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Sapphire C-Plane

Grade

also Sapphire Window, C-Plane Sapphire

Standard orientation for GaN/LED epitaxy and for maximum surface hardness and isotropic in-plane CTE.

Standard cost $$

Values for the C-Plane condition

Other Sapphire tempers and conditions

Sapphire is listed in 4 conditions; see the grade overview at Sapphire.

Compare all 4 conditionsHide
Condition · open for datasheetBest forYield MPaTensile MPaElong. %HardnessConductivity
r-plane oriented wafer
Used for silicon-on-sapphire and a-plane GaN growth; intermediate anisotropy between C- and A-plane.—36001,900 HV31 W/m·K
a-axis oriented wafer
Chosen for hybrid microelectronic/SOS substrates and optics needing the c-axis in the plane of the plate.—37001,950 HV30 W/m·K
as-grown / annealed optical sapphire (random or C-plane blank)
Default choice for windows, lenses and wear parts: stress-relief annealed sapphire blank with typical polycrystal-free optical quality.—40002,000 HV27 W/m·K
C-PlaneThis page
basal-plane oriented wafer/window
Standard orientation for GaN/LED epitaxy and for maximum surface hardness and isotropic in-plane CTE.—47002,100 HV33 W/m·K

What is Sapphire C-Plane?

Sapphire C-Plane is Sapphire in the C-Plane grade — standard orientation for GaN/LED epitaxy and for maximum surface hardness and isotropic in-plane CTE. Sapphire C-Plane has a tensile strength of 470 MPa (68.2 ksi), stronger than 96% of glass grades. Elongation at break is 0% and the elastic modulus is 435 GPa (63.1 Msi). Sapphire C-Plane has a density of 3.98 g/cm³ (0.144 lb/in³), heavier than 71% of glass grades. It melts at 2,053°C (3,727 °F). Annealed Glass is the default condition FabDigit quotes; C-Plane is available on request or by drawing note.

Advantages

  • Polishes to a fine finish — 100/100, better than 102% of glass grades
  • High service temperature — 1,800°C (3,272 °F), better than 100% of glass grades
  • Stiff — 435 GPa (63.1 Msi), better than 98% of glass grades
  • Tough — resists crack growth — 2.5 MPa·√m (2.28 ksi·√in), better than 98% of glass grades
  • Conducts heat well — 33 W/m·K (19.1 BTU/hr·ft·°F), better than 92% of glass grades

Limitations

  • Difficult to machine — 4/100, worse than 95% of glass grades
  • High embodied carbon — 60 kg CO₂/kg, worse than 87% of glass grades

Sapphire C-Plane properties

Typical room-temperature values for Sapphire C-Plane; 16 are specific to this condition. Other listed values are Sapphire reference data and may not represent this condition. Bars are the position among glass grades.

Physical5

Sapphire C-Plane has a density of 3.98 g/cm³ (0.144 lb/in³), heavier than 71% of glass grades. It melts at 2,053°C (3,727 °F).

Density3.98 g/cm³0.14 lb/in³
Melting Point (Solidus)2,053°C3,727 °F
Refractive Index1.768
Light Transmission85%
Porosity0%

Mechanical13

Sapphire C-Plane has a tensile strength of 470 MPa (68.2 ksi), stronger than 96% of glass grades. Elongation at break is 0% and the elastic modulus is 435 GPa (63.1 Msi).

Elastic (Young's) Modulus435 GPa63.1 Msi
Shear Modulus148 GPa21.5 Msi
Bulk Modulus250 GPa36.3 Msi
Poisson's Ratio0.27
Tensile Strength (Ultimate)470 MPa68.2 ksi
Elongation at Break0%
Compressive Strength2,100 MPa305 ksi
Flexural Strength900 MPa131 ksi
Shear Strength400 MPa58 ksi
Fracture Toughness (K_IC)2.5 MPa·√m2.3 ksi·√in
Hardness, Vickers2,100 HV
Hardness, Knoop2,000 HK
Hardness, Mohs9

Thermal5

Sapphire C-Plane is rated for continuous service to 1,800°C (3,272 °F). It conducts heat at 33 W/m·K (19.1 BTU/hr·ft·°F), better than 92% of glass grades. Thermal expansion is 5 µm/m·K (2.78 µin/in·°F).

Thermal Conductivity33 W/m·K19.1 BTU/hr·ft·°F
Specific Heat Capacity761 J/kg·K0.18 BTU/lb·°F
Thermal Expansion (CTE, 20–100 °C)5 µm/m·K2.8 µin/in·°F
Max Service Temperature (continuous)1,800°C3,272 °F
Min Service Temperature-269°C-452 °F

Electrical5

Sapphire C-Plane is an electrical insulator with a dielectric strength of 17 kV/mm (431.8 V/mil) and a resistivity of 1×10¹⁴ Ω·m.

Electrical Resistivity1×10¹⁴ Ω·m3.94×10²¹ µΩ·in
Dielectric Strength17 kV/mm432 V/mil
Dielectric Constant (1 MHz)9.4
Dissipation Factor (1 MHz)1×10⁻⁴
Volume Resistivity1×10¹⁶ Ω·cm

Chemical & Environmental2

Corrosion resistance is excellent (95/100), better than 92% of glass grades.

Corrosion ResistanceExcellent95/100
Chemical Resistance SummaryInert to water, most acids and organic solvents at RT; attacked slowly by hot concentrated H2SO4/H3PO4 and by molten alkalis, borates and HF above ~300 °C; reduced/etched by hydrogen and alkali vapours at very high temperature.

Sustainability4

Producing a kilogram of Sapphire C-Plane takes about 400 MJ of energy and emits 60 kg of CO₂ — more than 82% of glass grades. Typical recycled content is 5%.

Embodied Energy (primary production)400 MJ/kg171,969 BTU/lb
Embodied Carbon (primary production)60 kg CO₂/kg
Embodied Water250 L/kg30 gal/lb
Typical Recycled Content5%

Manufacturability2

Sapphire C-Plane's machinability is not recommended (4/100, worse than 95% of glass grades).

MachinabilityNot recommended4/100
PolishabilityExcellent100/100

Values are nominal handbook figures for design screening. Confirm any required mill or lot documentation when quoting.

Working with Sapphire C-Plane

Is Sapphire easy to machine?

No conventional cutting: use diamond wire/ID saw, diamond core drilling, creep-feed diamond grinding, laser or waterjet for rough shapes, then lap and CMP.

Can Sapphire be welded?

Not weldable; join by active-metal (Ti/Nb) brazing, diffusion bonding to Nb/Mo, or glass-frit/epoxy sealing with CTE-matched metals such as Kovar avoided in favour of Nb.

Can Sapphire be formed, bent or molded?

Shape is fixed at crystal growth (Kyropoulos, HEM, Czochralski, EFG for tubes/ribbon); no plastic forming below ~1000 °C, so near-net EFG growth is used for tubes and rods.

What surface finishes work on Sapphire?

Sub-nanometre Ra achievable by colloidal-silica CMP; AR/DLC coatings, ion-beam figuring for optics; avoid edge chipping with chamfers and keep tensile surface flaws minimal to realise full strength.

Sapphire chemical composition (wt %)

Limits by weight percent from the governing specification, written the way the spec states them — a single maximum for impurities, a range for alloying elements, and the base element as balance.

ElementSpec limit (wt %)
Alstoichiometric metal fraction≈ 52.9
Ostoichiometric oxygen fraction≈ 47.1
Al2O3single crystal α-Al2O3; typical impurities Si, Fe, Ti, Cr, Na each < 20 ppm≥ 99.99 (balance)

Sapphire C-Plane — frequently asked

What is Sapphire C-Plane used for?

Sapphire C-Plane is typically used for watch crystals, smartphone camera lens covers, barcode scanner and sensor windows, high-pressure and high-temperature sight glasses, IR domes and harsh-environment optics and semiconductor process chamber windows. In short: single-crystal optical sapphire.

What is the tensile strength of Sapphire C-Plane?

Sapphire C-Plane has a typical tensile strength of 470 MPa (68.2 ksi) — stronger than 96% of glass grades. Strength varies by condition: see the 4 listed tempers.

Is Sapphire C-Plane easy to machine?

Not especially — machinability is rated not recommended (4/100, worse than 95% of glass grades). No conventional cutting: use diamond wire/ID saw, diamond core drilling, creep-feed diamond grinding, laser or waterjet for rough shapes, then lap and CMP.

Can Sapphire C-Plane be welded?

Not weldable; join by active-metal (Ti/Nb) brazing, diffusion bonding to Nb/Mo, or glass-frit/epoxy sealing with CTE-matched metals such as Kovar avoided in favour of Nb.

What surface finishes work on Sapphire C-Plane?

Sub-nanometre Ra achievable by colloidal-silica CMP; AR/DLC coatings, ion-beam figuring for optics; avoid edge chipping with chamfers and keep tensile surface flaws minimal to realise full strength.

Can Sapphire C-Plane be formed, bent or molded?

Shape is fixed at crystal growth (Kyropoulos, HEM, Czochralski, EFG for tubes/ribbon); no plastic forming below ~1000 °C, so near-net EFG growth is used for tubes and rods.

What is the maximum service temperature of Sapphire C-Plane?

Sapphire C-Plane is rated for continuous use to about 1,800°C (3,272 °F). Strength falls off well before that limit — check the elevated-temperature data for load-bearing parts.

Sources

  1. Sapphire (Al2O3) optical material data — Crystran Ltd (2023)
  2. Single Crystal Sapphire product properties — Saint-Gobain Crystals (2022)
  3. Sapphire single crystal technical data — Kyocera Corporation (2022)
  4. Engineered Materials Handbook Vol.4: Ceramics and Glasses — ASM International (1991)
  5. Sapphire crystal properties and orientation data — Rubicon Technology / Monocrystal (2021)

Property data is compiled from published supplier and standards handbooks and normalised for comparison. Nothing on this page is a certification — request mill certs, CoC or material test reports with your order.