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YSZ 5YSZ

Grade

5YSZ = 5 mol% Y₂O₃ partially stabilized

Compromise grade: better conductivity and thermal-shock/ageing behaviour than 3YSZ, better strength than 8YSZ — used for sensor bodies and thicker electrolyte supports.

High cost $$$$

Values for the 5YSZ condition

Other YSZ tempers and conditions

YSZ is listed in 4 conditions; see the grade overview at YSZ.

Compare all 4 conditionsHide
Condition · open for datasheetBest forYield MPaTensile MPaElong. %HardnessConductivity
3 mol% Y₂O₃ tetragonal polycrystal
Pick when mechanical strength and toughness dominate — sensor housings, ferrules, blades, dental and pump parts — accepting much lower ionic conductivity and LTD risk.—450—1,250 HV3 W/m·K
5YSZThis page
5 mol% Y₂O₃ partially stabilized
Compromise grade: better conductivity and thermal-shock/ageing behaviour than 3YSZ, better strength than 8YSZ — used for sensor bodies and thicker electrolyte supports.———1,280 HV2 W/m·K
8YSZDefault
8 mol% Y₂O₃, fully stabilized cubic electrolyte
Pick for SOFC electrolyte membranes, oxygen sensors and oxygen pumps where maximum oxygen-ion conductivity matters more than strength.———1,300 HV2 W/m·K
10 mol% Y₂O₃ fully stabilized cubic
Pick for long-term high-temperature electrolyte service where phase stability and low conductivity degradation over thousands of hours outweigh peak conductivity.———1,300 HV2 W/m·K

What is YSZ 5YSZ?

YSZ 5YSZ is YSZ in the 5YSZ grade — compromise grade: better conductivity and thermal-shock/ageing behaviour than 3YSZ, better strength than 8YSZ — used for sensor bodies and thicker electrolyte supports. YSZ 5YSZ has a tensile strength of 120 MPa (17.4 ksi), stronger than 51% of ceramic grades. Elongation at break is 0% and the elastic modulus is 205 GPa (29.7 Msi). YSZ 5YSZ has a density of 5.98 g/cm³ (0.216 lb/in³), heavier than 65% of ceramic grades. It melts at 2,700°C (4,892 °F). 8YSZ is the default condition FabDigit quotes; 5YSZ is available on request or by drawing note.

Advantages

  • Polishes to a fine finish — 92/100, better than 89% of ceramic grades
  • Good corrosion resistance — 92/100, better than 88% of ceramic grades
  • High service temperature — 1,300°C (2,372 °F), better than 77% of ceramic grades

Limitations

  • Poor heat conductor — 2.4 W/m·K (1.39 BTU/hr·ft·°F), worse than 86% of ceramic grades

YSZ 5YSZ properties

Typical room-temperature values for YSZ 5YSZ; 10 are specific to this condition. Other listed values are YSZ reference data and may not represent this condition. Bars are the position among ceramic grades.

Physical4

YSZ 5YSZ has a density of 5.98 g/cm³ (0.216 lb/in³), heavier than 65% of ceramic grades. It melts at 2,700°C (4,892 °F).

Density5.98 g/cm³0.22 lb/in³
Melting Point (Solidus)2,700°C4,892 °F
Refractive Index2.16
Porosity0.2%

Mechanical12

YSZ 5YSZ has a tensile strength of 120 MPa (17.4 ksi), stronger than 51% of ceramic grades. Elongation at break is 0% and the elastic modulus is 205 GPa (29.7 Msi).

Elastic (Young's) Modulus205 GPa29.7 Msi
Shear Modulus77 GPa11.2 Msi
Bulk Modulus170 GPa24.7 Msi
Poisson's Ratio0.31
Tensile Strength (Ultimate)120 MPa17.4 ksi
Elongation at Break0%
Compressive Strength1,800 MPa261 ksi
Flexural Strength550 MPa79.8 ksi
Fracture Toughness (K_IC)4 MPa·√m3.6 ksi·√in
Hardness, Vickers1,280 HV
Hardness, Knoop1,150 HK
Hardness, Mohs8.5

Thermal5

YSZ 5YSZ is rated for continuous service to 1,300°C (2,372 °F). It conducts heat at 2.4 W/m·K (1.39 BTU/hr·ft·°F), worse than 86% of ceramic grades. Thermal expansion is 10.4 µm/m·K (5.78 µin/in·°F).

Thermal Conductivity2.4 W/m·K1.4 BTU/hr·ft·°F
Specific Heat Capacity450 J/kg·K0.11 BTU/lb·°F
Thermal Expansion (CTE, 20–100 °C)10.4 µm/m·K5.8 µin/in·°F
Max Service Temperature (continuous)1,300°C2,372 °F
Min Service Temperature-200°C-328 °F

Electrical3

YSZ 5YSZ has an electrical resistivity of 1×10⁸ Ω·m.

Electrical Resistivity1×10⁸ Ω·m3.94×10¹⁵ µΩ·in
Dielectric Constant (1 MHz)28
Volume Resistivity1×10¹⁰ Ω·cm

Chemical & Environmental2

Corrosion resistance is excellent (92/100), better than 88% of ceramic grades.

Corrosion ResistanceExcellent92/100
Chemical Resistance SummaryExcellent against molten metals, alkalis, most acids and oxidizing/reducing gases up to ~1000 °C; attacked by HF and hot concentrated H₂SO₄/H₃PO₄; cubic phase resists low-temperature ageing, but reduction at very low pO₂ plus high temperature can darken and degrade the electrolyte.

Sustainability4

Producing a kilogram of YSZ 5YSZ takes about 130 MJ of energy and emits 9 kg of CO₂ — more than 55% of ceramic grades. Typical recycled content is 0%.

Embodied Energy (primary production)130 MJ/kg55,890 BTU/lb
Embodied Carbon (primary production)9 kg CO₂/kg
Embodied Water250 L/kg30 gal/lb
Typical Recycled Content0%

Manufacturability3

YSZ 5YSZ's machinability is not recommended (5/100, worse than 59% of ceramic grades).

MachinabilityNot recommended5/100
PolishabilityExcellent92/100
Sintering / Firing Temperature1,450°C2,642 °F

Values are nominal handbook figures for design screening. Confirm any required mill or lot documentation when quoting.

Working with YSZ 5YSZ

Is YSZ easy to machine?

Machine green or bisque bodies with carbide tooling allowing ~20–25 % sinter shrinkage; fired YSZ requires diamond grinding, lapping or laser/ultrasonic machining.

Can YSZ be welded?

Not weldable — join by active-metal brazing (Ag-Cu-Ti), glass-ceramic seals (typical for SOFC stacks) or metallized Pt/Ni layers.

Can YSZ be formed, bent or molded?

Formed by tape casting (electrolyte foils 5–200 µm), uniaxial/CIP pressing, injection moulding or screen printing, then sintered 1350–1550 °C in air.

What surface finishes work on YSZ?

Takes a mirror polish with diamond slurries; electrodes applied as screen-printed Pt or Ni-YSZ/LSM cermet pastes fired at 900–1300 °C.

YSZ chemical composition (wt %)

Limits by weight percent from the governing specification, written the way the spec states them — a single maximum for impurities, a range for alloying elements, and the base element as balance. Nominal is the typical mid-range value.

ElementSpec limit (wt %)Nominal
Y2O38 mol% Y₂O₃ ≈ 13.7 wt% for the default grade; 3YSZ ≈ 5.2 wt%, 10YSZ ≈ 16.8 wt%13 – 1513.7
HfO2natural companion of zirconia, not removed1 – 2.51.8
Al2O3optional sintering aid / ageing suppressant0 – 0.50.25
SiO2impurity, degrades grain-boundary conductivity0 – 0.050.02
ZrO2balance—

YSZ 5YSZ — frequently asked

What is YSZ 5YSZ used for?

YSZ 5YSZ is typically used for automotive oxygen sensors, solid oxide fuel cell electrolytes and gas sensors. In short: standard oxygen-ion electrolyte; service to 1500 °C; diamond machining only.

What is the tensile strength of YSZ 5YSZ?

YSZ 5YSZ has a typical tensile strength of 120 MPa (17.4 ksi) — stronger than 51% of ceramic grades. Strength varies by condition: see the 4 listed tempers.

Is YSZ 5YSZ easy to machine?

Not especially — machinability is rated not recommended (5/100, worse than 59% of ceramic grades). Machine green or bisque bodies with carbide tooling allowing ~20–25 % sinter shrinkage; fired YSZ requires diamond grinding, lapping or laser/ultrasonic machining.

Can YSZ 5YSZ be welded?

Not weldable — join by active-metal brazing (Ag-Cu-Ti), glass-ceramic seals (typical for SOFC stacks) or metallized Pt/Ni layers.

What surface finishes work on YSZ 5YSZ?

Takes a mirror polish with diamond slurries; electrodes applied as screen-printed Pt or Ni-YSZ/LSM cermet pastes fired at 900–1300 °C.

Can YSZ 5YSZ be formed, bent or molded?

Formed by tape casting (electrolyte foils 5–200 µm), uniaxial/CIP pressing, injection moulding or screen printing, then sintered 1350–1550 °C in air.

What is the maximum service temperature of YSZ 5YSZ?

YSZ 5YSZ is rated for continuous use to about 1,300°C (2,372 °F). Strength falls off well before that limit — check the elevated-temperature data for load-bearing parts.

Sources

  1. ASM Engineered Materials Handbook Vol.4: Ceramics and Glasses — ASM International (1991)
  2. Zirconia (YSZ) powder and ceramic component data — Tosoh Corporation (2023)
  3. Zirconia technical ceramics datasheet — CoorsTek (2022)
  4. ASTM C1421 / ISO 13356 (yttria-stabilized tetragonal zirconia ceramics) — ASTM / ISO (2015)
  5. Solid oxide fuel cell electrolyte property compilations — NIST / open literature (2020)

Property data is compiled from published supplier and standards handbooks and normalised for comparison. Nothing on this page is a certification — request mill certs, CoC or material test reports with your order.