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Refractory Metal R02002-SR (Stress relieved)

Heat-treated state

UNS R02002 · ASTM B776 Grade 2, B737 Grade 2

Compromise condition: keeps most cold-work strength while removing residual stress and distortion after machining.

High cost $$$$

Values for the SR condition

Other R02002 tempers and conditions

R02002 is listed in 4 conditions; see the grade overview at R02002.

Compare all 4 conditionsHide
Condition · open for datasheetBest forYield MPaTensile MPaElong. %HardnessConductivity
ANNDefault
Annealed
Default stocked condition: maximum ductility for forming, welding and machining of plasma electrodes and chemical parts.24045025165 HB—
Hot Worked
Economical heavy-section form for further machining or re-melt stock; surface carries oxide/alpha case and is normally conditioned.31050020185 HB5 % IACS
SRThis page
Stress relieved
Compromise condition: keeps most cold-work strength while removing residual stress and distortion after machining.5006201219 HRC5.1 % IACS
Cold worked
Choose when higher strength, straightness and surface finish are needed and no severe forming follows.620700623 HRC5 % IACS

What is R02002-SR?

R02002-SR is R02002 heat treated to SR — compromise condition: keeps most cold-work strength while removing residual stress and distortion after machining. R02002-SR has a yield strength of 500 MPa (72.5 ksi) and a tensile strength of 620 MPa (89.9 ksi) — stronger than 75% of refractory metal grades. Elongation at break is 12% and the elastic modulus is 138 GPa (20 Msi). R02002-SR has a density of 13.31 g/cm³ (0.481 lb/in³), heavier than 77% of refractory metal grades. It melts at 2,233°C (4,051 °F). ANN is the default condition FabDigit quotes; SR is available on request or by drawing note.

Advantages

  • High strength — 500 MPa (72.5 ksi), better than 75% of refractory metal grades

Limitations

  • High embodied carbon — 130 kg CO₂/kg, worse than 83% of refractory metal grades
  • Heavy — 13.31 g/cm³ (0.481 lb/in³), worse than 77% of refractory metal grades

R02002-SR properties

Typical room-temperature values for R02002-SR; 22 are specific to this condition. Other listed values are R02002 reference data and may not represent this condition. Bars are the position among refractory metal grades.

Physical3

R02002-SR has a density of 13.31 g/cm³ (0.481 lb/in³), heavier than 77% of refractory metal grades. It melts at 2,233°C (4,051 °F).

Density13.31 g/cm³0.48 lb/in³
Melting Point (Solidus)2,233°C4,051 °F
Liquidus Temperature2,233°C4,051 °F

Mechanical12

R02002-SR has a yield strength of 500 MPa (72.5 ksi) and a tensile strength of 620 MPa (89.9 ksi) — stronger than 75% of refractory metal grades. Elongation at break is 12% and the elastic modulus is 138 GPa (20 Msi).

Elastic (Young's) Modulus138 GPa20 Msi
Shear Modulus55 GPa8 Msi
Bulk Modulus110 GPa16 Msi
Poisson's Ratio0.3
Tensile Strength (Ultimate)620 MPa89.9 ksi
Yield Strength (0.2% offset)500 MPa72.5 ksi
Elongation at Break12%
Reduction in Area25%
Shear Strength380 MPa55.1 ksi
Hardness, Brinell218 HB
Hardness, Rockwell B96 HRB
Hardness, Vickers230 HV

Thermal6

R02002-SR is rated for continuous service to 400°C (752 °F). It conducts heat at 23 W/m·K (13.3 BTU/hr·ft·°F), worse than 61% of refractory metal grades. Thermal expansion is 5.9 µm/m·K (3.28 µin/in·°F).

Thermal Conductivity23 W/m·K13.3 BTU/hr·ft·°F
Specific Heat Capacity144 J/kg·K0.03 BTU/lb·°F
Thermal Expansion (CTE, 20–100 °C)5.9 µm/m·K3.3 µin/in·°F
Latent Heat of Fusion152 J/g65.3 BTU/lb
Max Service Temperature (continuous)400°C752 °F
Min Service Temperature-196°C-321 °F

Electrical3

R02002-SR conducts electricity at 5.1 % IACS, worse than 58% of refractory metal grades.

Electrical Conductivity5.1 % IACS
Electrical Resistivity3.38×10⁻⁷ Ω·m13.3 µΩ·in
Magnetic Responsenon-magnetic

Chemical & Environmental2

Corrosion resistance is excellent (85/100), better than 52% of refractory metal grades.

Corrosion ResistanceExcellent85/100
Chemical Resistance SummarySelf-passivating oxide gives excellent resistance to seawater, alkalis, most organic acids and nitric/hydrochloric acid up to moderate concentrations; attacked by HF and fluoride-bearing media, hot concentrated sulfuric acid and aqua regia; powder/fine chips are pyrophoric.

Sustainability3

Producing a kilogram of R02002-SR takes about 2,000 MJ of energy and emits 130 kg of CO₂ — more than 83% of refractory metal grades. Typical recycled content is 20%.

Embodied Energy (primary production)2,000 MJ/kg859,846 BTU/lb
Embodied Carbon (primary production)130 kg CO₂/kg
Typical Recycled Content20%

Manufacturability8

R02002-SR's machinability is poor (33/100, better than 71% of refractory metal grades); weldability good (65/100); formability fair (35/100).

MachinabilityPoor33/100
Machinability Rating (AISI 1212 = 100 %)21%
WeldabilityGood65/100
Formability (cold)Fair35/100
CastabilityPoor25/100
Brazeability / SolderabilityFair40/100
PolishabilityVery good70/100
Anodizing Responsen/a for standard industrial finishing — Hf can be anodized to form interference-coloured oxide films (as with Zr/Nb) but this is a decorative/lab process, not a spec'd surface treatment.

Values are nominal handbook figures for design screening. Confirm any required mill or lot documentation when quoting.

Working with R02002-SR

Is R02002 easy to machine?

Machine like zirconium: slow speed, heavy positive-rake sharp carbide, deep cuts, flood coolant — never dry; collect chips wet, they are pyrophoric.

Can R02002 be welded?

GTAW/EB/laser only with full inert (Ar/He) chamber or trailing-shield coverage; keep O/N/H pickup low or the weld embrittles.

Can R02002 be formed, bent or molded?

Cold form annealed sheet with 3–5t bend radii and polished dies to avoid galling; warm form 200–400 °C for tighter radii, then stress relieve.

What surface finishes work on R02002?

Pickle in HNO3/HF to strip oxide and alpha case; passivates naturally in air, can be electropolished or anodized for colour; no plating normally required.

R02002 chemical composition (wt %)

Limits by weight percent from the governing specification, written the way the spec states them — a single maximum for impurities, a range for alloying elements, and the base element as balance. Nominal is the typical mid-range value.

ElementSpec limit (wt %)Nominal
ZrResidual zirconium; commercial grade may exceed reactor-grade practice — confirm with purchase order≤ 4.52.5
OMain strengthening interstitial≤ 0.20.1
C≤ 0.030.01
N≤ 0.010
H≤ 0.010
Fe+Cr≤ 0.250.1
Al≤ 0.010
Ti≤ 0.050.01
UNot restricted for commercial grade (restricted only in nuclear grade R02001)——
HfHf + Zr reported together; Hf/Zr ratio not restricted for commercial gradebalance—

R02002-SR — frequently asked

What is R02002-SR used for?

R02002-SR is typically used for plasma cutting electrode tips, getter alloys, high-temperature coatings and cermets, superalloy additive and research and specialty tooling. In short: cheaper non-nuclear hafnium; unrestricted Hf/Zr ratio; plasma electrode grade.

What is the yield strength of R02002-SR?

R02002-SR has a typical yield strength of 500 MPa (72.5 ksi) and a tensile strength of 620 MPa (89.9 ksi) — stronger than 75% of refractory metal grades. Strength varies by condition: see the 4 listed tempers.

Is R02002-SR easy to machine?

Not especially — machinability is rated poor (33/100, better than 71% of refractory metal grades). Machine like zirconium: slow speed, heavy positive-rake sharp carbide, deep cuts, flood coolant — never dry; collect chips wet, they are pyrophoric.

Can R02002-SR be welded?

Yes — weldability is rated good (65/100). GTAW/EB/laser only with full inert (Ar/He) chamber or trailing-shield coverage; keep O/N/H pickup low or the weld embrittles.

What surface finishes work on R02002-SR?

Pickle in HNO3/HF to strip oxide and alpha case; passivates naturally in air, can be electropolished or anodized for colour; no plating normally required.

Can R02002-SR be formed, bent or molded?

Cold form annealed sheet with 3–5t bend radii and polished dies to avoid galling; warm form 200–400 °C for tighter radii, then stress relieve.

What is the maximum service temperature of R02002-SR?

R02002-SR is rated for continuous use to about 400°C (752 °F). Strength falls off well before that limit — check the elevated-temperature data for load-bearing parts.

What is the difference between R02002-ANN and R02002-CW?

ANN is the default condition — default stocked condition: maximum ductility for forming, welding and machining of plasma electrodes and chemical parts. CW: choose when higher strength, straightness and surface finish are needed and no severe forming follows. Yield strength is 240 MPa in ANN versus 620 MPa in CW.

Sources

  1. ASTM B776 — Standard Specification for Hafnium and Hafnium Alloy Strip, Sheet, and Plate — ASTM International (2021)
  2. ASTM B737 — Standard Specification for Hafnium and Hafnium Alloy Bar, Rod, and Wire — ASTM International (2021)
  3. ASM Handbook Vol. 2 — Properties and Selection: Nonferrous Alloys and Special-Purpose Materials — ASM International (1990)
  4. CRC Handbook of Chemistry and Physics (hafnium physical constants) — CRC Press (2022)
  5. Hafnium metal mill products datasheet — ATI Wah Chang (2015)
  6. Mineral Commodity Summaries — Hafnium/Zirconium — USGS (2025)

Property data is compiled from published supplier and standards handbooks and normalised for comparison. Nothing on this page is a certification — request mill certs, CoC or material test reports with your order.