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Refractory Metal N1-RXA (Recrystallization annealed)

Heat-treated state · default condition

Standard condition for PWR fuel cladding tube: maximum ductility, lowest irradiation growth, stable creep behaviour.

High cost $$$$

Values for the RXA condition

Other N1 tempers and conditions

N1 is listed in 6 conditions; see the grade overview at N1.

Compare all 6 conditionsHide
Condition · open for datasheetBest forYield MPaTensile MPaElong. %HardnessConductivity
RXADefaultThis page
Recrystallization annealed
Standard condition for PWR fuel cladding tube: maximum ductility, lowest irradiation growth, stable creep behaviour.26042030150 HB3.1 % IACS
Hot rolled + annealed
General mill product form for grid straps, end plugs and machined components rather than thin-wall tube.27043028152 HB3.1 % IACS
beta quenched then recrystallization annealed
Beta-quench homogenizes Nb distribution before final anneal; used for pressure-tube and corrosion-optimized cladding lots.28044028157 HB3.1 % IACS
Partially recrystallized annealed
Intermediate strength/ductility balance used for guide tubes and some cladding designs.35048022166 HB3.1 % IACS
Cold worked + stress-relief annealed
Choose where higher strength and creep-collapse resistance of the tube are needed and some ductility can be traded away.43054015185 HB3 % IACS
Cold worked
Intermediate mill condition or hard strip/wire where maximum strength is wanted and ductility is not critical.540620917 HRC3 % IACS

What is N1-RXA?

N1-RXA is N1 heat treated to RXA — standard condition for PWR fuel cladding tube: maximum ductility, lowest irradiation growth, stable creep behaviour. N1-RXA has a yield strength of 260 MPa (37.7 ksi) and a tensile strength of 420 MPa (60.9 ksi) — weaker than 68% of refractory metal grades. Elongation at break is 30% and the elastic modulus is 97 GPa (14.1 Msi). N1-RXA has a density of 6.55 g/cm³ (0.237 lb/in³), lighter than 77% of refractory metal grades. It melts at 1,850°C (3,362 °F).

Advantages

  • Ductile — tolerates forming and impact — 30%, better than 86% of refractory metal grades
  • Readily welded — 75/100, better than 81% of refractory metal grades
  • Forms and bends easily — 75/100, better than 81% of refractory metal grades
  • Lightweight — 6.55 g/cm³ (0.237 lb/in³), better than 77% of refractory metal grades

Limitations

  • Low stiffness — 97 GPa (14.1 Msi), worse than 91% of refractory metal grades
  • Low electrical conductivity — 3.1 % IACS, worse than 78% of refractory metal grades

N1-RXA properties

Typical room-temperature values for N1-RXA; 22 are specific to this condition. Other listed values are N1 reference data and may not represent this condition. Bars are the position among refractory metal grades.

Physical3

N1-RXA has a density of 6.55 g/cm³ (0.237 lb/in³), lighter than 77% of refractory metal grades. It melts at 1,850°C (3,362 °F).

Density6.55 g/cm³0.24 lb/in³
Melting Point (Solidus)1,850°C3,362 °F
Liquidus Temperature1,870°C3,398 °F

Mechanical16

N1-RXA has a yield strength of 260 MPa (37.7 ksi) and a tensile strength of 420 MPa (60.9 ksi) — weaker than 68% of refractory metal grades. Elongation at break is 30% and the elastic modulus is 97 GPa (14.1 Msi).

Elastic (Young's) Modulus97 GPa14.1 Msi
Shear Modulus36 GPa5.2 Msi
Bulk Modulus98 GPa14.2 Msi
Poisson's Ratio0.35
Tensile Strength (Ultimate)420 MPa60.9 ksi
Yield Strength (0.2% offset)260 MPa37.7 ksi
Elongation at Break30%
Reduction in Area50%
Compressive Strength270 MPa39.2 ksi
Shear Strength270 MPa39.2 ksi
Fatigue Strength (Endurance Limit)200 MPa29 ksi
Fracture Toughness (K_IC)60 MPa·√m54.6 ksi·√in
Charpy V-Notch Impact (RT)60 J44.3 ft·lbf
Hardness, Brinell150 HB
Hardness, Rockwell B82 HRB
Hardness, Vickers158 HV

Thermal6

N1-RXA is rated for continuous service to 400°C (752 °F). It conducts heat at 18 W/m·K (10.4 BTU/hr·ft·°F), worse than 70% of refractory metal grades. Thermal expansion is 5.9 µm/m·K (3.28 µin/in·°F).

Thermal Conductivity18 W/m·K10.4 BTU/hr·ft·°F
Specific Heat Capacity285 J/kg·K0.07 BTU/lb·°F
Thermal Expansion (CTE, 20–100 °C)5.9 µm/m·K3.3 µin/in·°F
Latent Heat of Fusion155 J/g66.6 BTU/lb
Max Service Temperature (continuous)400°C752 °F
Min Service Temperature-200°C-328 °F

Electrical3

N1-RXA conducts electricity at 3.1 % IACS, worse than 78% of refractory metal grades.

Electrical Conductivity3.1 % IACS
Electrical Resistivity5.5×10⁻⁷ Ω·m21.7 µΩ·in
Magnetic Responsenon-magnetic

Chemical & Environmental3

Corrosion resistance is excellent (92/100), better than 86% of refractory metal grades.

Galvanic Potential (seawater, vs SCE)-0.1 V
Corrosion ResistanceExcellent92/100
Chemical Resistance SummaryOutstanding in high-temperature water and steam, most organics, HCl of all concentrations, H2SO4 to ~70 %, nitric acid and alkalis; attacked by HF, fluoride-bearing media, ferric/cupric chlorides, aqua regia and concentrated hot H2SO4.

Sustainability4

Producing a kilogram of N1-RXA takes about 1,200 MJ of energy and emits 72 kg of CO₂ — less than 51% of refractory metal grades. Typical recycled content is 10%.

Embodied Energy (primary production)1,200 MJ/kg515,908 BTU/lb
Embodied Carbon (primary production)72 kg CO₂/kg
Embodied Water900 L/kg108 gal/lb
Typical Recycled Content10%

Manufacturability8

N1-RXA's machinability is poor (32/100, better than 67% of refractory metal grades); weldability very good (75/100); formability very good (75/100).

MachinabilityPoor32/100
Machinability Rating (AISI 1212 = 100 %)25%
WeldabilityVery good75/100
Formability (cold)Very good75/100
CastabilityPoor25/100
Brazeability / SolderabilityPoor30/100
PolishabilityGood60/100
Anodizing Responsefair — anodic/thermal oxide films give interference colors and improve wear, but are not a structural or nuclear-service coating

Common Calculations5

Specific Strength (UTS / density)calculated64 kN·m/kg
Specific Stiffness (E / density)calculated14.8 MN·m/kg
Modulus of Resiliencecalculated348 kJ/m³
Thermal Diffusivitycalculated9.6 mm²/s
Thermal Shock Resistance Indexcalculated13

Values are nominal handbook figures for design screening. Confirm any required mill or lot documentation when quoting.

Working with N1-RXA

Is N1 easy to machine?

Machine like titanium — sharp, positive-rake carbide, low speed / heavy feed, flood coolant; collect fines wet since dry chips and dust are pyrophoric.

Can N1 be welded?

GTAW or electron-beam in a high-purity argon chamber or vacuum with full back-purge; any O/N/H pickup embrittles the joint and degrades corrosion.

Can N1 be formed, bent or molded?

Cold pilgering plus intermediate vacuum anneals is the standard tube route; bend radii ≥3t cold, texture control governs irradiation growth.

What surface finishes work on N1?

Pickle in HNO3/HF then rinse thoroughly, or electropolish/autoclave-passivate to form the protective black oxide; avoid iron contamination from steel tooling.

N1 chemical composition (wt %)

Limits by weight percent from the governing specification, written the way the spec states them — a single maximum for impurities, a range for alloying elements, and the base element as balance. Nominal is the typical mid-range value.

ElementSpec limit (wt %)Nominal
Nbprincipal alloying element0.9 – 1.11
Ocontrolled for strength0.05 – 0.120.09
Fe≤ 0.050.03
C≤ 0.020.01
N≤ 0.010
Hfnuclear grade — low neutron absorption≤ 0.010.01
Si≤ 0.01—
Ni≤ 0.01—
Cr≤ 0.02—
H≤ 0—
Zrbalance—

N1-RXA — frequently asked

What is N1-RXA used for?

N1-RXA is typically used for fuel cladding tubes, pressure tubes and reactor structural parts. In short: domestic E110 equivalent; most formable Zr-1%Nb grade; low neutron absorption.

What is the yield strength of N1-RXA?

N1-RXA has a typical yield strength of 260 MPa (37.7 ksi) and a tensile strength of 420 MPa (60.9 ksi) — weaker than 68% of refractory metal grades. Strength varies by condition: see the 6 listed tempers.

Is N1-RXA easy to machine?

Not especially — machinability is rated poor (32/100, better than 67% of refractory metal grades). Machine like titanium — sharp, positive-rake carbide, low speed / heavy feed, flood coolant; collect fines wet since dry chips and dust are pyrophoric.

Can N1-RXA be welded?

Yes — weldability is rated very good (75/100). GTAW or electron-beam in a high-purity argon chamber or vacuum with full back-purge; any O/N/H pickup embrittles the joint and degrades corrosion.

What surface finishes work on N1-RXA?

Pickle in HNO3/HF then rinse thoroughly, or electropolish/autoclave-passivate to form the protective black oxide; avoid iron contamination from steel tooling.

Can N1-RXA be formed, bent or molded?

Cold pilgering plus intermediate vacuum anneals is the standard tube route; bend radii ≥3t cold, texture control governs irradiation growth.

What is the maximum service temperature of N1-RXA?

N1-RXA is rated for continuous use to about 400°C (752 °F). Strength falls off well before that limit — check the elevated-temperature data for load-bearing parts.

What is the difference between N1-RXA and N1-CW?

RXA is the default condition — standard condition for PWR fuel cladding tube: maximum ductility, lowest irradiation growth, stable creep behaviour. CW: intermediate mill condition or hard strip/wire where maximum strength is wanted and ductility is not critical. Yield strength is 260 MPa in RXA versus 540 MPa in CW.

Sources

  1. ASTM B811 Standard Specification for Wrought Zirconium Alloy Seamless Tubes for Nuclear Reactor Fuel Cladding — ASTM International (2019)
  2. ASTM B350/B350M Zirconium and Zirconium Alloy Ingots for Nuclear Application — ASTM International (2018)
  3. ASM Handbook Vol. 2 — Properties and Selection: Nonferrous Alloys (Zirconium and Hafnium) — ASM International (1990)
  4. IAEA TECDOC series on zirconium alloy fuel cladding behaviour and thermophysical properties — IAEA (2010)
  5. Zr-1Nb (E110/M5-type) cladding tube technical data — nuclear zirconium tube producers (2022)

Property data is compiled from published supplier and standards handbooks and normalised for comparison. Nothing on this page is a certification — request mill certs, CoC or material test reports with your order.