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ZnS HP (Hot-pressed ZnS)

Other

also Cleartran, Irtran-2

Legacy/low-cost route for small IR windows and lenses where fine grain size gives good hardness but visible scatter and slightly lower LWIR transmission are acceptable.

High cost $$$$

Values for the HP condition

What is ZnS HP?

ZnS HP is ZnS in the HP condition — legacy/low-cost route for small IR windows and lenses where fine grain size gives good hardness but visible scatter and slightly lower LWIR transmission are acceptable. The elastic modulus is 87.6 GPa (12.7 Msi). ZnS HP has a density of 4.08 g/cm³ (0.147 lb/in³), heavier than 73% of glass grades. It melts at 1,830°C (3,326 °F).

Advantages

  • Conducts heat well — 27.2 W/m·K (15.7 BTU/hr·ft·°F), better than 90% of glass grades
  • Tough — resists crack growth — 1 MPa·√m (0.91 ksi·√in), better than 87% of glass grades
  • Easy to machine — 45/100, better than 85% of glass grades

Limitations

  • High embodied carbon — 30 kg CO₂/kg, worse than 82% of glass grades

ZnS HP properties

Typical room-temperature values for ZnS HP; 9 are specific to this condition. Other listed values are ZnS reference data and may not represent this condition. Bars are the position among glass grades.

Physical5

ZnS HP has a density of 4.08 g/cm³ (0.147 lb/in³), heavier than 73% of glass grades. It melts at 1,830°C (3,326 °F).

Density4.08 g/cm³0.15 lb/in³
Melting Point (Solidus)1,830°C3,326 °F
Refractive Index2.2
Light Transmission68%
Porosity0.1%

Mechanical10

The elastic modulus is 87.6 GPa (12.7 Msi).

Elastic (Young's) Modulus87.6 GPa12.7 Msi
Shear Modulus30.3 GPa4.4 Msi
Bulk Modulus45 GPa6.5 Msi
Poisson's Ratio0.29
Compressive Strength620 MPa89.9 ksi
Flexural Strength95 MPa13.8 ksi
Fracture Toughness (K_IC)1 MPa·√m0.91 ksi·√in
Hardness, Vickers200 HV
Hardness, Knoop230 HK
Hardness, Mohs3.8

Thermal5

ZnS HP is rated for continuous service to 350°C (662 °F). It conducts heat at 27.2 W/m·K (15.7 BTU/hr·ft·°F), better than 90% of glass grades. Thermal expansion is 6.6 µm/m·K (3.67 µin/in·°F).

Thermal Conductivity27.2 W/m·K15.7 BTU/hr·ft·°F
Specific Heat Capacity469 J/kg·K0.11 BTU/lb·°F
Thermal Expansion (CTE, 20–100 °C)6.6 µm/m·K3.7 µin/in·°F
Max Service Temperature (continuous)350°C662 °F
Min Service Temperature-200°C-328 °F

Electrical3

ZnS HP has an electrical resistivity of 1×10¹⁰ Ω·m.

Electrical Resistivity1×10¹⁰ Ω·m3.94×10¹⁷ µΩ·in
Dielectric Constant (1 MHz)8.35
Volume Resistivity1×10¹² Ω·cm

Chemical & Environmental2

Corrosion resistance is good (55/100), worse than 74% of glass grades.

Corrosion ResistanceGood55/100
Chemical Resistance SummaryEssentially insoluble in water (~0.0007 g/100 g) and stable to weak alkalis and most solvents; dissolves in mineral acids evolving toxic H2S, is attacked by strong oxidizers, and oxidises to ZnO/SO2 in air above about 300 °C.

Sustainability4

Producing a kilogram of ZnS HP takes about 450 MJ of energy and emits 30 kg of CO₂ — more than 84% of glass grades. Typical recycled content is 0%.

Embodied Energy (primary production)450 MJ/kg193,465 BTU/lb
Embodied Carbon (primary production)30 kg CO₂/kg
Embodied Water600 L/kg71.9 gal/lb
Typical Recycled Content0%

Manufacturability3

ZnS HP's machinability is fair (45/100, better than 85% of glass grades).

MachinabilityFair45/100
PolishabilityVery good80/100
Sintering / Firing Temperature950°C1,742 °F

Values are nominal handbook figures for design screening. Confirm any required mill or lot documentation when quoting.

Working with ZnS HP

Is ZnS easy to machine?

Soft and brittle — grind and lap with diamond, or single-point diamond turn to optical figure; use light loads and wet cutting to avoid chipping and to control toxic ZnS dust.

Can ZnS be welded?

Not weldable; joined only by optical contacting, epoxy/edge bonding or metal-to-glass style mounting in compliant retainers.

Can ZnS be formed, bent or molded?

Net shape is set by CVD deposition onto a mandrel (flat plates or domes), optionally followed by HIP for the multispectral grade; no plastic forming is possible.

What surface finishes work on ZnS?

Polishes to <20 Å rms with pitch/colloidal silica but scratches easily — almost always finished with AR/DLC or hard carbon coatings for durability and to cut the ~28 % Fresnel loss.

ZnS chemical composition (wt %)

Limits by weight percent from the governing specification, written the way the spec states them — a single maximum for impurities, a range for alloying elements, and the base element as balance. Nominal is the typical mid-range value.

ElementSpec limit (wt %)Nominal
Znstoichiometric ZnS66.8 – 67.567.1
S≥ 32.5 (balance)—

ZnS HP — frequently asked

What is ZnS HP used for?

ZnS HP is typically used for IR domes and windows, multispectral optics, missile seeker domes and thermal imaging. In short: rugged multispectral IR window; visible through far-IR transmission; tougher, cheaper than ZnSe.

Is ZnS HP easy to machine?

Reasonably — machinability is rated fair (45/100, better than 85% of glass grades). Soft and brittle — grind and lap with diamond, or single-point diamond turn to optical figure; use light loads and wet cutting to avoid chipping and to control toxic ZnS dust.

Can ZnS HP be welded?

Not weldable; joined only by optical contacting, epoxy/edge bonding or metal-to-glass style mounting in compliant retainers.

What surface finishes work on ZnS HP?

Polishes to <20 Å rms with pitch/colloidal silica but scratches easily — almost always finished with AR/DLC or hard carbon coatings for durability and to cut the ~28 % Fresnel loss.

Can ZnS HP be formed, bent or molded?

Net shape is set by CVD deposition onto a mandrel (flat plates or domes), optionally followed by HIP for the multispectral grade; no plastic forming is possible.

What is the maximum service temperature of ZnS HP?

ZnS HP is rated for continuous use to about 350°C (662 °F). Strength falls off well before that limit — check the elevated-temperature data for load-bearing parts.

Sources

  1. CVD Zinc Sulfide and Multispectral ZnS optical material data — II-VI / Coherent (2022)
  2. Cleartran multispectral zinc sulfide — Dow / Rohm and Haas Advanced Materials (2008)
  3. Engineered Materials Handbook Vol.4: Ceramics and Glasses — ASM International (1991)
  4. Handbook of Optical Constants of Solids — Academic Press (1998)

Property data is compiled from published supplier and standards handbooks and normalised for comparison. Nothing on this page is a certification — request mill certs, CoC or material test reports with your order.