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Refractory Metal Excel-CW (Cold worked)

Supply condition · default condition

Standard CANDU pressure-tube condition: cold pilgered/drawn then stress-relieved ~400 °C for high strength with retained toughness.

High cost $$$$

Values for the CW condition

Other Excel tempers and conditions

Excel is listed in 4 conditions; see the grade overview at Excel.

Compare all 4 conditionsHide
Condition · open for datasheetBest forYield MPaTensile MPaElong. %HardnessConductivity
Annealed
Softest, most ductile and most corrosion-stable condition; chosen when formability or maximum toughness matters more than strength.47062022205 HV—
CWDefaultThis page
Cold worked
Standard CANDU pressure-tube condition: cold pilgered/drawn then stress-relieved ~400 °C for high strength with retained toughness.7308501425 HRC—
Cold worked and aged
Ageing after cold work precipitates β/Mo-bearing phases for extra strength and creep resistance at some ductility cost.8009001228 HRC—
Β-quenched and aged
Highest-strength and best creep-resistant condition for thin-wall pressure tubes; lowest fracture toughness and most sensitive to hydride embrittlement.8709901031 HRC—

What is Excel-CW?

Excel-CW is Excel supplied in the CW condition — standard CANDU pressure-tube condition: cold pilgered/drawn then stress-relieved ~400 °C for high strength with retained toughness. Excel-CW has a yield strength of 730 MPa (106 ksi) and a tensile strength of 850 MPa (123 ksi) — stronger than 87% of refractory metal grades. Elongation at break is 14% and the elastic modulus is 97 GPa (14.1 Msi). Excel-CW has a density of 6.57 g/cm³ (0.237 lb/in³), lighter than 67% of refractory metal grades. It melts at 1,780°C (3,236 °F).

Advantages

  • High strength — 730 MPa (106 ksi), better than 87% of refractory metal grades

Limitations

  • Low stiffness — 97 GPa (14.1 Msi), worse than 91% of refractory metal grades
  • Low electrical conductivity — 2.2 % IACS, worse than 91% of refractory metal grades
  • Poor heat conductor — 15.5 W/m·K (8.96 BTU/hr·ft·°F), worse than 81% of refractory metal grades

Excel-CW properties

Typical room-temperature values for Excel-CW; 11 are specific to this condition. Other listed values are Excel reference data and may not represent this condition. Bars are the position among refractory metal grades.

Physical3

Excel-CW has a density of 6.57 g/cm³ (0.237 lb/in³), lighter than 67% of refractory metal grades. It melts at 1,780°C (3,236 °F).

Density6.57 g/cm³0.24 lb/in³
Melting Point (Solidus)1,780°C3,236 °F
Liquidus Temperature1,840°C3,344 °F

Mechanical13

Excel-CW has a yield strength of 730 MPa (106 ksi) and a tensile strength of 850 MPa (123 ksi) — stronger than 87% of refractory metal grades. Elongation at break is 14% and the elastic modulus is 97 GPa (14.1 Msi).

Elastic (Young's) Modulus97 GPa14.1 Msi
Shear Modulus36 GPa5.2 Msi
Bulk Modulus98 GPa14.2 Msi
Poisson's Ratio0.35
Tensile Strength (Ultimate)850 MPa123 ksi
Yield Strength (0.2% offset)730 MPa106 ksi
Elongation at Break14%
Reduction in Area40%
Shear Strength500 MPa72.5 ksi
Fatigue Strength (Endurance Limit)350 MPa50.8 ksi
Fracture Toughness (K_IC)45 MPa·√m41 ksi·√in
Hardness, Rockwell C25 HRC
Hardness, Vickers265 HV

Thermal6

Excel-CW is rated for continuous service to 400°C (752 °F). It conducts heat at 15.5 W/m·K (8.96 BTU/hr·ft·°F), worse than 81% of refractory metal grades. Thermal expansion is 6 µm/m·K (3.33 µin/in·°F).

Thermal Conductivity15.5 W/m·K9 BTU/hr·ft·°F
Specific Heat Capacity285 J/kg·K0.07 BTU/lb·°F
Thermal Expansion (CTE, 20–100 °C)6 µm/m·K3.3 µin/in·°F
Latent Heat of Fusion155 J/g66.6 BTU/lb
Max Service Temperature (continuous)400°C752 °F
Min Service Temperature-196°C-321 °F

Electrical3

Excel-CW conducts electricity at 2.2 % IACS, worse than 91% of refractory metal grades.

Electrical Conductivity2.2 % IACS
Electrical Resistivity8×10⁻⁷ Ω·m31.5 µΩ·in
Magnetic Responsenon-magnetic

Chemical & Environmental3

Corrosion resistance is excellent (85/100), better than 52% of refractory metal grades.

Galvanic Potential (seawater, vs SCE)-0.15 V
Corrosion ResistanceExcellent85/100
Chemical Resistance SummaryExcellent in hot water, steam, most organics, and strong alkalis and non-oxidising acids (HCl, H2SO4); attacked by HF, fluoride-bearing media, aqua regia and concentrated FeCl3/CuCl2; oxide film degrades faster than Zr-2.5Nb in 300 °C water with higher deuterium/hydrogen pickup.

Sustainability4

Producing a kilogram of Excel-CW takes about 1,400 MJ of energy and emits 85 kg of CO₂ — more than 67% of refractory metal grades. Typical recycled content is 15%.

Embodied Energy (primary production)1,400 MJ/kg601,892 BTU/lb
Embodied Carbon (primary production)85 kg CO₂/kg
Embodied Water600 L/kg71.9 gal/lb
Typical Recycled Content15%

Manufacturability8

Excel-CW's machinability is poor (28/100, worse than 58% of refractory metal grades); weldability fair (45/100); formability fair (35/100).

MachinabilityPoor28/100
Machinability Rating (AISI 1212 = 100 %)22%
WeldabilityFair45/100
Formability (cold)Fair35/100
CastabilityPoor20/100
Brazeability / SolderabilityPoor25/100
PolishabilityGood60/100
Anodizing Responsegood — anodises to coloured interference oxide films like Ti/Zr; used for identification rather than wear protection

Common Calculations5

Specific Strength (UTS / density)calculated129 kN·m/kg
Specific Stiffness (E / density)calculated14.8 MN·m/kg
Modulus of Resiliencecalculated2,747 kJ/m³
Thermal Diffusivitycalculated8.3 mm²/s
Thermal Shock Resistance Indexcalculated23

Values are nominal handbook figures for design screening. Confirm any required mill or lot documentation when quoting.

Working with Excel-CW

Is Excel easy to machine?

Slow speeds, heavy positive-rake carbide tooling and flood coolant; fine chips are pyrophoric and must be collected wet.

Can Excel be welded?

GTAW/EBW in high-purity argon or vacuum only — any air, N or H pickup embrittles the weld; heat-treated strength is lost in the HAZ and cannot be restored without full re-solution treatment.

Can Excel be formed, bent or molded?

Cold pilgering and tube drawing are feasible but the alloy work-hardens rapidly, needing intermediate vacuum anneals; hot working done in the α+β range around 800 °C.

What surface finishes work on Excel?

Pickle in HNO3/HF to remove oxide and hydride-rich surface, then autoclave-passivate in steam; anodising gives decorative/identification oxide films only.

Excel chemical composition (wt %)

Limits by weight percent from the governing specification, written the way the spec states them — a single maximum for impurities, a range for alloying elements, and the base element as balance. Nominal is the typical mid-range value.

ElementSpec limit (wt %)Nominal
Snprimary solid-solution strengthener3.2 – 3.83.5
Nbβ-stabiliser0.6 – 10.8
Moβ-stabiliser, creep resistance0.6 – 10.8
Ocontrolled interstitial (900–1300 ppm)0.09 – 0.130.11
Feresidual≤ 0.050.03
Cresidual≤ 0.030.02
Nresidual≤ 0.010
Hfnuclear-grade limit≤ 0.010.01
Zrbalance—

Excel-CW — frequently asked

What is Excel-CW used for?

Excel-CW is typically used for CANDU reactor pressure tubes, heavy-water reactor structural components, calandria and channel hardware, high-strength zirconium tubing and reactor pressure-boundary fittings. In short: strongest zirconium pressure-tube alloy; high creep resistance; heat-treatable Zr-Sn-Nb-Mo.

What is the yield strength of Excel-CW?

Excel-CW has a typical yield strength of 730 MPa (106 ksi) and a tensile strength of 850 MPa (123 ksi) — stronger than 87% of refractory metal grades. Strength varies by condition: see the 4 listed tempers.

Is Excel-CW easy to machine?

Not especially — machinability is rated poor (28/100, worse than 58% of refractory metal grades). Slow speeds, heavy positive-rake carbide tooling and flood coolant; fine chips are pyrophoric and must be collected wet.

Can Excel-CW be welded?

With care — weldability is rated fair (45/100). GTAW/EBW in high-purity argon or vacuum only — any air, N or H pickup embrittles the weld; heat-treated strength is lost in the HAZ and cannot be restored without full re-solution treatment.

What surface finishes work on Excel-CW?

Pickle in HNO3/HF to remove oxide and hydride-rich surface, then autoclave-passivate in steam; anodising gives decorative/identification oxide films only.

Can Excel-CW be formed, bent or molded?

Cold pilgering and tube drawing are feasible but the alloy work-hardens rapidly, needing intermediate vacuum anneals; hot working done in the α+β range around 800 °C.

What is the maximum service temperature of Excel-CW?

Excel-CW is rated for continuous use to about 400°C (752 °F). Strength falls off well before that limit — check the elevated-temperature data for load-bearing parts.

What is the difference between Excel-CW and Excel-ANN?

CW is the default condition — standard CANDU pressure-tube condition: cold pilgered/drawn then stress-relieved ~400 °C for high strength with retained toughness. ANN: softest, most ductile and most corrosion-stable condition; chosen when formability or maximum toughness matters more than strength. Yield strength is 730 MPa in CW versus 470 MPa in ANN.

Sources

  1. ASM Handbook Vol.2 — Properties and Selection: Nonferrous Alloys (Zirconium and Zirconium Alloys) — ASM International (1990)
  2. ASM Handbook Vol.13B — Corrosion: Materials (Zirconium) — ASM International (2005)
  3. ASTM B353 / B811 — Wrought zirconium and zirconium alloy tubing for nuclear service — ASTM International (2018)
  4. AECL CANDU pressure-tube alloy development literature (Excel Zr-3.5Sn-0.8Nb-0.8Mo) — Atomic Energy of Canada Limited (1990)
  5. IAEA TECDOC on zirconium alloy properties for water reactor fuel and pressure tubes — IAEA (2010)

Property data is compiled from published supplier and standards handbooks and normalised for comparison. Nothing on this page is a certification — request mill certs, CoC or material test reports with your order.