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KNN TGG

Grade

TGG = textured (templated grain growth) <001> KNN

Choose textured <001> material grown from NaNbO3 platelet templates when piezoelectric constants must come closest to soft PZT; cost and process complexity are the highest of the family.

High cost $$$$

Values for the TGG condition

Other KNN tempers and conditions

KNN is listed in 5 conditions; see the grade overview at KNN.

Compare all 5 conditionsHide
Condition · open for datasheetBest forYield MPaTensile MPaElong. %HardnessConductivity
Undoped (K0.5Na0.5)NbO3, conventional air sintering
Use the undoped, conventionally air-sintered baseline when the highest Curie temperature (~410 °C) or an academic reference matters; piezoelectric response and density are lower.———330 HV2 W/m·K
TGGThis page
Textured (templated grain growth) <001> KNN
Choose textured <001> material grown from NaNbO3 platelet templates when piezoelectric constants must come closest to soft PZT; cost and process complexity are the highest of the family.———380 HV—
LTSDefault
Li/Ta/Sb-modified soft KNN
Choose the Li/Ta/Sb-modified soft composition, with its phase boundary shifted near room temperature, for the highest piezoelectric and dielectric response in buzzers, atomizer discs and sensors.———400 HV3 W/m·K
CuO/Mn-doped hard KNN for high-power resonators
Pick the acceptor-doped CuO/Mn hard type for high mechanical quality factor Qm and low loss under continuous high-power drive, such as ultrasonic welding horns and cleaning transducers.———420 HV—
HP/SPS
Use the hot-pressed or spark-plasma-sintered near-fully-dense route to suppress alkali volatilization and get the best strength, insulation and consistency in thin elements and high-field drive.———460 HV3 W/m·K

What is KNN TGG?

KNN TGG is KNN in the TGG grade — choose textured <001> material grown from NaNbO3 platelet templates when piezoelectric constants must come closest to soft PZT; cost and process complexity are the highest of the family. The elastic modulus is 100 GPa (14.5 Msi). KNN TGG has a density of 4.45 g/cm³ (0.161 lb/in³), lighter than 56% of ceramic grades. It melts at 1,140°C (2,084 °F). LTS is the default condition FabDigit quotes; TGG is available on request or by drawing note.

Limitations

  • Low fracture toughness — 0.9 MPa·√m (0.819 ksi·√in), worse than 96% of ceramic grades
  • Limited service temperature — 140°C (284 °F), worse than 92% of ceramic grades
  • Poor heat conductor — 2.5 W/m·K (1.44 BTU/hr·ft·°F), worse than 83% of ceramic grades

KNN TGG properties

Typical room-temperature values for KNN TGG; 11 are specific to this condition. Other listed values are KNN reference data and may not represent this condition. Bars are the position among ceramic grades.

Physical4

KNN TGG has a density of 4.45 g/cm³ (0.161 lb/in³), lighter than 56% of ceramic grades. It melts at 1,140°C (2,084 °F).

Density4.45 g/cm³0.16 lb/in³
Melting Point (Solidus)1,140°C2,084 °F
Refractive Index2.2
Porosity2%

Mechanical9

The elastic modulus is 100 GPa (14.5 Msi).

Elastic (Young's) Modulus100 GPa14.5 Msi
Shear Modulus40 GPa5.8 Msi
Bulk Modulus88 GPa12.8 Msi
Poisson's Ratio0.3
Compressive Strength550 MPa79.8 ksi
Flexural Strength90 MPa13.1 ksi
Fracture Toughness (K_IC)0.9 MPa·√m0.82 ksi·√in
Hardness, Vickers380 HV
Hardness, Mohs5.5

Thermal5

KNN TGG is rated for continuous service to 140°C (284 °F). It conducts heat at 2.5 W/m·K (1.44 BTU/hr·ft·°F), worse than 83% of ceramic grades. Thermal expansion is 7 µm/m·K (3.89 µin/in·°F).

Thermal Conductivity2.5 W/m·K1.4 BTU/hr·ft·°F
Specific Heat Capacity420 J/kg·K0.1 BTU/lb·°F
Thermal Expansion (CTE, 20–100 °C)7 µm/m·K3.9 µin/in·°F
Max Service Temperature (continuous)140°C284 °F
Min Service Temperature-50°C-58 °F

Electrical5

KNN TGG is an electrical insulator with a dielectric strength of 6 kV/mm (152.4 V/mil) and a resistivity of 1×10⁹ Ω·m.

Electrical Resistivity1×10⁹ Ω·m3.94×10¹⁶ µΩ·in
Dielectric Strength6 kV/mm152 V/mil
Dielectric Constant (1 MHz)1,400
Dissipation Factor (1 MHz)0.03
Volume Resistivity1×10¹¹ Ω·cm

Chemical & Environmental2

Corrosion resistance is good (62/100), worse than 70% of ceramic grades.

Corrosion ResistanceGood62/100
Chemical Resistance Summary—

Sustainability4

Producing a kilogram of KNN TGG takes about 160 MJ of energy and emits 11 kg of CO₂ — more than 59% of ceramic grades. Typical recycled content is 0%.

Embodied Energy (primary production)160 MJ/kg68,788 BTU/lb
Embodied Carbon (primary production)11 kg CO₂/kg
Embodied Water250 L/kg30 gal/lb
Typical Recycled Content0%

Manufacturability3

KNN TGG's machinability is not recommended (7/100, better than 63% of ceramic grades).

MachinabilityNot recommended7/100
PolishabilityVery good70/100
Sintering / Firing Temperature1,130°C2,066 °F

Values are nominal handbook figures for design screening. Confirm any required mill or lot documentation when quoting.

Working with KNN TGG

Is KNN easy to machine?

After firing, only diamond grinding, ultrasonic drilling or laser cutting is possible; machining in the green or bisque state is by far the cheapest route. Anneal after grinding to remove surface residual stress before poling.

Can KNN be welded?

The ceramic is not weldable. Metal connection is made through fired silver-paste electrodes followed by soft soldering below 250 °C to avoid depoling, or by conductive adhesive.

Can KNN be formed, bent or molded?

Dry pressing, cold isostatic pressing and tape casting are all usable. The sintering window is narrow (about ±20 °C), so fire in sealed saggars with excess alkali in the batch to compensate K/Na volatilisation, otherwise second phases and abnormal grain growth appear.

What surface finishes work on KNN?

Screen-print and fire silver electrodes at roughly 700–800 °C, or sputter Cr/Au. Pole at 2–4 kV/mm in silicone oil at 80–120 °C and age 24 h; finished parts need moisture-barrier packaging.

KNN chemical composition (wt %)

Limits by weight percent from the governing specification, written the way the spec states them — a single maximum for impurities, a range for alloying elements, and the base element as balance. Nominal is the typical mid-range value.

ElementSpec limit (wt %)Nominal
Nbadded as Nb2O5; partly replaced by Ta/Sb in modified grades50 – 5554
Kfrom K2CO3; volatile in sintering, added in excess to compensate10 – 1211.4
Naintroduced as Na2CO36 – 7.56.7
LiA-site dopant in modified (LTS) grades, ~3–6 mol%0 – 0.50.15
TaB-site substitution for Nb in modified grades, ~10–20 mol%0 – 126
SbB-site substitution in modified grades, ~3–7 mol%0 – 41.5
Ooxygen site of perovskite ABO3, ~28 wt%balance—

KNN TGG — frequently asked

What is KNN TGG used for?

KNN TGG is typically used for lead-free piezo actuators, lead-free sensors and green electronics components. In short: lead-free PZT alternative; narrow sintering window; lower density than PZT.

Is KNN TGG easy to machine?

Not especially — machinability is rated not recommended (7/100, better than 63% of ceramic grades). After firing, only diamond grinding, ultrasonic drilling or laser cutting is possible; machining in the green or bisque state is by far the cheapest route. Anneal after grinding to remove surface residual stress before poling.

Can KNN TGG be welded?

The ceramic is not weldable. Metal connection is made through fired silver-paste electrodes followed by soft soldering below 250 °C to avoid depoling, or by conductive adhesive.

What surface finishes work on KNN TGG?

Screen-print and fire silver electrodes at roughly 700–800 °C, or sputter Cr/Au. Pole at 2–4 kV/mm in silicone oil at 80–120 °C and age 24 h; finished parts need moisture-barrier packaging.

Can KNN TGG be formed, bent or molded?

Dry pressing, cold isostatic pressing and tape casting are all usable. The sintering window is narrow (about ±20 °C), so fire in sealed saggars with excess alkali in the batch to compensate K/Na volatilisation, otherwise second phases and abnormal grain growth appear.

What is the maximum service temperature of KNN TGG?

KNN TGG is rated for continuous use to about 140°C (284 °F). Strength falls off well before that limit — check the elevated-temperature data for load-bearing parts.

Sources

  1. ASM Engineered Materials Handbook Vol.4: Ceramics and Glasses — ASM International (1991)
  2. IEEE 176 Standard on Piezoelectricity — IEEE (1987)
  3. Lead-free piezoceramics (KNN) property reviews — Journal of the American Ceramic Society / Journal of Materials Chemistry C (2019)

Property data is compiled from published supplier and standards handbooks and normalised for comparison. Nothing on this page is a certification — request mill certs, CoC or material test reports with your order.