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Refractory Metal ZIRLO OPT-ZIRLO

Grade

Lower Sn (~0.67 %) version for high-burnup cores: further reduced corrosion and hydrogen pickup at the cost of slightly lower strength.

High cost $$$$

Values for the OPT-ZIRLO condition

Other ZIRLO tempers and conditions

ZIRLO is listed in 4 conditions; see the grade overview at ZIRLO.

Compare all 4 conditionsHide
Condition · open for datasheetBest forYield MPaTensile MPaElong. %HardnessConductivity
Fully recrystallized annealed
Choose for spacer-grid strip and components needing maximum ductility, formability and low irradiation growth.32047028152 HB2.6 % IACS
Partially recrystallized annealed
Intermediate anneal used for guide tubes and some cladding designs balancing creep strength with irradiation-growth stability.42056021176 HB2.5 % IACS
OPT-ZIRLOThis page
reduced-tin variant, CWSR/PRXA tube
Lower Sn (~0.67 %) version for high-burnup cores: further reduced corrosion and hydrogen pickup at the cost of slightly lower strength.4906101812 HRC2.5 % IACS
CWSRDefault
Cold worked and stress-relief annealed
Standard PWR fuel cladding tube condition: highest strength and creep resistance under rod internal pressure.5306501614 HRC2.4 % IACS

What is ZIRLO OPT-ZIRLO?

ZIRLO OPT-ZIRLO is ZIRLO in the OPT-ZIRLO grade — lower Sn (~0.67 %) version for high-burnup cores: further reduced corrosion and hydrogen pickup at the cost of slightly lower strength. ZIRLO OPT-ZIRLO has a yield strength of 490 MPa (71.1 ksi) and a tensile strength of 610 MPa (88.5 ksi) — stronger than 75% of refractory metal grades. Elongation at break is 18% and the elastic modulus is 99 GPa (14.4 Msi). ZIRLO OPT-ZIRLO has a density of 6.55 g/cm³ (0.237 lb/in³), lighter than 77% of refractory metal grades. It melts at 1,840°C (3,344 °F). CWSR is the default condition FabDigit quotes; OPT-ZIRLO is available on request or by drawing note.

Advantages

  • Lightweight — 6.55 g/cm³ (0.237 lb/in³), better than 77% of refractory metal grades
  • High strength — 490 MPa (71.1 ksi), better than 75% of refractory metal grades

Limitations

  • Low electrical conductivity — 2.5 % IACS, worse than 86% of refractory metal grades
  • Poor heat conductor — 14.8 W/m·K (8.55 BTU/hr·ft·°F), worse than 83% of refractory metal grades
  • Low stiffness — 99 GPa (14.4 Msi), worse than 79% of refractory metal grades
  • High embodied carbon — 95 kg CO₂/kg, worse than 75% of refractory metal grades

ZIRLO OPT-ZIRLO properties

Typical room-temperature values for ZIRLO OPT-ZIRLO; 23 are specific to this condition. Other listed values are ZIRLO reference data and may not represent this condition. Bars are the position among refractory metal grades.

Physical3

ZIRLO OPT-ZIRLO has a density of 6.55 g/cm³ (0.237 lb/in³), lighter than 77% of refractory metal grades. It melts at 1,840°C (3,344 °F).

Density6.55 g/cm³0.24 lb/in³
Melting Point (Solidus)1,840°C3,344 °F
Liquidus Temperature1,870°C3,398 °F

Mechanical17

ZIRLO OPT-ZIRLO has a yield strength of 490 MPa (71.1 ksi) and a tensile strength of 610 MPa (88.5 ksi) — stronger than 75% of refractory metal grades. Elongation at break is 18% and the elastic modulus is 99 GPa (14.4 Msi).

Elastic (Young's) Modulus99 GPa14.4 Msi
Shear Modulus36 GPa5.2 Msi
Bulk Modulus98 GPa14.2 Msi
Poisson's Ratio0.37
Tensile Strength (Ultimate)610 MPa88.5 ksi
Yield Strength (0.2% offset)490 MPa71.1 ksi
Elongation at Break18%
Reduction in Area52%
Compressive Strength520 MPa75.4 ksi
Shear Strength370 MPa53.7 ksi
Fatigue Strength (Endurance Limit)235 MPa34.1 ksi
Fracture Toughness (K_IC)58 MPa·√m52.8 ksi·√in
Charpy V-Notch Impact (RT)48 J35.4 ft·lbf
Hardness, Brinell182 HB
Hardness, Rockwell B91 HRB
Hardness, Rockwell C12 HRC
Hardness, Vickers195 HV

Thermal6

ZIRLO OPT-ZIRLO is rated for continuous service to 400°C (752 °F). It conducts heat at 14.8 W/m·K (8.55 BTU/hr·ft·°F), worse than 83% of refractory metal grades. Thermal expansion is 6 µm/m·K (3.33 µin/in·°F).

Thermal Conductivity14.8 W/m·K8.6 BTU/hr·ft·°F
Specific Heat Capacity285 J/kg·K0.07 BTU/lb·°F
Thermal Expansion (CTE, 20–100 °C)6 µm/m·K3.3 µin/in·°F
Latent Heat of Fusion155 J/g66.6 BTU/lb
Max Service Temperature (continuous)400°C752 °F
Min Service Temperature-196°C-321 °F

Electrical3

ZIRLO OPT-ZIRLO conducts electricity at 2.5 % IACS, worse than 86% of refractory metal grades.

Electrical Conductivity2.5 % IACS
Electrical Resistivity6.9×10⁻⁷ Ω·m27.2 µΩ·in
Magnetic Responsenon-magnetic

Chemical & Environmental3

Corrosion resistance is excellent (94/100), better than 94% of refractory metal grades.

Galvanic Potential (seawater, vs SCE)-0.25 V
Corrosion ResistanceExcellent94/100
Chemical Resistance SummaryExcellent in high-temperature water, steam, most alkalis and organic acids; attacked by HF, fluoride-bearing media, concentrated H2SO4 above ~70 % and hot oxidizing chlorides; pyrophoric as fine chips or powder.

Sustainability4

Producing a kilogram of ZIRLO OPT-ZIRLO takes about 1,500 MJ of energy and emits 95 kg of CO₂ — more than 77% of refractory metal grades. Typical recycled content is 15%.

Embodied Energy (primary production)1,500 MJ/kg644,885 BTU/lb
Embodied Carbon (primary production)95 kg CO₂/kg
Embodied Water700 L/kg83.9 gal/lb
Typical Recycled Content15%

Manufacturability8

ZIRLO OPT-ZIRLO's machinability is poor (32/100, better than 67% of refractory metal grades); weldability very good (70/100); formability fair (48/100).

MachinabilityPoor32/100
Machinability Rating (AISI 1212 = 100 %)22%
WeldabilityVery good70/100
Formability (cold)Fair48/100
CastabilityPoor30/100
Brazeability / SolderabilityPoor25/100
PolishabilityGood60/100
Anodizing Responsefair — Zr can be anodically oxidized for coloured/decorative or pre-oxidised films, but reactor components rely on the natural autoclave-grown oxide, not anodising.

Values are nominal handbook figures for design screening. Confirm any required mill or lot documentation when quoting.

Working with ZIRLO OPT-ZIRLO

Is ZIRLO easy to machine?

Machine slow with sharp, positive-rake carbide, heavy flood coolant and no dwelling; fine chips are pyrophoric so keep swarf wet and segregated.

Can ZIRLO be welded?

GTAW with high-purity argon/helium plus full trailing and back purge, or EB/laser in vacuum; any O/N/H pickup embrittles the joint, and post-weld stress relief ~500–550 °C is common.

Can ZIRLO be formed, bent or molded?

Tube produced by repeated cold pilgering with intermediate vacuum anneals; strip forms well in RXA condition but strong basal texture makes properties markedly anisotropic.

What surface finishes work on ZIRLO?

Final surface is pickled and autoclaved (400 °C steam) to grow a protective black oxide; avoid iron contamination and fluoride-bearing pickling residues.

ZIRLO chemical composition (wt %)

Limits by weight percent from the governing specification, written the way the spec states them — a single maximum for impurities, a range for alloying elements, and the base element as balance. Nominal is the typical mid-range value.

ElementSpec limit (wt %)Nominal
Nbprimary corrosion/creep alloying addition0.8 – 1.21
Sn≈0.6–0.8 % in Optimized ZIRLO0.8 – 1.21
Fe0.09 – 0.130.1
Ocontrolled for strength0.09 – 0.160.12
Hfnuclear grade, low neutron-absorption limit≤ 0.010.01
C≤ 0.030.02
N≤ 0.010
Zrbalance—

ZIRLO OPT-ZIRLO — frequently asked

What is ZIRLO OPT-ZIRLO used for?

ZIRLO OPT-ZIRLO is typically used for PWR fuel rod cladding, fuel assembly guide tubes, spacer grids and nuclear structural components. In short: upgraded PWR cladding alloy; better creep than Zircaloy-4; low neutron absorption.

What is the yield strength of ZIRLO OPT-ZIRLO?

ZIRLO OPT-ZIRLO has a typical yield strength of 490 MPa (71.1 ksi) and a tensile strength of 610 MPa (88.5 ksi) — stronger than 75% of refractory metal grades. Strength varies by condition: see the 4 listed tempers.

Is ZIRLO OPT-ZIRLO easy to machine?

Not especially — machinability is rated poor (32/100, better than 67% of refractory metal grades). Machine slow with sharp, positive-rake carbide, heavy flood coolant and no dwelling; fine chips are pyrophoric so keep swarf wet and segregated.

Can ZIRLO OPT-ZIRLO be welded?

Yes — weldability is rated very good (70/100). GTAW with high-purity argon/helium plus full trailing and back purge, or EB/laser in vacuum; any O/N/H pickup embrittles the joint, and post-weld stress relief ~500–550 °C is common.

What surface finishes work on ZIRLO OPT-ZIRLO?

Final surface is pickled and autoclaved (400 °C steam) to grow a protective black oxide; avoid iron contamination and fluoride-bearing pickling residues.

Can ZIRLO OPT-ZIRLO be formed, bent or molded?

Tube produced by repeated cold pilgering with intermediate vacuum anneals; strip forms well in RXA condition but strong basal texture makes properties markedly anisotropic.

What is the maximum service temperature of ZIRLO OPT-ZIRLO?

ZIRLO OPT-ZIRLO is rated for continuous use to about 400°C (752 °F). Strength falls off well before that limit — check the elevated-temperature data for load-bearing parts.

What is the difference between ZIRLO CWSR and ZIRLO-RXA?

CWSR is the default condition — standard PWR fuel cladding tube condition: highest strength and creep resistance under rod internal pressure. RXA: choose for spacer-grid strip and components needing maximum ductility, formability and low irradiation growth. Yield strength is 530 MPa in CWSR versus 320 MPa in RXA.

Sources

  1. ASTM B811 — Wrought Zirconium Alloy Seamless Tubes for Nuclear Reactor Fuel Cladding — ASTM International (2021)
  2. ASTM B350/B350M — Zirconium and Zirconium Alloy Ingots for Nuclear Application — ASTM International (2022)
  3. ZIRLO / Optimized ZIRLO fuel cladding topical reports — Westinghouse Electric Company (2010)
  4. ASM Handbook Vol. 2 — Properties of Zirconium and Zirconium Alloys — ASM International (1990)
  5. MATPRO / SCDAP-RELAP5 zirconium alloy material property correlations — US NRC / INL (2003)
  6. IAEA TECDOC — Waterside corrosion of zirconium alloys in nuclear power plants — IAEA (1998)

Property data is compiled from published supplier and standards handbooks and normalised for comparison. Nothing on this page is a certification — request mill certs, CoC or material test reports with your order.