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Refractory Metal R04251-SR (Stress relieved)

Heat-treated state

UNS R04251 · ASTM B393 Type 3

Pick when dimensional stability and moderate strength are wanted without full softening of cold-worked stock.

High cost $$$$

Values for the SR condition

Other R04251 tempers and conditions

R04251 is listed in 3 conditions; see the grade overview at R04251.

Compare all 3 conditionsHide
Condition · open for datasheetBest forYield MPaTensile MPaElong. %HardnessConductivity
AnnealedDefault
vacuum recrystallization annealed (ASTM B393 Type 3, annealed condition)
Standard stocked condition for forming, deep drawing, tube reducing and welded reactor/alkali-metal hardware.1402503058 HRB—
SRThis page
Stress relieved
Pick when dimensional stability and moderate strength are wanted without full softening of cold-worked stock.26034018133 HB8.3 % IACS
Cold worked
Choose for maximum room-temperature strength and springiness in foil, wire and thin strip that will not see recrystallization temperatures.470520792 HRB—

What is R04251-SR?

R04251-SR is R04251 heat treated to SR — pick when dimensional stability and moderate strength are wanted without full softening of cold-worked stock. R04251-SR has a yield strength of 260 MPa (37.7 ksi) and a tensile strength of 340 MPa (49.3 ksi) — weaker than 68% of refractory metal grades. Elongation at break is 18% and the elastic modulus is 100 GPa (14.5 Msi). R04251-SR has a density of 8.6 g/cm³ (0.311 lb/in³), heavier than 54% of refractory metal grades. It melts at 2,410°C (4,370 °F). Annealed is the default condition FabDigit quotes; SR is available on request or by drawing note.

Advantages

  • Readily welded — 78/100, better than 86% of refractory metal grades

R04251-SR properties

Typical room-temperature values for R04251-SR; 21 are specific to this condition. Other listed values are R04251 reference data and may not represent this condition. Bars are the position among refractory metal grades.

Physical3

R04251-SR has a density of 8.6 g/cm³ (0.311 lb/in³), heavier than 54% of refractory metal grades. It melts at 2,410°C (4,370 °F).

Density8.6 g/cm³0.31 lb/in³
Melting Point (Solidus)2,410°C4,370 °F
Liquidus Temperature2,450°C4,442 °F

Mechanical12

R04251-SR has a yield strength of 260 MPa (37.7 ksi) and a tensile strength of 340 MPa (49.3 ksi) — weaker than 68% of refractory metal grades. Elongation at break is 18% and the elastic modulus is 100 GPa (14.5 Msi).

Elastic (Young's) Modulus100 GPa14.5 Msi
Shear Modulus37 GPa5.4 Msi
Bulk Modulus170 GPa24.7 Msi
Poisson's Ratio0.38
Tensile Strength (Ultimate)340 MPa49.3 ksi
Yield Strength (0.2% offset)260 MPa37.7 ksi
Elongation at Break18%
Reduction in Area65%
Shear Strength210 MPa30.5 ksi
Fatigue Strength (Endurance Limit)170 MPa24.7 ksi
Hardness, Rockwell B75 HRB
Hardness, Vickers140 HV

Thermal6

R04251-SR is rated for continuous service to 400°C (752 °F). It conducts heat at 44 W/m·K (25.4 BTU/hr·ft·°F), better than 53% of refractory metal grades. Thermal expansion is 7.2 µm/m·K (4 µin/in·°F).

Thermal Conductivity44 W/m·K25.4 BTU/hr·ft·°F
Specific Heat Capacity270 J/kg·K0.06 BTU/lb·°F
Thermal Expansion (CTE, 20–100 °C)7.2 µm/m·K4 µin/in·°F
Latent Heat of Fusion288 J/g124 BTU/lb
Max Service Temperature (continuous)400°C752 °F
Min Service Temperature-253°C-423 °F

Electrical3

R04251-SR conducts electricity at 8.3 % IACS, better than 57% of refractory metal grades.

Electrical Conductivity8.3 % IACS
Electrical Resistivity2.08×10⁻⁷ Ω·m8.19 µΩ·in
Magnetic Responsenon-magnetic (paramagnetic; superconducting below ~9 K)

Chemical & Environmental3

Corrosion resistance is excellent (85/100), better than 52% of refractory metal grades.

Galvanic Potential (seawater, vs SCE)-0.2 V
Corrosion ResistanceExcellent85/100
Chemical Resistance SummaryExcellent in liquid alkali metals (Na, K, NaK, Li) to >1000 °C when oxygen is controlled, and in most mineral acids, chlorides and organics; attacked by HF, hot concentrated alkalis and fluoride-bearing media, and embrittled by hydrogen and by air/oxygen above ~400 °C.

Sustainability4

Producing a kilogram of R04251-SR takes about 900 MJ of energy and emits 55 kg of CO₂ — less than 59% of refractory metal grades. Typical recycled content is 15%.

Embodied Energy (primary production)900 MJ/kg386,931 BTU/lb
Embodied Carbon (primary production)55 kg CO₂/kg
Embodied Water600 L/kg71.9 gal/lb
Typical Recycled Content15%

Manufacturability8

R04251-SR's machinability is poor (32/100, better than 67% of refractory metal grades); weldability very good (78/100); formability good (65/100).

MachinabilityPoor32/100
Machinability Rating (AISI 1212 = 100 %)27%
WeldabilityVery good78/100
Formability (cold)Good65/100
CastabilityPoor20/100
Brazeability / SolderabilityGood60/100
PolishabilityVery good70/100
Anodizing Responsegood — anodizes to stable, colored Nb2O5 interference films used for decorative and biomedical/implant surfaces; not a wear coating

Values are nominal handbook figures for design screening. Confirm any required mill or lot documentation when quoting.

Working with R04251-SR

Is R04251 easy to machine?

Very gummy and galling — use sharp, high-positive-rake carbide or HSS tools, slow speeds, heavy positive feeds and copious chlorinated or sulfurized oil, then degrease thoroughly to avoid hydrogen/carbon pickup.

Can R04251 be welded?

Excellent by GTAW in a purged glove box, EBW or laser in vacuum; the weld and heat-affected zone must be shielded until below ~200 °C or the joint embrittles from O/N/H pickup.

Can R04251 be formed, bent or molded?

Outstanding cold formability — deep draws, spinning and >90% cold reductions are practical with clean tooling and Nb-friendly lubricants; interanneal in vacuum at 1100–1250 °C.

What surface finishes work on R04251?

Chemically polish or electropolish (HF/HNO3-based or sulfuric-HF electrolytes); anodizes to durable colored Nb2O5 films; avoid pickling residues and always vacuum-degas before high-temperature service.

R04251 chemical composition (wt %)

Limits by weight percent from the governing specification, written the way the spec states them — a single maximum for impurities, a range for alloying elements, and the base element as balance. Nominal is the typical mid-range value.

ElementSpec limit (wt %)Nominal
Zrprimary alloying addition0.8 – 1.21
Creactor-grade interstitial limit≤ 0.010.01
Oreactor-grade interstitial limit≤ 0.020.01
Nreactor-grade interstitial limit≤ 0.010
Hreactor-grade interstitial limit≤ 05×10⁻⁴
Tarestricted for low neutron cross-section≤ 0.1—
Wrestricted for low neutron cross-section≤ 0.05—
Hfrestricted for low neutron cross-section≤ 0.02—
Mo≤ 0.01—
Ti≤ 0.02—
Fe≤ 0.01—
Ni≤ 0.01—
Si≤ 0.01—
Nbbalance; limits above are ASTM B393 Type 3 reactor-grade maximabalance—

R04251-SR — frequently asked

What is R04251-SR used for?

R04251-SR is typically used for nuclear reactor fuel cladding, liquid metal heat exchangers, high-temperature space reactor components and sodium-cooled reactor hardware. In short: reactor-grade Nb-1Zr; low neutron cross-section; stronger than pure niobium.

What is the yield strength of R04251-SR?

R04251-SR has a typical yield strength of 260 MPa (37.7 ksi) and a tensile strength of 340 MPa (49.3 ksi) — weaker than 68% of refractory metal grades. Strength varies by condition: see the 3 listed tempers.

Is R04251-SR easy to machine?

Not especially — machinability is rated poor (32/100, better than 67% of refractory metal grades). Very gummy and galling — use sharp, high-positive-rake carbide or HSS tools, slow speeds, heavy positive feeds and copious chlorinated or sulfurized oil, then degrease thoroughly to avoid hydrogen/carbon pickup.

Can R04251-SR be welded?

Yes — weldability is rated very good (78/100). Excellent by GTAW in a purged glove box, EBW or laser in vacuum; the weld and heat-affected zone must be shielded until below ~200 °C or the joint embrittles from O/N/H pickup.

What surface finishes work on R04251-SR?

Chemically polish or electropolish (HF/HNO3-based or sulfuric-HF electrolytes); anodizes to durable colored Nb2O5 films; avoid pickling residues and always vacuum-degas before high-temperature service.

Can R04251-SR be formed, bent or molded?

Outstanding cold formability — deep draws, spinning and >90% cold reductions are practical with clean tooling and Nb-friendly lubricants; interanneal in vacuum at 1100–1250 °C.

What is the maximum service temperature of R04251-SR?

R04251-SR is rated for continuous use to about 400°C (752 °F). Strength falls off well before that limit — check the elevated-temperature data for load-bearing parts.

What is the difference between R04251 Annealed and R04251-CW?

Annealed is the default condition — standard stocked condition for forming, deep drawing, tube reducing and welded reactor/alkali-metal hardware. CW: choose for maximum room-temperature strength and springiness in foil, wire and thin strip that will not see recrystallization temperatures. Yield strength is 140 MPa in Annealed versus 470 MPa in CW.

Sources

  1. ASTM B393 — Niobium and Niobium Alloy Strip, Sheet, and Plate — ASTM International (2020)
  2. ASTM B392 / B394 — Niobium and Niobium Alloy Bar, Rod and Seamless/Welded Tubing — ASTM International (2019)
  3. ASM Handbook Vol. 2 — Properties and Selection: Nonferrous Alloys and Special-Purpose Materials (Refractory Metals) — ASM International (1990)
  4. ASM Specialty Handbook: Heat-Resistant Materials / Refractory metal design data — ASM International (1997)
  5. Nb-1Zr niobium-zirconium alloy mill product data — / ATI-type refractory metal producers (2023)

Property data is compiled from published supplier and standards handbooks and normalised for comparison. Nothing on this page is a certification — request mill certs, CoC or material test reports with your order.