FabDigitFabDigit

Refractory Metal R04261-CW (Cold worked)

Supply condition

UNS R04261 · ASTM B393 Type 4

Highest room-temperature strength and hardness for wire, thin strip and springs, but limited formability and it recrystallizes above ~1100 °C.

High cost $$$$

Values for the CW condition

Other R04261 tempers and conditions

R04261 is listed in 4 conditions; see the grade overview at R04261.

Compare all 4 conditionsHide
Condition · open for datasheetBest forYield MPaTensile MPaElong. %HardnessConductivity
AnnealedDefault
vacuum recrystallization annealed (ASTM B393/B392 annealed condition)
Standard stocked condition for sheet, plate, bar and tube — maximum ductility for forming, welding and deep drawing.20031025105 HB41 W/m·K
Hot worked / as-forged bar and billet
Mill condition for heavy bar, forgings and machining stock where a final anneal is not required.26038020124 HB8.4 % IACS
Stress relieved
Choose when moderate strength must be combined with dimensional stability after cold forming or machining.34042015143 HB8.4 % IACS
CWThis page
Cold worked
Highest room-temperature strength and hardness for wire, thin strip and springs, but limited formability and it recrystallizes above ~1100 °C.5005608185 HB—

What is R04261-CW?

R04261-CW is R04261 supplied in the CW condition — highest room-temperature strength and hardness for wire, thin strip and springs, but limited formability and it recrystallizes above ~1100 °C. R04261-CW has a yield strength of 500 MPa (72.5 ksi) and a tensile strength of 560 MPa (81.2 ksi) — stronger than 75% of refractory metal grades. Elongation at break is 8% and the elastic modulus is 103 GPa (14.9 Msi). R04261-CW has a density of 8.57 g/cm³ (0.31 lb/in³), heavier than 51% of refractory metal grades. It melts at 2,410°C (4,370 °F). Annealed is the default condition FabDigit quotes; CW is available on request or by drawing note.

Advantages

  • Easy to machine — 42/100, better than 97% of refractory metal grades
  • Readily welded — 80/100, better than 92% of refractory metal grades
  • High strength — 500 MPa (72.5 ksi), better than 75% of refractory metal grades

Limitations

  • Limited ductility — 8%, worse than 75% of refractory metal grades

R04261-CW properties

Typical room-temperature values for R04261-CW; 12 are specific to this condition. Other listed values are R04261 reference data and may not represent this condition. Bars are the position among refractory metal grades.

Physical3

R04261-CW has a density of 8.57 g/cm³ (0.31 lb/in³), heavier than 51% of refractory metal grades. It melts at 2,410°C (4,370 °F).

Density8.57 g/cm³0.31 lb/in³
Melting Point (Solidus)2,410°C4,370 °F
Liquidus Temperature2,460°C4,460 °F

Mechanical13

R04261-CW has a yield strength of 500 MPa (72.5 ksi) and a tensile strength of 560 MPa (81.2 ksi) — stronger than 75% of refractory metal grades. Elongation at break is 8% and the elastic modulus is 103 GPa (14.9 Msi).

Elastic (Young's) Modulus103 GPa14.9 Msi
Shear Modulus37.5 GPa5.4 Msi
Bulk Modulus170 GPa24.7 Msi
Poisson's Ratio0.4
Tensile Strength (Ultimate)560 MPa81.2 ksi
Yield Strength (0.2% offset)500 MPa72.5 ksi
Elongation at Break8%
Reduction in Area35%
Shear Strength330 MPa47.9 ksi
Fatigue Strength (Endurance Limit)150 MPa21.8 ksi
Hardness, Brinell185 HB
Hardness, Rockwell B92 HRB
Hardness, Vickers195 HV

Thermal6

R04261-CW is rated for continuous service to 800°C (1,472 °F). It conducts heat at 41 W/m·K (23.7 BTU/hr·ft·°F), worse than 53% of refractory metal grades. Thermal expansion is 7.1 µm/m·K (3.94 µin/in·°F).

Thermal Conductivity41 W/m·K23.7 BTU/hr·ft·°F
Specific Heat Capacity270 J/kg·K0.06 BTU/lb·°F
Thermal Expansion (CTE, 20–100 °C)7.1 µm/m·K3.9 µin/in·°F
Latent Heat of Fusion320 J/g138 BTU/lb
Max Service Temperature (continuous)800°C1,472 °F
Min Service Temperature-253°C-423 °F

Electrical3

R04261-CW conducts electricity at 8.6 % IACS, better than 58% of refractory metal grades.

Electrical Conductivity8.6 % IACS
Electrical Resistivity2×10⁻⁷ Ω·m7.87 µΩ·in
Magnetic Responsenon-magnetic (paramagnetic; pure Nb is superconducting below ~9 K, Zr addition lowers Tc slightly)

Chemical & Environmental3

Corrosion resistance is excellent (85/100), better than 52% of refractory metal grades.

Galvanic Potential (seawater, vs SCE)-0.05 V
Corrosion ResistanceExcellent85/100
Chemical Resistance SummaryExcellent in most mineral acids (HCl, H2SO4, HNO3, phosphoric), all concentrations of liquid alkali metals (Na, K, Li) and molten salts; attacked by HF, hot concentrated alkalis and oxidising fluorides; oxidises rapidly in air above ~400 °C and absorbs hydrogen above ~250 °C, causing embrittlement.

Sustainability4

Producing a kilogram of R04261-CW takes about 1,100 MJ of energy and emits 65 kg of CO₂ — less than 54% of refractory metal grades. Typical recycled content is 25%.

Embodied Energy (primary production)1,100 MJ/kg472,915 BTU/lb
Embodied Carbon (primary production)65 kg CO₂/kg
Embodied Water900 L/kg108 gal/lb
Typical Recycled Content25%

Manufacturability7

R04261-CW's machinability is fair (42/100, better than 97% of refractory metal grades); weldability very good (80/100); formability fair (40/100).

MachinabilityFair42/100
Machinability Rating (AISI 1212 = 100 %)30%
WeldabilityVery good80/100
Formability (cold)Fair40/100
Brazeability / SolderabilityGood60/100
PolishabilityGood60/100
Anodizing Responsegood — Nb anodises to a stable coloured Nb2O5 film (used for coloured biomedical/decorative parts); not a wear coating

Values are nominal handbook figures for design screening. Confirm any required mill or lot documentation when quoting.

Working with R04261-CW

Is R04261 easy to machine?

Gummy and galling-prone: use sharp high-positive-rake carbide or HSS tools, slow-to-moderate speeds, heavy feeds, chlorinated or flood coolant, and never let the tool dwell; degrease thoroughly before any high-temperature use.

Can R04261 be welded?

Excellent GTAW/EBW/laser weldability but only under high-purity argon trailing shield, glove box or vacuum — any O/N/H pickup above ~500 °C embrittles the weld; no filler needed for thin sections and no post-weld heat treatment other than vacuum stress relief.

Can R04261 be formed, bent or molded?

Very ductile cold: deep draws, spins, bends to tight radii at room temperature with lubricated tooling (avoid iron pickup); anneal 1100–1250 °C in vacuum between heavy reductions.

What surface finishes work on R04261?

Pickle in HNO3/HF mixtures to remove oxide (short exposure — HF attacks Nb), electropolish for high-purity or UHV surfaces, or anodise to a coloured Nb2O5 film; for service in air above ~400 °C an aluminide or silicide coating is mandatory.

R04261 chemical composition (wt %)

Limits by weight percent from the governing specification, written the way the spec states them — a single maximum for impurities, a range for alloying elements, and the base element as balance. Nominal is the typical mid-range value.

ElementSpec limit (wt %)Nominal
Zralloying addition; scavenges oxygen0.8 – 1.21
C≤ 0.01—
Omax; looser than reactor grade R04251≤ 0.03—
N≤ 0.01—
H≤ 0—
Fe≤ 0.01—
Ta≤ 0.1—
W≤ 0.05—
Mo≤ 0.02—
Hf≤ 0.02—
Ti≤ 0.03—
Si≤ 0.01—
Ni≤ 0.01—
Nbbalance; commercial grade per ASTM B391/B392/B393/B394 Type 4balance—

R04261-CW — frequently asked

What is R04261-CW used for?

R04261-CW is typically used for rocket nozzle liners, high-temperature furnace parts, chemical process equipment and vacuum tube components. In short: commercial Nb-1Zr workhorse; weldable and highly formable; hot service to 1200 °C.

What is the yield strength of R04261-CW?

R04261-CW has a typical yield strength of 500 MPa (72.5 ksi) and a tensile strength of 560 MPa (81.2 ksi) — stronger than 75% of refractory metal grades. Strength varies by condition: see the 4 listed tempers.

Is R04261-CW easy to machine?

Not especially — machinability is rated fair (42/100, better than 97% of refractory metal grades). Gummy and galling-prone: use sharp high-positive-rake carbide or HSS tools, slow-to-moderate speeds, heavy feeds, chlorinated or flood coolant, and never let the tool dwell; degrease thoroughly before any high-temperature use.

Can R04261-CW be welded?

Yes — weldability is rated very good (80/100). Excellent GTAW/EBW/laser weldability but only under high-purity argon trailing shield, glove box or vacuum — any O/N/H pickup above ~500 °C embrittles the weld; no filler needed for thin sections and no post-weld heat treatment other than vacuum stress relief.

What surface finishes work on R04261-CW?

Pickle in HNO3/HF mixtures to remove oxide (short exposure — HF attacks Nb), electropolish for high-purity or UHV surfaces, or anodise to a coloured Nb2O5 film; for service in air above ~400 °C an aluminide or silicide coating is mandatory.

Can R04261-CW be formed, bent or molded?

Very ductile cold: deep draws, spins, bends to tight radii at room temperature with lubricated tooling (avoid iron pickup); anneal 1100–1250 °C in vacuum between heavy reductions.

What is the maximum service temperature of R04261-CW?

R04261-CW is rated for continuous use to about 800°C (1,472 °F). Strength falls off well before that limit — check the elevated-temperature data for load-bearing parts.

What is the difference between R04261 Annealed and R04261-CW?

Annealed is the default condition — standard stocked condition for sheet, plate, bar and tube — maximum ductility for forming, welding and deep drawing. CW: highest room-temperature strength and hardness for wire, thin strip and springs, but limited formability and it recrystallizes above ~1100 °C. Yield strength is 200 MPa in Annealed versus 500 MPa in CW.

Sources

  1. ASTM B393 — Niobium and Niobium Alloy Strip, Sheet, and Plate (Type 4, R04261) — ASTM International (2018)
  2. ASTM B392 — Niobium and Niobium Alloy Bar, Rod, and Wire — ASTM International (2020)
  3. ASTM B391 — Niobium and Niobium Alloy Ingots — ASTM International (2018)
  4. ASTM B394 — Niobium and Niobium Alloy Seamless and Welded Tubes — ASTM International (2019)
  5. ASM Handbook Vol. 2 — Properties and Selection: Nonferrous Alloys and Special-Purpose Materials (refractory metals) — ASM International (1990)
  6. ASM Handbook Vol. 13B — Corrosion: Materials (niobium and tantalum) — ASM International (2005)
  7. Niobium and Nb-1Zr mill product datasheets — refractory-metal producers (e.g. H.C. Starck / Ningxia Orient Tantalum) (2022)

Property data is compiled from published supplier and standards handbooks and normalised for comparison. Nothing on this page is a certification — request mill certs, CoC or material test reports with your order.