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Magnesium Alloy ZM4-F (As fabricated)

Temper

Pick for lightly loaded, pressure-tight housings where the aging cycle is not economically justified.

High cost $$$$

Values for the F condition

Other ZM4 tempers and conditions

ZM4 is listed in 3 conditions; see the grade overview at ZM4.

Compare all 3 conditionsHide
Condition · open for datasheetBest forYield MPaTensile MPaElong. %HardnessConductivity
FThis page
As fabricated
Pick for lightly loaded, pressure-tight housings where the aging cycle is not economically justified.85135348 HB23 % IACS
T1Default
Cooled from hot working and naturally aged
Standard supplied condition for ZM4 castings per GB/T 1177 — best balance of strength, ductility and dimensional stability.100160355 HB25 % IACS
Solution heat treated and artificially aged
Used only on thin-wall, chill/investment castings processed by the ZE63A hydrogen heat-treatment route when maximum tensile properties are required.180280865 HB27 % IACS

What is ZM4-F?

ZM4-F is ZM4 in the F temper — pick for lightly loaded, pressure-tight housings where the aging cycle is not economically justified. ZM4-F has a yield strength of 85 MPa (12.3 ksi) and a tensile strength of 135 MPa (19.6 ksi) — weaker than 97% of magnesium alloy grades. Elongation at break is 3% and the elastic modulus is 44 GPa (6.38 Msi). ZM4-F has a density of 1.83 g/cm³ (0.0661 lb/in³), heavier than 81% of magnesium alloy grades. It melts at 510°C (950 °F). T1 is the default condition FabDigit quotes; F is available on request or by drawing note.

Limitations

  • Low fracture toughness — 11 MPa·√m (10 ksi·√in), worse than 100% of magnesium alloy grades
  • Low strength — 85 MPa (12.3 ksi), worse than 97% of magnesium alloy grades
  • Limited ductility — 3%, worse than 85% of magnesium alloy grades

ZM4-F properties

Typical room-temperature values for ZM4-F; 21 are specific to this condition. Other listed values are ZM4 reference data and may not represent this condition. Bars are the position among magnesium alloy grades.

Physical3

ZM4-F has a density of 1.83 g/cm³ (0.0661 lb/in³), heavier than 81% of magnesium alloy grades. It melts at 510°C (950 °F).

Density1.83 g/cm³0.07 lb/in³
Melting Point (Solidus)510°C950 °F
Liquidus Temperature640°C1,184 °F

Mechanical15

ZM4-F has a yield strength of 85 MPa (12.3 ksi) and a tensile strength of 135 MPa (19.6 ksi) — weaker than 97% of magnesium alloy grades. Elongation at break is 3% and the elastic modulus is 44 GPa (6.38 Msi).

Elastic (Young's) Modulus44 GPa6.4 Msi
Shear Modulus16.5 GPa2.4 Msi
Bulk Modulus45 GPa6.5 Msi
Poisson's Ratio0.35
Tensile Strength (Ultimate)135 MPa19.6 ksi
Yield Strength (0.2% offset)85 MPa12.3 ksi
Elongation at Break3%
Reduction in Area4%
Compressive Strength250 MPa36.3 ksi
Shear Strength105 MPa15.2 ksi
Fatigue Strength (Endurance Limit)70 MPa10.2 ksi
Fracture Toughness (K_IC)11 MPa·√m10 ksi·√in
Charpy V-Notch Impact (RT)3 J2.2 ft·lbf
Hardness, Brinell48 HB
Hardness, Vickers50 HV

Thermal6

ZM4-F is rated for continuous service to 150°C (302 °F). It conducts heat at 105 W/m·K (60.7 BTU/hr·ft·°F), better than 61% of magnesium alloy grades. Thermal expansion is 26.5 µm/m·K (14.7 µin/in·°F).

Thermal Conductivity105 W/m·K60.7 BTU/hr·ft·°F
Specific Heat Capacity1,000 J/kg·K0.24 BTU/lb·°F
Thermal Expansion (CTE, 20–100 °C)26.5 µm/m·K14.7 µin/in·°F
Latent Heat of Fusion370 J/g159 BTU/lb
Max Service Temperature (continuous)150°C302 °F
Min Service Temperature-100°C-148 °F

Electrical3

ZM4-F conducts electricity at 23 % IACS, better than 57% of magnesium alloy grades.

Electrical Conductivity23 % IACS
Electrical Resistivity7.5×10⁻⁸ Ω·m2.95 µΩ·in
Magnetic Responsenon-magnetic

Chemical & Environmental3

Corrosion resistance is poor (25/100), better than 64% of magnesium alloy grades.

Galvanic Potential (seawater, vs SCE)-1.6 V
Corrosion ResistancePoor25/100
Chemical Resistance SummaryResists dry air, most alcohols, alkalis and many organics; attacked rapidly by salt water, acids and any chloride-bearing wet environment; strongly anodic to steel, brass and aluminium so all fasteners and joints must be insulated.

Sustainability4

Producing a kilogram of ZM4-F takes about 320 MJ of energy and emits 30 kg of CO₂ — less than 74% of magnesium alloy grades. Typical recycled content is 15%.

Embodied Energy (primary production)320 MJ/kg137,575 BTU/lb
Embodied Carbon (primary production)30 kg CO₂/kg
Embodied Water500 L/kg59.9 gal/lb
Typical Recycled Content15%

Manufacturability8

ZM4-F's machinability is excellent (90/100, worse than 95% of magnesium alloy grades); weldability good (60/100); formability poor (15/100).

MachinabilityExcellent90/100
Machinability Rating (AISI 1212 = 100 %)380%
WeldabilityGood60/100
Formability (cold)Poor15/100
CastabilityVery good78/100
Brazeability / SolderabilityPoor25/100
PolishabilityGood55/100
Anodizing Responsen/a — not sulfuric-acid anodized; use chromate/fluoride conversion coating or Mg-specific anodic processes (HAE, Dow 17, MAO) followed by sealing and paint

Values are nominal handbook figures for design screening. Confirm any required mill or lot documentation when quoting.

Working with ZM4-F

Is ZM4 easy to machine?

Machines extremely easily at high speeds with sharp, positive-rake tools; use flood coolant or dry with chip control and never let fine chips/dust accumulate — Mg fines are a fire hazard (Class D extinguisher on hand).

Can ZM4 be welded?

TIG/GTAW in argon with EZ33A or matching Mg-RE-Zn filler works for foundry repair; preheat 150–260 °C and stress-relieve after welding to limit hot cracking around the Zn-rich grain boundaries.

Can ZM4 be formed, bent or molded?

Foundry alloy only — sand, investment and permanent-mould casting with SF6-free protective cover gas or flux; Zr grain refinement gives fine, pressure-tight structure but requires clean, low-Fe melt practice.

What surface finishes work on ZM4?

Always apply a chromate-free conversion coating or MAO/HAE anodic film followed by epoxy primer and topcoat; insulate from steel/aluminium fasteners to avoid severe galvanic attack.

ZM4 chemical composition (wt %)

Limits by weight percent from the governing specification, written the way the spec states them — a single maximum for impurities, a range for alloying elements, and the base element as balance. Nominal is the typical mid-range value.

ElementSpec limit (wt %)Nominal
Zn2 – 32.5
RE (Ce-rich mischmetal)Ce-rich mischmetal, ≥45 % Ce2.5 – 43
Zrgrain refiner, soluble Zr0.5 – 10.7
Alimpurity limit≤ 0.02—
Siimpurity limit≤ 0.01—
Feimpurity limit≤ 0.01—
Cuimpurity limit≤ 0.03—
Niimpurity limit≤ 0.01—
Others (total)total impurities≤ 0.3—
Mgbalance—

ZM4-F — frequently asked

What is ZM4-F used for?

ZM4-F is typically used for aerospace structural castings, high-strength gearbox housings, aircraft accessory housings, pressure-tight cast covers, cast brackets and mounts and missile structural castings. In short: highest-strength RE casting; fine Zr-refined structure; pressure-tight castings.

What is the yield strength of ZM4-F?

ZM4-F has a typical yield strength of 85 MPa (12.3 ksi) and a tensile strength of 135 MPa (19.6 ksi) — weaker than 97% of magnesium alloy grades. Strength varies by condition: see the 3 listed tempers.

Is ZM4-F easy to machine?

Yes — machinability is rated excellent (90/100, worse than 95% of magnesium alloy grades). Machines extremely easily at high speeds with sharp, positive-rake tools; use flood coolant or dry with chip control and never let fine chips/dust accumulate — Mg fines are a fire hazard (Class D extinguisher on hand).

Can ZM4-F be welded?

Yes — weldability is rated good (60/100). TIG/GTAW in argon with EZ33A or matching Mg-RE-Zn filler works for foundry repair; preheat 150–260 °C and stress-relieve after welding to limit hot cracking around the Zn-rich grain boundaries.

What surface finishes work on ZM4-F?

Always apply a chromate-free conversion coating or MAO/HAE anodic film followed by epoxy primer and topcoat; insulate from steel/aluminium fasteners to avoid severe galvanic attack.

Can ZM4-F be formed, bent or molded?

Foundry alloy only — sand, investment and permanent-mould casting with SF6-free protective cover gas or flux; Zr grain refinement gives fine, pressure-tight structure but requires clean, low-Fe melt practice.

What is the maximum service temperature of ZM4-F?

ZM4-F is rated for continuous use to about 150°C (302 °F). Strength falls off well before that limit — check the elevated-temperature data for load-bearing parts.

What is the difference between ZM4-T1 and ZM4-T6?

T1 is the default condition — standard supplied condition for ZM4 castings per GB/T 1177 — best balance of strength, ductility and dimensional stability. T6: used only on thin-wall, chill/investment castings processed by the ZE63A hydrogen heat-treatment route when maximum tensile properties are required. Yield strength is 100 MPa in T1 versus 180 MPa in T6.

Sources

  1. ASM Handbook Vol. 2 — Properties and Selection: Nonferrous Alloys (Magnesium Casting Alloys) — ASM International (1990)
  2. ASTM B80 — Magnesium-Alloy Sand Castings (ZE41A/ZE63A) — ASTM International (2020)
  3. ASM Handbook Vol. 13B — Corrosion: Materials (Magnesium) — ASM International (2005)

Property data is compiled from published supplier and standards handbooks and normalised for comparison. Nothing on this page is a certification — request mill certs, CoC or material test reports with your order.