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Refractory Metal Zr 706-STA (Solution treated and aged)

Heat-treated state

UNS R60706 · ASTM B550/B551 Grade 706

Special-order high-strength condition for fasteners and small structural parts; corrosion resistance and toughness drop and it is rarely used for pressure vessels.

High cost $$$$

Values for the STA condition

Other Zr 706 tempers and conditions

Zr 706 is listed in 4 conditions; see the grade overview at Zr 706.

Compare all 4 conditionsHide
Condition · open for datasheetBest forYield MPaTensile MPaElong. %HardnessConductivity
Hot worked / as-forged
Economical condition for heavy forged bar, flanges and valve bodies where a full anneal is not specified.39054521176 HB3.1 % IACS
AnnealedDefault
recrystallization annealed (ASTM B550/B551/B523 standard condition)
Default stocked condition for plate, sheet, bar and tube; best ductility and formability with full corrosion resistance.40055024180 HB—
Cold worked and stress relieved
Pick for tube and bar needing higher strength and stiffness-limited sections; ductility and formability are reduced.5506601496 HRB—
STAThis page
Solution treated and aged
Special-order high-strength condition for fasteners and small structural parts; corrosion resistance and toughness drop and it is rarely used for pressure vessels.7509001032 HRC—

What is Zr 706-STA?

Zr 706-STA is Zr 706 heat treated to STA — special-order high-strength condition for fasteners and small structural parts; corrosion resistance and toughness drop and it is rarely used for pressure vessels. Zr 706-STA has a yield strength of 750 MPa (109 ksi) and a tensile strength of 900 MPa (131 ksi) — stronger than 88% of refractory metal grades. Elongation at break is 10% and the elastic modulus is 97 GPa (14.1 Msi). Zr 706-STA has a density of 6.64 g/cm³ (0.24 lb/in³), lighter than 63% of refractory metal grades. It melts at 1,840°C (3,344 °F). Annealed is the default condition FabDigit quotes; STA is available on request or by drawing note.

Advantages

  • High strength — 750 MPa (109 ksi), better than 88% of refractory metal grades

Limitations

  • Low stiffness — 97 GPa (14.1 Msi), worse than 91% of refractory metal grades
  • Limited formability — 15/100, worse than 80% of refractory metal grades
  • Low electrical conductivity — 3.1 % IACS, worse than 78% of refractory metal grades
  • Poor heat conductor — 17.1 W/m·K (9.88 BTU/hr·ft·°F), worse than 76% of refractory metal grades

Zr 706-STA properties

Typical room-temperature values for Zr 706-STA; 10 are specific to this condition. Other listed values are Zr 706 reference data and may not represent this condition. Bars are the position among refractory metal grades.

Physical3

Zr 706-STA has a density of 6.64 g/cm³ (0.24 lb/in³), lighter than 63% of refractory metal grades. It melts at 1,840°C (3,344 °F).

Density6.64 g/cm³0.24 lb/in³
Melting Point (Solidus)1,840°C3,344 °F
Liquidus Temperature1,860°C3,380 °F

Mechanical16

Zr 706-STA has a yield strength of 750 MPa (109 ksi) and a tensile strength of 900 MPa (131 ksi) — stronger than 88% of refractory metal grades. Elongation at break is 10% and the elastic modulus is 97 GPa (14.1 Msi).

Elastic (Young's) Modulus97 GPa14.1 Msi
Shear Modulus36 GPa5.2 Msi
Bulk Modulus92 GPa13.3 Msi
Poisson's Ratio0.35
Tensile Strength (Ultimate)900 MPa131 ksi
Yield Strength (0.2% offset)750 MPa109 ksi
Elongation at Break10%
Reduction in Area40%
Compressive Strength420 MPa60.9 ksi
Shear Strength330 MPa47.9 ksi
Fatigue Strength (Endurance Limit)250 MPa36.3 ksi
Fracture Toughness (K_IC)60 MPa·√m54.6 ksi·√in
Charpy V-Notch Impact (RT)15 J11.1 ft·lbf
Hardness, Brinell180 HB
Hardness, Rockwell B88 HRB
Hardness, Vickers320 HV

Thermal6

Zr 706-STA is rated for continuous service to 400°C (752 °F). It conducts heat at 17.1 W/m·K (9.88 BTU/hr·ft·°F), worse than 76% of refractory metal grades. Thermal expansion is 6 µm/m·K (3.33 µin/in·°F).

Thermal Conductivity17.1 W/m·K9.9 BTU/hr·ft·°F
Specific Heat Capacity281 J/kg·K0.07 BTU/lb·°F
Thermal Expansion (CTE, 20–100 °C)6 µm/m·K3.3 µin/in·°F
Latent Heat of Fusion155 J/g66.6 BTU/lb
Max Service Temperature (continuous)400°C752 °F
Min Service Temperature-196°C-321 °F

Electrical3

Zr 706-STA conducts electricity at 3.1 % IACS, worse than 78% of refractory metal grades.

Electrical Conductivity3.1 % IACS
Electrical Resistivity5.5×10⁻⁷ Ω·m21.7 µΩ·in
Magnetic Responsenon-magnetic

Chemical & Environmental3

Corrosion resistance is very good (82/100), worse than 54% of refractory metal grades.

Galvanic Potential (seawater, vs SCE)-0.15 V
Corrosion ResistanceVery good82/100
Chemical Resistance SummaryOutstanding in HCl (all concentrations up to boiling), H2SO4 to ~70%, HNO3, phosphoric acid, caustics and most chloride/organic media; attacked by HF and fluorides, ferric and cupric chloride, wet chlorine, aqua regia and concentrated H2SO4 >~75%. Fine chips/powder are pyrophoric.

Sustainability4

Producing a kilogram of Zr 706-STA takes about 1,300 MJ of energy and emits 78 kg of CO₂ — more than 57% of refractory metal grades. Typical recycled content is 20%.

Embodied Energy (primary production)1,300 MJ/kg558,900 BTU/lb
Embodied Carbon (primary production)78 kg CO₂/kg
Embodied Water500 L/kg59.9 gal/lb
Typical Recycled Content20%

Manufacturability8

Zr 706-STA's machinability is poor (30/100, better than 54% of refractory metal grades); weldability fair (45/100); formability poor (15/100).

MachinabilityPoor30/100
Machinability Rating (AISI 1212 = 100 %)40%
WeldabilityFair45/100
Formability (cold)Poor15/100
CastabilityPoor25/100
Brazeability / SolderabilityPoor20/100
PolishabilityGood65/100
Anodizing Responsefair — anodic oxide can be grown for colour/ID or as an anti-galling film, but it is thin and not a load-bearing wear coating

Values are nominal handbook figures for design screening. Confirm any required mill or lot documentation when quoting.

Working with Zr 706-STA

Is Zr 706 easy to machine?

Machine like a gummy austenitic stainless — sharp carbide tools, heavy positive rake, slow speed with high feed and flood coolant; never let fine chips accumulate dry (pyrophoric).

Can Zr 706 be welded?

GTAW/plasma or EB with high-purity argon/helium plus trailing shields or a chamber; keep the weld and HAZ below ~200 ppm oxygen pickup and expect bright silver, not straw or blue, welds.

Can Zr 706 be formed, bent or molded?

The low-oxygen 706 chemistry cold-bends and dishes well with generous radii (≥3t) and slow ram speeds; hot form 700–800 °C in inert conditions and pickle scale in HNO3-HF afterwards.

What surface finishes work on Zr 706?

Mechanically polish or abrasive-blast then pickle/passivate for a stable oxide; anodic colouring is possible, and avoid embedding iron from steel tooling to prevent rust staining and localized attack.

Zr 706 chemical composition (wt %)

Limits by weight percent from the governing specification, written the way the spec states them — a single maximum for impurities, a range for alloying elements, and the base element as balance. Nominal is the typical mid-range value.

ElementSpec limit (wt %)Nominal
Nbcolumbium (niobium)2 – 32.5
Hfhafnium not removed (industrial, non-nuclear grade)≤ 4.52
Fe+Cr≤ 0.20.1
Otighter than Zr 705 (0.18 max) — source of the higher ductility≤ 0.160.11
C≤ 0.050.02
N≤ 0.030.01
H≤ 0.010
Zr+HfZr+Hf minimum per ASTM B550/B551≥ 95.5 (balance)—

Zr 706-STA — frequently asked

What is Zr 706-STA used for?

Zr 706-STA is typically used for critical chemical process components, corrosion-resistant reactor internals and specialty piping. In short: formable Nb zirconium; tighter-chemistry Zr 705; weldable high-strength Zr.

What is the yield strength of Zr 706-STA?

Zr 706-STA has a typical yield strength of 750 MPa (109 ksi) and a tensile strength of 900 MPa (131 ksi) — stronger than 88% of refractory metal grades. Strength varies by condition: see the 4 listed tempers.

Is Zr 706-STA easy to machine?

Not especially — machinability is rated poor (30/100, better than 54% of refractory metal grades). Machine like a gummy austenitic stainless — sharp carbide tools, heavy positive rake, slow speed with high feed and flood coolant; never let fine chips accumulate dry (pyrophoric).

Can Zr 706-STA be welded?

With care — weldability is rated fair (45/100). GTAW/plasma or EB with high-purity argon/helium plus trailing shields or a chamber; keep the weld and HAZ below ~200 ppm oxygen pickup and expect bright silver, not straw or blue, welds.

What surface finishes work on Zr 706-STA?

Mechanically polish or abrasive-blast then pickle/passivate for a stable oxide; anodic colouring is possible, and avoid embedding iron from steel tooling to prevent rust staining and localized attack.

Can Zr 706-STA be formed, bent or molded?

The low-oxygen 706 chemistry cold-bends and dishes well with generous radii (≥3t) and slow ram speeds; hot form 700–800 °C in inert conditions and pickle scale in HNO3-HF afterwards.

What is the maximum service temperature of Zr 706-STA?

Zr 706-STA is rated for continuous use to about 400°C (752 °F). Strength falls off well before that limit — check the elevated-temperature data for load-bearing parts.

What is the difference between Zr 706 Annealed and Zr 706-STA?

Annealed is the default condition — default stocked condition for plate, sheet, bar and tube; best ductility and formability with full corrosion resistance. STA: special-order high-strength condition for fasteners and small structural parts; corrosion resistance and toughness drop and it is rarely used for pressure vessels. Yield strength is 400 MPa in Annealed versus 750 MPa in STA.

Sources

  1. ASTM B550/B550M — Zirconium and Zirconium Alloy Bar and Wire — ASTM International (2020)
  2. ASTM B551/B551M — Zirconium and Zirconium Alloy Strip, Sheet and Plate — ASTM International (2019)
  3. ASTM B523/B658 — Zirconium and Zirconium Alloy Seamless and Welded Tube/Pipe — ASTM International (2020)
  4. ASM Handbook Vol. 2 — Properties of Nonferrous Alloys (Zirconium and Hafnium) — ASM International (1990)
  5. Zirconium alloy 702/705 industrial grade property sheets — ATI / Wah Chang (2015)
  6. Corrosion of Zirconium and Zirconium Alloys (ASM Corrosion Handbook Vol. 13B) — ASM International (2005)

Property data is compiled from published supplier and standards handbooks and normalised for comparison. Nothing on this page is a certification — request mill certs, CoC or material test reports with your order.