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Refractory Metal Reactor Grade Zr Sponge

Grade

UNS R60001 · ASTM B350 Reactor Grade

Sponge = kroll-process reactor grade zirconium sponge

Buy this as melt feedstock for Zircaloy/Zr-2.5Nb ingots; quality is judged by Brinell hardness of compacted sponge plus impurity/Hf limits, not by tensile data.

High cost $$$$

Values for the Sponge condition

Other Reactor Grade Zr tempers and conditions

Reactor Grade Zr is listed in 4 conditions; see the grade overview at Reactor Grade Zr.

Compare all 4 conditionsHide
Condition · open for datasheetBest forYield MPaTensile MPaElong. %HardnessConductivity
ANNDefault
Annealed
Default wrought condition for reactor-grade bar, sheet, plate and wire: maximum ductility and formability, lowest residual stress and best hydride/corrosion behaviour.2003303095 HB22 W/m·K
Hot Worked
Intermediate mill condition for heavy bar, billet and plate; slightly stronger and less ductile than fully annealed, usually annealed before final service.25038025110 HB4.1 % IACS
SpongeThis page
Kroll-process reactor grade zirconium sponge
Buy this as melt feedstock for Zircaloy/Zr-2.5Nb ingots; quality is judged by Brinell hardness of compacted sponge plus impurity/Hf limits, not by tensile data.———85 HB4.1 % IACS
Cold worked and stress relieved
Choose for tube, thin strip and springy parts needing higher strength and creep resistance; ductility and formability drop and residual texture anisotropy is pronounced.38048016145 HB—

What is Reactor Grade Zr Sponge?

Reactor Grade Zr Sponge is Reactor Grade Zr in the Sponge grade — buy this as melt feedstock for Zircaloy/Zr-2.5Nb ingots; quality is judged by Brinell hardness of compacted sponge plus impurity/Hf limits, not by tensile data. Reactor Grade Zr Sponge has a yield strength of 200 MPa (29 ksi) and a tensile strength of 330 MPa (47.9 ksi) — weaker than 87% of refractory metal grades. Elongation at break is 30% and the elastic modulus is 99 GPa (14.4 Msi). Reactor Grade Zr Sponge has a density of 6.51 g/cm³ (0.235 lb/in³), lighter than 84% of refractory metal grades. It melts at 1,852°C (3,366 °F). ANN is the default condition FabDigit quotes; Sponge is available on request or by drawing note.

Advantages

  • Ductile — tolerates forming and impact — 30%, better than 86% of refractory metal grades
  • Lightweight — 6.51 g/cm³ (0.235 lb/in³), better than 84% of refractory metal grades

Limitations

  • Difficult to machine — 0/100, worse than 100% of refractory metal grades
  • Difficult to weld — 0/100, worse than 100% of refractory metal grades
  • Limited formability — 0/100, worse than 100% of refractory metal grades
  • Limited service temperature — 350°C (662 °F), worse than 89% of refractory metal grades
  • Low strength — 200 MPa (29 ksi), worse than 87% of refractory metal grades

Reactor Grade Zr Sponge properties

Typical room-temperature values for Reactor Grade Zr Sponge; 10 are specific to this condition. Other listed values are Reactor Grade Zr reference data and may not represent this condition. Bars are the position among refractory metal grades.

Physical3

Reactor Grade Zr Sponge has a density of 6.51 g/cm³ (0.235 lb/in³), lighter than 84% of refractory metal grades. It melts at 1,852°C (3,366 °F).

Density6.51 g/cm³0.24 lb/in³
Melting Point (Solidus)1,852°C3,366 °F
Liquidus Temperature1,852°C3,366 °F

Mechanical16

Reactor Grade Zr Sponge has a yield strength of 200 MPa (29 ksi) and a tensile strength of 330 MPa (47.9 ksi) — weaker than 87% of refractory metal grades. Elongation at break is 30% and the elastic modulus is 99 GPa (14.4 Msi).

Elastic (Young's) Modulus99 GPa14.4 Msi
Shear Modulus36 GPa5.2 Msi
Bulk Modulus91 GPa13.2 Msi
Poisson's Ratio0.34
Tensile Strength (Ultimate)330 MPa47.9 ksi
Yield Strength (0.2% offset)200 MPa29 ksi
Elongation at Break30%
Reduction in Area45%
Compressive Strength220 MPa31.9 ksi
Shear Strength215 MPa31.2 ksi
Fatigue Strength (Endurance Limit)180 MPa26.1 ksi
Fracture Toughness (K_IC)60 MPa·√m54.6 ksi·√in
Charpy V-Notch Impact (RT)70 J51.6 ft·lbf
Hardness, Brinell85 HB
Hardness, Rockwell B40 HRB
Hardness, Vickers90 HV

Thermal6

Reactor Grade Zr Sponge is rated for continuous service to 350°C (662 °F). It conducts heat at 22 W/m·K (12.7 BTU/hr·ft·°F), worse than 66% of refractory metal grades. Thermal expansion is 5.8 µm/m·K (3.22 µin/in·°F).

Thermal Conductivity22 W/m·K12.7 BTU/hr·ft·°F
Specific Heat Capacity285 J/kg·K0.07 BTU/lb·°F
Thermal Expansion (CTE, 20–100 °C)5.8 µm/m·K3.2 µin/in·°F
Latent Heat of Fusion153 J/g65.8 BTU/lb
Max Service Temperature (continuous)350°C662 °F
Min Service Temperature-196°C-321 °F

Electrical3

Reactor Grade Zr Sponge conducts electricity at 4.1 % IACS, worse than 66% of refractory metal grades.

Electrical Conductivity4.1 % IACS
Electrical Resistivity4.2×10⁻⁷ Ω·m16.5 µΩ·in
Magnetic Responsenon-magnetic (paramagnetic, relative permeability ≈ 1.0)

Chemical & Environmental3

Corrosion resistance is very good (80/100), worse than 54% of refractory metal grades.

Galvanic Potential (seawater, vs SCE)-0.15 V
Corrosion ResistanceVery good80/100
Chemical Resistance SummaryOutstanding in high-temperature water/steam, most alkalis, chlorides, nitric and dilute-to-moderate sulfuric/hydrochloric acids; attacked by HF, fluoride-bearing media, aqua regia, hot concentrated H2SO4 (>70 %) and wet chlorine; picks up hydrogen and forms brittle hydrides under cathodic conditions.

Sustainability4

Producing a kilogram of Reactor Grade Zr Sponge takes about 1,300 MJ of energy and emits 80 kg of CO₂ — more than 57% of refractory metal grades. Typical recycled content is 5%.

Embodied Energy (primary production)1,300 MJ/kg558,900 BTU/lb
Embodied Carbon (primary production)80 kg CO₂/kg
Embodied Water900 L/kg108 gal/lb
Typical Recycled Content5%

Manufacturability8

Reactor Grade Zr Sponge's machinability is not recommended (0/100, worse than 100% of refractory metal grades); weldability not recommended (0/100); formability not recommended (0/100).

MachinabilityNot recommended0/100
Machinability Rating (AISI 1212 = 100 %)25%
WeldabilityNot recommended0/100
Formability (cold)Not recommended0/100
CastabilityPoor25/100
Brazeability / SolderabilityPoor25/100
PolishabilityGood60/100
Anodizing Responsefair — decorative/interference anodic oxide colours are achievable in phosphoric or sulfuric electrolytes, but anodizing is not a standard nuclear finish; the natural ZrO2 film or autoclave pre-oxidation is used instead

Values are nominal handbook figures for design screening. Confirm any required mill or lot documentation when quoting.

Working with Reactor Grade Zr Sponge

Is Reactor Grade Zr easy to machine?

Machine like austenitic stainless but gummy: sharp positive-rake carbide or HSS tools, slow speed with heavy feed, flood coolant (water-soluble, chlorine-free) and continuous chip removal — fine chips and swarf are pyrophoric, so collect wet and never dry-grind.

Can Reactor Grade Zr be welded?

GTAW/EBW/laser only, with high-purity argon or helium chamber/trailing shield and clean pickled surfaces; oxygen, nitrogen and hydrogen pickup embrittles the weld, and bright silver bead colour is the acceptance indicator.

Can Reactor Grade Zr be formed, bent or molded?

Cold form annealed material with generous bend radii (≥3–5 t) allowing for HCP texture anisotropy and springback; warm form or forge at 700–800 °C in the alpha field, avoiding lead/chloride lubricants and iron pickup from tooling.

What surface finishes work on Reactor Grade Zr?

Nitric–hydrofluoric pickling plus grit blasting removes oxide/alpha case; autoclave pre-oxidation gives the protective black ZrO2 film, decorative anodic colours are possible, and plating/painting is rarely used.

Reactor Grade Zr chemical composition (wt %)

Limits by weight percent from the governing specification, written the way the spec states them — a single maximum for impurities, a range for alloying elements, and the base element as balance. Nominal is the typical mid-range value.

ElementSpec limit (wt %)Nominal
Hfkey reactor-grade limit (<100 ppm)≤ 0.010.01
Fe≤ 0.150.05
Cr≤ 0.020.01
Ocontrols strength/hardness; often reported rather than limited on sponge≤ 0.160.09
C≤ 0.030.01
N≤ 0.010
H≤ 00
Al≤ 0.010
Si≤ 0.010.01
Ni≤ 0.010
Ti≤ 0.010
Cu≤ 0.010
Mn≤ 0.010
Mo≤ 0.010
W≤ 0.010
Coactivation-sensitive≤ 05×10⁻⁴
B≤0.5 ppm, neutron poison≤ 5×10⁻⁵2×10⁻⁵
Cd≤0.5 ppm, neutron poison≤ 5×10⁻⁵2×10⁻⁵
U (total)≤3.5 ppm≤ 3.5×10⁻⁴1×10⁻⁴
Zrbalance; typically ≥99.5 % excluding Hfbalance—

Reactor Grade Zr Sponge — frequently asked

What is Reactor Grade Zr Sponge used for?

Reactor Grade Zr Sponge is typically used for zircaloy feedstock, reactor internals and fuel cladding precursor material. In short: hafnium-free nuclear feedstock; lowest neutron absorption; ASTM B350 reactor purity.

What is the yield strength of Reactor Grade Zr Sponge?

Reactor Grade Zr Sponge has a typical yield strength of 200 MPa (29 ksi) and a tensile strength of 330 MPa (47.9 ksi) — weaker than 87% of refractory metal grades. Strength varies by condition: see the 4 listed tempers.

Is Reactor Grade Zr Sponge easy to machine?

Not especially — machinability is rated not recommended (0/100, worse than 100% of refractory metal grades). Machine like austenitic stainless but gummy: sharp positive-rake carbide or HSS tools, slow speed with heavy feed, flood coolant (water-soluble, chlorine-free) and continuous chip removal — fine chips and swarf are pyrophoric, so collect wet and never dry-grind.

Can Reactor Grade Zr Sponge be welded?

Not readily — weldability is rated not recommended (0/100). GTAW/EBW/laser only, with high-purity argon or helium chamber/trailing shield and clean pickled surfaces; oxygen, nitrogen and hydrogen pickup embrittles the weld, and bright silver bead colour is the acceptance indicator.

What surface finishes work on Reactor Grade Zr Sponge?

Nitric–hydrofluoric pickling plus grit blasting removes oxide/alpha case; autoclave pre-oxidation gives the protective black ZrO2 film, decorative anodic colours are possible, and plating/painting is rarely used.

Can Reactor Grade Zr Sponge be formed, bent or molded?

Cold form annealed material with generous bend radii (≥3–5 t) allowing for HCP texture anisotropy and springback; warm form or forge at 700–800 °C in the alpha field, avoiding lead/chloride lubricants and iron pickup from tooling.

What is the maximum service temperature of Reactor Grade Zr Sponge?

Reactor Grade Zr Sponge is rated for continuous use to about 350°C (662 °F). Strength falls off well before that limit — check the elevated-temperature data for load-bearing parts.

What is the difference between Reactor Grade Zr-ANN and Reactor Grade Zr CWSR?

ANN is the default condition — default wrought condition for reactor-grade bar, sheet, plate and wire: maximum ductility and formability, lowest residual stress and best hydride/corrosion behaviour. CWSR: choose for tube, thin strip and springy parts needing higher strength and creep resistance; ductility and formability drop and residual texture anisotropy is pronounced. Yield strength is 200 MPa in ANN versus 380 MPa in CWSR.

Sources

  1. ASTM B349/B349M — Zirconium Sponge and Other Forms of Virgin Metal for Nuclear Application — ASTM International (2022)
  2. ASTM B350/B350M — Zirconium and Zirconium Alloy Ingots for Nuclear Application — ASTM International (2022)
  3. ASTM B550/B550M — Zirconium and Zirconium Alloy Bar and Wire — ASTM International (2020)
  4. ASTM B551/B551M — Zirconium and Zirconium Alloy Strip, Sheet, and Plate — ASTM International (2019)
  5. ASM Handbook Vol. 2 — Properties and Selection: Nonferrous Alloys and Special-Purpose Materials (Zirconium and Hafnium) — ASM International (1990)
  6. Zirconium alloys — properties and fabrication guide — ATI (Wah Chang) (2015)

Property data is compiled from published supplier and standards handbooks and normalised for comparison. Nothing on this page is a certification — request mill certs, CoC or material test reports with your order.