr 704C-F — frequently asked

What is Zr 704C-F used for?

Zr 704C-F is typically used for cast valve bodies, pump impellers and corrosion-resistant castings. In short: strongest cast Zr grade; sn-alloyed for higher yield; self-forming oxide barrier.

What is the yield strength of Zr 704C-F?

Zr 704C-F has a typical yield strength of 300 MPa (43.5 ksi) and a tensile strength of 450 MPa (65.3 ksi) — weaker than 60% of refractory metal grades. Strength varies by condition: see the 3 listed tempers.

Is Zr 704C-F easy to machine?

Not especially — machinability is rated poor (30/100, better than 54% of refractory metal grades). Use slow speeds, heavy positive-rake carbide tooling and flood coolant to avoid galling and work hardening; collect chips wet — fine Zr swarf is pyrophoric.

Can Zr 704C-F be welded?

Yes — weldability is rated good (65/100). GTAW weld repair is routine but must be done with full argon/helium shielding or in a chamber (<50 ppm O2/N2); avoid oxide, oil and hydrogen sources, then stress relieve.

What surface finishes work on Zr 704C-F?

Grit blast plus nitric-hydrofluoric pickle to remove alpha case and mould reaction layer; the self-formed oxide is the working corrosion barrier — no coating or plating required.

Can Zr 704C-F be formed, bent or molded?

Vacuum or inert-gas induction melting into graphite or rammed-graphite moulds; generous risers and controlled interstitial pickup are essential, HIP optional to close porosity.

What is the maximum service temperature of Zr 704C-F?

Zr 704C-F is rated for continuous use to about 400°C (752 °F). Strength falls off well before that limit — check the elevated-temperature data for load-bearing parts.

What is the difference between Zr 704C-F and Zr 704C-SR?

F is the default condition — standard supply condition for corrosion-service valve bodies and pump casings; meets ASTM B752 Grade 704C minima without further heat treatment. SR: choose when residual casting or weld-repair stresses must be removed to minimise stress-corrosion cracking risk in chloride-bearing service. Yield strength is 300 MPa in F versus 275 MPa in SR.

Sources

  1. ASTM B752 — Standard Specification for Castings, Zirconium-Base, Corrosion Resistant, for General Application — ASTM International (2020)
  2. ASTM B551/B550 — Zirconium and Zirconium Alloy Strip, Sheet, Plate, Bar and Wire (Grade R60704) — ASTM International (2019)
  3. ASM Handbook Vol. 2 — Properties and Selection: Nonferrous Alloys (Zirconium and Hafnium) — ASM International (1990)
  4. ASM Handbook Vol. 13B — Corrosion: Materials (Zirconium) — ASM International (2005)
  5. ATI Zirconium Alloys 702/704/705 technical data — ATI Specialty Materials (2016)

Property data is compiled from published supplier and standards handbooks and normalised for comparison. Nothing on this page is a certification — request mill certs, CoC or material test reports with your order.