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ZnSe CVD-MS

Grade

also Irtran-4

CVD-MS = multispectral / HIP-treated water-clear ZnSe

Pick when visible/NIR clarity and low scatter matter (0.4–14 µm multispectral windows, thermal imagers with visible channel); HIP coarsens grains so it is slightly weaker.

High cost $$$$

Values for the CVD-MS condition

Other ZnSe tempers and conditions

ZnSe is listed in 2 conditions; see the grade overview at ZnSe.

Compare all 2 conditionsHide
Condition · open for datasheetBest forYield MPaTensile MPaElong. %HardnessConductivity
Single-crystal ZnSe
Used as substrate and host for Cr²⁺:ZnSe / Fe²⁺:ZnSe mid-IR lasers and for lowest-scatter research optics; anisotropic, cleaves on {110}, expensive in large sizes.—42095 HV19 W/m·K
CVD-MSThis page
Multispectral / HIP-treated water-clear ZnSe
Pick when visible/NIR clarity and low scatter matter (0.4–14 µm multispectral windows, thermal imagers with visible channel); HIP coarsens grains so it is slightly weaker.—480100 HV18 W/m·K

What is ZnSe CVD-MS?

ZnSe CVD-MS is ZnSe in the CVD-MS grade — pick when visible/NIR clarity and low scatter matter (0.4–14 µm multispectral windows, thermal imagers with visible channel); HIP coarsens grains so it is slightly weaker. ZnSe CVD-MS has a tensile strength of 48 MPa (6.96 ksi), stronger than 51% of glass grades. The elastic modulus is 67 GPa (9.72 Msi). ZnSe CVD-MS has a density of 5.27 g/cm³ (0.19 lb/in³), heavier than 90% of glass grades. It melts at 1,525°C (2,777 °F).

Advantages

  • Conducts heat well — 18 W/m·K (10.4 BTU/hr·ft·°F), better than 85% of glass grades
  • Easy to machine — 45/100, better than 85% of glass grades

Limitations

  • Heavy — 5.27 g/cm³ (0.19 lb/in³), worse than 90% of glass grades
  • Limited service temperature — 250°C (482 °F), worse than 83% of glass grades
  • Low fracture toughness — 0.4 MPa·√m (0.364 ksi·√in), worse than 78% of glass grades

ZnSe CVD-MS properties

Typical room-temperature values for ZnSe CVD-MS; 16 are specific to this condition. Other listed values are ZnSe reference data and may not represent this condition. Bars are the position among glass grades.

Physical5

ZnSe CVD-MS has a density of 5.27 g/cm³ (0.19 lb/in³), heavier than 90% of glass grades. It melts at 1,525°C (2,777 °F).

Density5.27 g/cm³0.19 lb/in³
Melting Point (Solidus)1,525°C2,777 °F
Refractive Index2.403
Light Transmission71%
Porosity0%

Mechanical10

ZnSe CVD-MS has a tensile strength of 48 MPa (6.96 ksi), stronger than 51% of glass grades. The elastic modulus is 67 GPa (9.72 Msi).

Elastic (Young's) Modulus67 GPa9.7 Msi
Shear Modulus26.6 GPa3.9 Msi
Bulk Modulus40 GPa5.8 Msi
Poisson's Ratio0.28
Tensile Strength (Ultimate)48 MPa7 ksi
Flexural Strength50 MPa7.3 ksi
Fracture Toughness (K_IC)0.4 MPa·√m0.36 ksi·√in
Hardness, Vickers100 HV
Hardness, Knoop105 HK
Hardness, Mohs2.5

Thermal5

ZnSe CVD-MS is rated for continuous service to 250°C (482 °F). It conducts heat at 18 W/m·K (10.4 BTU/hr·ft·°F), better than 85% of glass grades. Thermal expansion is 7.1 µm/m·K (3.94 µin/in·°F).

Thermal Conductivity18 W/m·K10.4 BTU/hr·ft·°F
Specific Heat Capacity339 J/kg·K0.08 BTU/lb·°F
Thermal Expansion (CTE, 20–100 °C)7.1 µm/m·K3.9 µin/in·°F
Max Service Temperature (continuous)250°C482 °F
Min Service Temperature-200°C-328 °F

Electrical3

ZnSe CVD-MS has an electrical resistivity of 1×10¹⁰ Ω·m.

Electrical Resistivity1×10¹⁰ Ω·m3.94×10¹⁷ µΩ·in
Dielectric Constant (1 MHz)9.1
Volume Resistivity1×10¹² Ω·cm

Chemical & Environmental2

Corrosion resistance is good (55/100), worse than 74% of glass grades.

Corrosion ResistanceGood55/100
Chemical Resistance SummaryInsoluble in water (~0.001 g/100 g) and stable in most organic solvents and alcohols; attacked by mineral acids (HNO₃, HCl, H₂SO₄) and by strong alkalis, and surface oxidizes/hazes in humid air above ~300 °C. Avoid ultrasonic cleaning of coated parts; clean with isopropanol/acetone and lens tissue.

Manufacturability2

ZnSe CVD-MS's machinability is fair (45/100, better than 85% of glass grades).

MachinabilityFair45/100
PolishabilityExcellent88/100

Values are nominal handbook figures for design screening. Confirm any required mill or lot documentation when quoting.

Working with ZnSe CVD-MS

Is ZnSe easy to machine?

Grind/core with diamond tooling under flood coolant or single-point diamond turn with light depth of cut; brittle and prone to edge chipping, and all dust/swarf is toxic (Se) so wet cutting with sealed extraction is mandatory.

Can ZnSe be welded?

Not weldable — a brittle ceramic; join only by optical contacting, epoxy bonding or mechanical mounting in compliant (RTV/retaining-ring) cells to avoid mount stress.

Can ZnSe be formed, bent or molded?

Formed to net shape by CVD deposition on mandrels, then HIP for multispectral grade; no plastic forming is possible, curved optics are generated and polished from blanks.

What surface finishes work on ZnSe?

Pitch or polyurethane polish to <10 Å rms, then AR coat (ThF₄/YbF₃ or ZnS/YF₃ stacks) or DLC-protect the exposed face; keep bare surfaces dry and handle with gloves — hygroscopic-free but easily scratched.

ZnSe chemical composition (wt %)

Limits by weight percent from the governing specification, written the way the spec states them — a single maximum for impurities, a range for alloying elements, and the base element as balance. Nominal is the typical mid-range value.

ElementSpec limit (wt %)Nominal
Znstoichiometric ZnSe, 1:1 molar45 – 45.645.3
impurities (C, Si, Fe, Cu, O)total metallic + carbon impurities in optical grade; low absorption depends on ppm-level control≤ 0.010
Se≥ 54.4 (balance)—

ZnSe CVD-MS — frequently asked

What is ZnSe CVD-MS used for?

ZnSe CVD-MS is typically used for CO2 laser lenses/windows, IR camera lenses and multispectral optics. In short: standard CO2 laser optic; low 10.6 µm absorption; brittle, selenium-bearing dust.

What is the tensile strength of ZnSe CVD-MS?

ZnSe CVD-MS has a typical tensile strength of 48 MPa (6.96 ksi) — stronger than 51% of glass grades. Strength varies by condition: see the 2 listed tempers.

Is ZnSe CVD-MS easy to machine?

Reasonably — machinability is rated fair (45/100, better than 85% of glass grades). Grind/core with diamond tooling under flood coolant or single-point diamond turn with light depth of cut; brittle and prone to edge chipping, and all dust/swarf is toxic (Se) so wet cutting with sealed extraction is mandatory.

Can ZnSe CVD-MS be welded?

Not weldable — a brittle ceramic; join only by optical contacting, epoxy bonding or mechanical mounting in compliant (RTV/retaining-ring) cells to avoid mount stress.

What surface finishes work on ZnSe CVD-MS?

Pitch or polyurethane polish to <10 Å rms, then AR coat (ThF₄/YbF₃ or ZnS/YF₃ stacks) or DLC-protect the exposed face; keep bare surfaces dry and handle with gloves — hygroscopic-free but easily scratched.

Can ZnSe CVD-MS be formed, bent or molded?

Formed to net shape by CVD deposition on mandrels, then HIP for multispectral grade; no plastic forming is possible, curved optics are generated and polished from blanks.

What is the maximum service temperature of ZnSe CVD-MS?

ZnSe CVD-MS is rated for continuous use to about 250°C (482 °F). Strength falls off well before that limit — check the elevated-temperature data for load-bearing parts.

Sources

  1. CVD ZnSe optical material datasheet — II-VI / Coherent (2022)
  2. Cleartran multispectral ZnSe properties — Dow / II-VI (2019)
  3. Handbook of Optical Constants of Solids — Academic Press (Palik, ed.) (1998)
  4. Handbook of Optical Materials — CRC Press (Weber) (2003)
  5. IR window and lens material property tables — Thorlabs / Edmund Optics technical notes (2023)

Property data is compiled from published supplier and standards handbooks and normalised for comparison. Nothing on this page is a certification — request mill certs, CoC or material test reports with your order.