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Refractory Metal NbTi-ANN (Annealed)

Heat-treated state · default condition

Standard stocked condition for NbTi billets, extrusion feedstock, rod and sheet; maximum ductility for subsequent co-extrusion and drawing.

High cost $$$$

Values for the ANN condition

Other NbTi tempers and conditions

NbTi is listed in 4 conditions; see the grade overview at NbTi.

Compare all 4 conditionsHide
Condition · open for datasheetBest forYield MPaTensile MPaElong. %HardnessConductivity
ANNDefaultThis page
Annealed
Standard stocked condition for NbTi billets, extrusion feedstock, rod and sheet; maximum ductility for subsequent co-extrusion and drawing.35062025160 HB12 W/m·K
Hot worked (extruded / forged) bar, as-worked
Choose for as-forged or as-extruded NbTi bar and monofilament preform stock where partial work hardening is acceptable.5207201812 HRC2.9 % IACS
Cold worked
Bare NbTi filament or fine wire after heavy drawing reduction, before or between precipitation heat treatments; highest strength, low ductility.9001,000428 HRC2.7 % IACS
Cold drawn with intermediate α-Ti precipitation heat treatments
The functional condition of finished superconducting filaments: 3–5 heat treatments near 400 °C interleaved with drawing to create α-Ti flux-pinning ribbons and maximum Jc.9301,050526 HRC2.7 % IACS

What is NbTi-ANN?

NbTi-ANN is NbTi heat treated to ANN — standard stocked condition for NbTi billets, extrusion feedstock, rod and sheet; maximum ductility for subsequent co-extrusion and drawing. NbTi-ANN has a yield strength of 350 MPa (50.8 ksi) and a tensile strength of 620 MPa (89.9 ksi) — stronger than 57% of refractory metal grades. Elongation at break is 25% and the elastic modulus is 65 GPa (9.43 Msi). NbTi-ANN has a density of 6.05 g/cm³ (0.219 lb/in³), lighter than 87% of refractory metal grades. It melts at 1,900°C (3,452 °F).

Advantages

  • Forms and bends easily — 92/100, better than 95% of refractory metal grades
  • Lightweight — 6.05 g/cm³ (0.219 lb/in³), better than 87% of refractory metal grades

Limitations

  • Low stiffness — 65 GPa (9.43 Msi), worse than 100% of refractory metal grades
  • Poor heat conductor — 12 W/m·K (6.93 BTU/hr·ft·°F), worse than 98% of refractory metal grades
  • Low electrical conductivity — 2.9 % IACS, worse than 83% of refractory metal grades
  • Difficult to machine — 20/100, worse than 77% of refractory metal grades

NbTi-ANN properties

Typical room-temperature values for NbTi-ANN; 12 are specific to this condition. Other listed values are NbTi reference data and may not represent this condition. Bars are the position among refractory metal grades.

Physical3

NbTi-ANN has a density of 6.05 g/cm³ (0.219 lb/in³), lighter than 87% of refractory metal grades. It melts at 1,900°C (3,452 °F).

Density6.05 g/cm³0.22 lb/in³
Melting Point (Solidus)1,900°C3,452 °F
Liquidus Temperature2,020°C3,668 °F

Mechanical10

NbTi-ANN has a yield strength of 350 MPa (50.8 ksi) and a tensile strength of 620 MPa (89.9 ksi) — stronger than 57% of refractory metal grades. Elongation at break is 25% and the elastic modulus is 65 GPa (9.43 Msi).

Elastic (Young's) Modulus65 GPa9.4 Msi
Shear Modulus24 GPa3.5 Msi
Poisson's Ratio0.34
Tensile Strength (Ultimate)620 MPa89.9 ksi
Yield Strength (0.2% offset)350 MPa50.8 ksi
Elongation at Break25%
Reduction in Area60%
Hardness, Brinell160 HB
Hardness, Rockwell B88 HRB
Hardness, Vickers170 HV

Thermal6

NbTi-ANN is rated for continuous service to 400°C (752 °F). It conducts heat at 12 W/m·K (6.93 BTU/hr·ft·°F), worse than 98% of refractory metal grades. Thermal expansion is 8 µm/m·K (4.44 µin/in·°F).

Thermal Conductivity12 W/m·K6.9 BTU/hr·ft·°F
Specific Heat Capacity350 J/kg·K0.08 BTU/lb·°F
Thermal Expansion (CTE, 20–100 °C)8 µm/m·K4.4 µin/in·°F
Latent Heat of Fusion290 J/g125 BTU/lb
Max Service Temperature (continuous)400°C752 °F
Min Service Temperature-271°C-456 °F

Electrical3

NbTi-ANN conducts electricity at 2.9 % IACS, worse than 83% of refractory metal grades.

Electrical Conductivity2.9 % IACS
Electrical Resistivity6×10⁻⁷ Ω·m23.6 µΩ·in
Magnetic Responsenon-magnetic (paramagnetic above Tc; perfectly diamagnetic in the superconducting state below ~9.5 K)

Chemical & Environmental3

Corrosion resistance is excellent (85/100), better than 52% of refractory metal grades.

Galvanic Potential (seawater, vs SCE)-0.1 V
Corrosion ResistanceExcellent85/100
Chemical Resistance SummarySelf-passivating TiO2/Nb2O5 film gives excellent resistance to seawater, most organic acids, chlorides and dilute mineral acids; attacked by HF, hot concentrated H2SO4/HCl and molten alkali; absorbs hydrogen and embrittles above ~300 °C in H2.

Sustainability3

Producing a kilogram of NbTi-ANN takes about 700 MJ of energy and emits 45 kg of CO₂ — less than 65% of refractory metal grades. Typical recycled content is 10%.

Embodied Energy (primary production)700 MJ/kg300,946 BTU/lb
Embodied Carbon (primary production)45 kg CO₂/kg
Typical Recycled Content10%

Manufacturability8

NbTi-ANN's machinability is poor (20/100, worse than 77% of refractory metal grades); weldability fair (45/100); formability excellent (92/100).

MachinabilityPoor20/100
Machinability Rating (AISI 1212 = 100 %)15%
WeldabilityFair45/100
Formability (cold)Excellent92/100
CastabilityPoor25/100
Brazeability / SolderabilityFair40/100
PolishabilityGood60/100
Anodizing Responsegood — anodizes like Nb/Ti to give hard interference-coloured oxide films; used for filament insulation and identification, not for wear protection

Common Calculations5

Specific Strength (UTS / density)calculated102 kN·m/kg
Specific Stiffness (E / density)calculated10.7 MN·m/kg
Modulus of Resiliencecalculated942 kJ/m³
Thermal Diffusivitycalculated5.7 mm²/s
Thermal Shock Resistance Indexcalculated14

Values are nominal handbook figures for design screening. Confirm any required mill or lot documentation when quoting.

Working with NbTi-ANN

Is NbTi easy to machine?

Machines like commercially pure titanium — gummy and work-hardening; use sharp uncoated carbide, low speed (15–30 m/min), heavy positive rake, flood coolant and never dwell.

Can NbTi be welded?

Weld only by EB or GTAW in high-purity argon/vacuum chambers; O/N/H pickup above ~300 °C causes embrittlement and destroys superconducting performance near the joint.

Can NbTi be formed, bent or molded?

Outstandingly cold-drawable — area reductions of 10^5 with intermediate 400 °C precipitation treatments; co-extrude in a copper can at 600–700 °C, avoid intermetallic-forming barriers (use Nb diffusion barrier with Cu).

What surface finishes work on NbTi?

Chemically etch/pickle in HNO3-HF, then anodize for coloured insulating oxide; copper cladding is normally left bright or given a thin Sn/Ag or Formvar/polyimide insulation.

NbTi chemical composition (wt %)

Limits by weight percent from the governing specification, written the way the spec states them — a single maximum for impurities, a range for alloying elements, and the base element as balance. Nominal is the typical mid-range value.

ElementSpec limit (wt %)Nominal
TiNb-47Ti nominal; Nb-46.5Ti and Nb-50Ti also produced46.5 – 4847
Tatypical superconductor-grade limit≤ 0.1—
Fe≤ 0.03—
Ointerstitials controlled to preserve drawability≤ 0.06—
C≤ 0.02—
N≤ 0.01—
H≤ 0—
Nbbalance—

NbTi-ANN — frequently asked

What is NbTi-ANN used for?

NbTi-ANN is typically used for MRI magnet wire, particle accelerator superconducting coils, fusion reactor magnets (e.g. ITER) and superconducting cables. In short: standard NbTi superconductor wire; formability score 92; cold-drawn, not welded.

What is the yield strength of NbTi-ANN?

NbTi-ANN has a typical yield strength of 350 MPa (50.8 ksi) and a tensile strength of 620 MPa (89.9 ksi) — stronger than 57% of refractory metal grades. Strength varies by condition: see the 4 listed tempers.

Is NbTi-ANN easy to machine?

Not especially — machinability is rated poor (20/100, worse than 77% of refractory metal grades). Machines like commercially pure titanium — gummy and work-hardening; use sharp uncoated carbide, low speed (15–30 m/min), heavy positive rake, flood coolant and never dwell.

Can NbTi-ANN be welded?

With care — weldability is rated fair (45/100). Weld only by EB or GTAW in high-purity argon/vacuum chambers; O/N/H pickup above ~300 °C causes embrittlement and destroys superconducting performance near the joint.

What surface finishes work on NbTi-ANN?

Chemically etch/pickle in HNO3-HF, then anodize for coloured insulating oxide; copper cladding is normally left bright or given a thin Sn/Ag or Formvar/polyimide insulation.

Can NbTi-ANN be formed, bent or molded?

Outstandingly cold-drawable — area reductions of 10^5 with intermediate 400 °C precipitation treatments; co-extrude in a copper can at 600–700 °C, avoid intermetallic-forming barriers (use Nb diffusion barrier with Cu).

What is the maximum service temperature of NbTi-ANN?

NbTi-ANN is rated for continuous use to about 400°C (752 °F). Strength falls off well before that limit — check the elevated-temperature data for load-bearing parts.

What is the difference between NbTi-ANN and NbTi-CW?

ANN is the default condition — standard stocked condition for NbTi billets, extrusion feedstock, rod and sheet; maximum ductility for subsequent co-extrusion and drawing. CW: bare NbTi filament or fine wire after heavy drawing reduction, before or between precipitation heat treatments; highest strength, low ductility. Yield strength is 350 MPa in ANN versus 900 MPa in CW.

Sources

  1. Handbook of Superconducting Materials (Cardwell & Ginley) — IOP Publishing (2003)
  2. ASM Handbook Vol.2 — Properties and Selection: Nonferrous Alloys and Special-Purpose Materials — ASM International (1990)
  3. NIST Cryogenic Material Properties Database — NIST (2020)
  4. NbTi superconducting wire and NbTi alloy rod datasheets — Supercon Inc. / Luvata / Bruker EAS / WST (2023)
  5. IEC 61788 series — Superconductivity: critical current and mechanical test methods — IEC (2020)

Property data is compiled from published supplier and standards handbooks and normalised for comparison. Nothing on this page is a certification — request mill certs, CoC or material test reports with your order.