FabDigitFabDigit

Pyrolytic Graphite HOPG-ZYB

Grade

General-purpose HOPG: good crystalline quality for SPM calibration and electrochemistry at moderate cost.

High cost $$$$

Values for the HOPG-ZYB condition

Other Pyrolytic Graphite tempers and conditions

Pyrolytic Graphite is listed in 5 conditions; see the grade overview at Pyrolytic Graphite.

Compare all 5 conditionsHide
Condition · open for datasheetBest forYield MPaTensile MPaElong. %HardnessConductivity
HOPG-ZYBThis page
mosaic spread 0.8° ± 0.2°
General-purpose HOPG: good crystalline quality for SPM calibration and electrochemistry at moderate cost.—350.158 HV1,600 W/m·K
mosaic spread 0.4° ± 0.1°
Highest-perfection HOPG for X-ray/neutron monochromators and reference-flat AFM/STM substrates; smallest pieces, highest price.—40——1,800 W/m·K
mosaic spread 3.5° ± 1.5°
Economy HOPG grade for routine STM/AFM substrates, electrode blanks and teaching use where mosaic spread is uncritical.—500.212 HV1,200 W/m·K
APG / TPG
Pick when maximum in-plane thermal conductivity (>1200 W/m·K) is needed for encapsulated heat spreaders and satellite thermal doublers.—80——1,500 W/m·K
PGDefault
As-deposited pyrolytic graphite
Standard CVD plate/tube stock: impermeable, moderate in-plane conductivity, best strength-to-cost of the PG family.—100——300 W/m·K

What is Pyrolytic Graphite HOPG-ZYB?

Pyrolytic Graphite HOPG-ZYB is Pyrolytic Graphite in the HOPG-ZYB grade — general-purpose HOPG: good crystalline quality for SPM calibration and electrochemistry at moderate cost. Pyrolytic Graphite HOPG-ZYB has a tensile strength of 35 MPa (5.08 ksi), weaker than 71% of ceramic grades. Elongation at break is 0.15% and the elastic modulus is 800 GPa (116 Msi). Pyrolytic Graphite HOPG-ZYB has a density of 2.26 g/cm³ (0.0816 lb/in³), lighter than 85% of ceramic grades. It melts at 3,650°C (6,602 °F). PG is the default condition FabDigit quotes; HOPG-ZYB is available on request or by drawing note.

Advantages

  • Conducts heat well — 1,600 W/m·K (924.5 BTU/hr·ft·°F), better than 101% of ceramic grades
  • Stiff — 800 GPa (116 Msi), better than 99% of ceramic grades
  • Polishes to a fine finish — 92/100, better than 89% of ceramic grades
  • Lightweight — 2.26 g/cm³ (0.0816 lb/in³), better than 85% of ceramic grades
  • Easy to machine — 25/100, better than 84% of ceramic grades

Limitations

  • Low fracture toughness — 0.6 MPa·√m (0.546 ksi·√in), worse than 100% of ceramic grades
  • High embodied carbon — 25 kg CO₂/kg, worse than 78% of ceramic grades
  • Limited service temperature — 450°C (842 °F), worse than 77% of ceramic grades

Pyrolytic Graphite HOPG-ZYB properties

Typical room-temperature values for Pyrolytic Graphite HOPG-ZYB; 15 are specific to this condition. Other listed values are Pyrolytic Graphite reference data and may not represent this condition. Bars are the position among ceramic grades.

Physical3

Pyrolytic Graphite HOPG-ZYB has a density of 2.26 g/cm³ (0.0816 lb/in³), lighter than 85% of ceramic grades. It melts at 3,650°C (6,602 °F).

Density2.26 g/cm³0.08 lb/in³
Melting Point (Solidus)3,650°C6,602 °F
Porosity0.5%

Mechanical11

Pyrolytic Graphite HOPG-ZYB has a tensile strength of 35 MPa (5.08 ksi), weaker than 71% of ceramic grades. Elongation at break is 0.15% and the elastic modulus is 800 GPa (116 Msi).

Elastic (Young's) Modulus800 GPa116 Msi
Shear Modulus4.5 GPa0.65 Msi
Bulk Modulus34 GPa4.9 Msi
Poisson's Ratio0.17
Tensile Strength (Ultimate)35 MPa5.1 ksi
Elongation at Break0.15%
Compressive Strength80 MPa11.6 ksi
Flexural Strength45 MPa6.5 ksi
Shear Strength0.5 MPa0.07 ksi
Fracture Toughness (K_IC)0.6 MPa·√m0.55 ksi·√in
Hardness, Mohs1

Thermal5

Pyrolytic Graphite HOPG-ZYB is rated for continuous service to 450°C (842 °F). It conducts heat at 1,600 W/m·K (924.5 BTU/hr·ft·°F), better than 101% of ceramic grades. Thermal expansion is 1 µm/m·K (0.556 µin/in·°F).

Thermal Conductivity1,600 W/m·K924 BTU/hr·ft·°F
Specific Heat Capacity710 J/kg·K0.17 BTU/lb·°F
Thermal Expansion (CTE, 20–100 °C)1 µm/m·K0.56 µin/in·°F
Max Service Temperature (continuous)450°C842 °F
Min Service Temperature-269°C-452 °F

Electrical2

Pyrolytic Graphite HOPG-ZYB has an electrical resistivity of 4.5×10⁻⁷ Ω·m.

Electrical Resistivity4.5×10⁻⁷ Ω·m17.7 µΩ·in
Volume Resistivity5×10⁻⁴ Ω·cm

Chemical & Environmental2

Corrosion resistance is excellent (88/100), better than 77% of ceramic grades.

Corrosion ResistanceExcellent88/100
Chemical Resistance SummaryInert to nearly all acids, alkalis and organic solvents at room temperature; attacked by strong oxidisers (hot HNO3, chromic acid, molten alkali/nitrates), oxidises in air above ~450 °C and reacts with carbide-forming metals (Ti, Zr, Fe) at high temperature.

Sustainability3

Producing a kilogram of Pyrolytic Graphite HOPG-ZYB takes about 350 MJ of energy and emits 25 kg of CO₂ — more than 81% of ceramic grades. Typical recycled content is 0%.

Embodied Energy (primary production)350 MJ/kg150,473 BTU/lb
Embodied Carbon (primary production)25 kg CO₂/kg
Typical Recycled Content0%

Manufacturability3

Pyrolytic Graphite HOPG-ZYB's machinability is poor (25/100, better than 84% of ceramic grades).

MachinabilityPoor25/100
PolishabilityExcellent92/100
Sintering / Firing Temperature2,100°C3,812 °F

Values are nominal handbook figures for design screening. Confirm any required mill or lot documentation when quoting.

Working with Pyrolytic Graphite HOPG-ZYB

Is Pyrolytic Graphite easy to machine?

Cuts and grinds easily with carbide/diamond tools dry, but must be supported and fed lightly to avoid basal-plane delamination; EDM and laser cutting also used; capture the conductive dust.

Can Pyrolytic Graphite be welded?

Not weldable — joined by graphite cement, brazing with active (Ti/Cr) filler metals, or mechanical clamping / metal encapsulation for APG heat spreaders.

Can Pyrolytic Graphite be formed, bent or molded?

Net shape is set by CVD onto a mandrel (tubes, crucibles, plates); no plastic forming, and thick deposits must be annealed under pressure to reach APG/HOPG texture.

What surface finishes work on Pyrolytic Graphite?

Basal surfaces are refreshed by adhesive-tape cleaving rather than polishing; CVD SiC/pyrolytic-carbon or metal (Ni, Cu) coatings are applied for oxidation protection and solderability.

Pyrolytic Graphite chemical composition (wt %)

Limits by weight percent from the governing specification, written the way the spec states them — a single maximum for impurities, a range for alloying elements, and the base element as balance. Nominal is the typical mid-range value.

ElementSpec limit (wt %)Nominal
ashtotal metallic impurities, typically <20 ppm0 – 0.010
CCVD-deposited carbon; HOPG grades typically >99.99 %≥ 99.9 (balance)—

Pyrolytic Graphite HOPG-ZYB — frequently asked

What is Pyrolytic Graphite HOPG-ZYB used for?

Pyrolytic Graphite HOPG-ZYB is typically used for heat spreaders, susceptors for CVD/MOCVD, X-ray monochromators and aerospace thermal insulation. In short: highest in-plane conductivity; densest graphite form; strongly anisotropic properties.

What is the tensile strength of Pyrolytic Graphite HOPG-ZYB?

Pyrolytic Graphite HOPG-ZYB has a typical tensile strength of 35 MPa (5.08 ksi) — weaker than 71% of ceramic grades. Strength varies by condition: see the 5 listed tempers.

Is Pyrolytic Graphite HOPG-ZYB easy to machine?

Not especially — machinability is rated poor (25/100, better than 84% of ceramic grades). Cuts and grinds easily with carbide/diamond tools dry, but must be supported and fed lightly to avoid basal-plane delamination; EDM and laser cutting also used; capture the conductive dust.

Can Pyrolytic Graphite HOPG-ZYB be welded?

Not weldable — joined by graphite cement, brazing with active (Ti/Cr) filler metals, or mechanical clamping / metal encapsulation for APG heat spreaders.

What surface finishes work on Pyrolytic Graphite HOPG-ZYB?

Basal surfaces are refreshed by adhesive-tape cleaving rather than polishing; CVD SiC/pyrolytic-carbon or metal (Ni, Cu) coatings are applied for oxidation protection and solderability.

Can Pyrolytic Graphite HOPG-ZYB be formed, bent or molded?

Net shape is set by CVD onto a mandrel (tubes, crucibles, plates); no plastic forming, and thick deposits must be annealed under pressure to reach APG/HOPG texture.

What is the maximum service temperature of Pyrolytic Graphite HOPG-ZYB?

Pyrolytic Graphite HOPG-ZYB is rated for continuous use to about 450°C (842 °F). Strength falls off well before that limit — check the elevated-temperature data for load-bearing parts.

Sources

  1. ASM Engineered Materials Handbook Vol. 4: Ceramics and Glasses — Carbon and Graphite — ASM International (1991)
  2. Pyroid HT / Pyroid TC pyrolytic graphite property data — Minteq International (Pyrogenics Group) (2020)
  3. TC1050 Thermal Pyrolytic Graphite (TPG) datasheet — Momentive Technologies (2021)
  4. HOPG grades ZYA / ZYB / ZYH specification sheet — SPI Supplies / NT-MDT (2022)
  5. Graphite single-crystal and pyrolytic graphite property tables — CRC Handbook of Chemistry and Physics (2023)

Property data is compiled from published supplier and standards handbooks and normalised for comparison. Nothing on this page is a certification — request mill certs, CoC or material test reports with your order.