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PZT-4 NAVY-I

Grade · default condition

NAVY-I = navy Type I

Default choice for high-power ultrasonic and sonar transducers: Qm ≈ 500, d33 ≈ 290 pC/N, low loss under high drive.

High cost $$$$

Values for the NAVY-I condition

Other PZT-4 tempers and conditions

PZT-4 is listed in 3 conditions; see the grade overview at PZT-4.

Compare all 3 conditionsHide
Condition · open for datasheetBest forYield MPaTensile MPaElong. %HardnessConductivity
NAVY-IDefaultThis page
Navy Type I
Default choice for high-power ultrasonic and sonar transducers: Qm ≈ 500, d33 ≈ 290 pC/N, low loss under high drive.—750.1320 HV1 W/m·K
PZT-4D
Pick when a Navy-I-class hard material is needed but with more output/lower drive voltage; Qm drops somewhat versus standard PZT-4.—750.1310 HV1 W/m·K
Hot-pressed / high-density PZT-4
Use where near-zero porosity, higher strength and better uniformity are required (deep-submergence sonar rings, high stress prestressed stacks).—950.1350 HV1 W/m·K

What is PZT-4 NAVY-I?

PZT-4 NAVY-I is PZT-4 in the NAVY-I grade — default choice for high-power ultrasonic and sonar transducers: Qm ≈ 500, d33 ≈ 290 pC/N, low loss under high drive. PZT-4 NAVY-I has a tensile strength of 75 MPa (10.9 ksi), weaker than 56% of ceramic grades. Elongation at break is 0.1% and the elastic modulus is 70 GPa (10.2 Msi). PZT-4 NAVY-I has a density of 7.5 g/cm³ (0.271 lb/in³), heavier than 73% of ceramic grades.

Limitations

  • Poor heat conductor — 1.3 W/m·K (0.722 BTU/hr·ft·°F), worse than 95% of ceramic grades
  • Limited service temperature — 160°C (320 °F), worse than 88% of ceramic grades
  • Low fracture toughness — 1 MPa·√m (0.91 ksi·√in), worse than 84% of ceramic grades
  • Low stiffness — 70 GPa (10.2 Msi), worse than 79% of ceramic grades

PZT-4 NAVY-I properties

Typical room-temperature values for PZT-4 NAVY-I; 16 are specific to this condition. Other listed values are PZT-4 reference data and may not represent this condition. Bars are the position among ceramic grades.

Physical2

PZT-4 NAVY-I has a density of 7.5 g/cm³ (0.271 lb/in³), heavier than 73% of ceramic grades.

Density7.5 g/cm³0.27 lb/in³
Porosity1%

Mechanical13

PZT-4 NAVY-I has a tensile strength of 75 MPa (10.9 ksi), weaker than 56% of ceramic grades. Elongation at break is 0.1% and the elastic modulus is 70 GPa (10.2 Msi).

Elastic (Young's) Modulus70 GPa10.2 Msi
Shear Modulus26 GPa3.8 Msi
Bulk Modulus60 GPa8.7 Msi
Poisson's Ratio0.31
Tensile Strength (Ultimate)75 MPa10.9 ksi
Elongation at Break0.1%
Compressive Strength520 MPa75.4 ksi
Flexural Strength85 MPa12.3 ksi
Shear Strength65 MPa9.4 ksi
Fracture Toughness (K_IC)1 MPa·√m0.91 ksi·√in
Hardness, Vickers320 HV
Hardness, Knoop300 HK
Hardness, Mohs5

Thermal5

PZT-4 NAVY-I is rated for continuous service to 160°C (320 °F). It conducts heat at 1.3 W/m·K (0.722 BTU/hr·ft·°F), worse than 95% of ceramic grades. Thermal expansion is 4 µm/m·K (2.22 µin/in·°F).

Thermal Conductivity1.3 W/m·K0.72 BTU/hr·ft·°F
Specific Heat Capacity350 J/kg·K0.08 BTU/lb·°F
Thermal Expansion (CTE, 20–100 °C)4 µm/m·K2.2 µin/in·°F
Max Service Temperature (continuous)160°C320 °F
Min Service Temperature-50°C-58 °F

Electrical5

PZT-4 NAVY-I is an electrical insulator with a dielectric strength of 10 kV/mm (254 V/mil) and a resistivity of 1×10¹¹ Ω·m.

Electrical Resistivity1×10¹¹ Ω·m3.94×10¹⁸ µΩ·in
Dielectric Strength10 kV/mm254 V/mil
Dielectric Constant (1 MHz)1,300
Dissipation Factor (1 MHz)0.004
Volume Resistivity1×10¹³ Ω·cm

Chemical & Environmental2

Corrosion resistance is good (65/100), worse than 67% of ceramic grades.

Corrosion ResistanceGood65/100
Chemical Resistance SummaryStable in water, oils and common solvents; strong mineral acids (HCl, HNO3, HF) and hot alkalis leach lead and attack the perovskite; avoid ultrasonic cleaning in acidic baths and note lead content for RoHS-exempt handling.

Manufacturability3

PZT-4 NAVY-I's machinability is not recommended (12/100, better than 78% of ceramic grades).

MachinabilityNot recommended12/100
PolishabilityVery good70/100
Sintering / Firing Temperature1,275°C2,327 °F

Common Calculations4

Specific Strength (UTS / density)calculated10 kN·m/kg
Specific Stiffness (E / density)calculated9.3 MN·m/kg
Thermal Diffusivitycalculated0.5 mm²/s
Thermal Shock Resistance Indexcalculated0

Values are nominal handbook figures for design screening. Confirm any required mill or lot documentation when quoting.

Working with PZT-4 NAVY-I

Is PZT-4 easy to machine?

Green machining is preferred; fired parts only by diamond grinding, lapping, ultrasonic or laser cutting with coolant, keeping the part below ~150 °C to avoid depoling.

Can PZT-4 be welded?

Not weldable — electrodes are fired-on silver or sputtered Ni/Au and are attached with low-temperature solder (<230 °C, brief) or conductive epoxy; stacks are usually bonded or mechanically prestressed.

Can PZT-4 be formed, bent or molded?

Dry pressing, isostatic pressing or tape casting of doped PZT powder, binder burnout, sintering ~1250–1300 °C in a PbO-rich sealed setter, then DC poling at roughly 2–3 kV/mm above 100 °C.

What surface finishes work on PZT-4?

Lap electrode faces flat and parallel, apply fired silver or sputtered electrodes, then age at least 24 h before final property measurement; avoid acidic cleaners and mechanical shock.

PZT-4 chemical composition (wt %)

Limits by weight percent from the governing specification, written the way the spec states them — a single maximum for impurities, a range for alloying elements, and the base element as balance. Nominal is the typical mid-range value.

ElementSpec limit (wt %)Nominal
Pbas PbO in Pb(Zr,Ti)O3 perovskite; slight PbO excess used to suppress volatilisation60 – 6563.5
ZrZr/Ti ≈ 52/48, near morphotropic phase boundary13 – 1614.6
Ti6 – 87.1
Feacceptor dopant (as Fe2O3) giving the 'hard' high-Qm behaviour0.1 – 0.80.3
Sroptional A-site substitution used by some producers to tune Tc/K0 – 1.50.5
Operovskite oxygen, ≈14.7 wt %balance—

PZT-4 NAVY-I — frequently asked

What is PZT-4 NAVY-I used for?

PZT-4 NAVY-I is typically used for sonar transducers, ultrasonic cleaning/welding transducers, high-power actuators and NDT probes. In short: hard high-power piezoceramic; high mechanical Q; navy Type I equivalent.

What is the tensile strength of PZT-4 NAVY-I?

PZT-4 NAVY-I has a typical tensile strength of 75 MPa (10.9 ksi) — weaker than 56% of ceramic grades. Strength varies by condition: see the 3 listed tempers.

Is PZT-4 NAVY-I easy to machine?

Not especially — machinability is rated not recommended (12/100, better than 78% of ceramic grades). Green machining is preferred; fired parts only by diamond grinding, lapping, ultrasonic or laser cutting with coolant, keeping the part below ~150 °C to avoid depoling.

Can PZT-4 NAVY-I be welded?

Not weldable — electrodes are fired-on silver or sputtered Ni/Au and are attached with low-temperature solder (<230 °C, brief) or conductive epoxy; stacks are usually bonded or mechanically prestressed.

What surface finishes work on PZT-4 NAVY-I?

Lap electrode faces flat and parallel, apply fired silver or sputtered electrodes, then age at least 24 h before final property measurement; avoid acidic cleaners and mechanical shock.

Can PZT-4 NAVY-I be formed, bent or molded?

Dry pressing, isostatic pressing or tape casting of doped PZT powder, binder burnout, sintering ~1250–1300 °C in a PbO-rich sealed setter, then DC poling at roughly 2–3 kV/mm above 100 °C.

What is the maximum service temperature of PZT-4 NAVY-I?

PZT-4 NAVY-I is rated for continuous use to about 160°C (320 °F). Strength falls off well before that limit — check the elevated-temperature data for load-bearing parts.

Sources

  1. IEEE Std 176 — Standard on Piezoelectricity — IEEE (1987)
  2. MIL-STD-1376B — Piezoelectric Ceramic Material and Measurements Guidelines for Sonar Transducers — US DoD (1995)
  3. Hard PZT (Navy Type I) piezoceramic property sheets — Morgan Advanced Materials / APC International / Channel Industries (2022)
  4. Engineered Materials Handbook Vol. 4: Ceramics and Glasses — piezoelectric ceramics — ASM International (1991)

Property data is compiled from published supplier and standards handbooks and normalised for comparison. Nothing on this page is a certification — request mill certs, CoC or material test reports with your order.