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Refractory Metal M5-BQ (Beta-quenched)

Heat-treated state

Specify as a process intermediate: the beta quench refines the structure and homogenises Nb distribution before final cold tube reduction and recrystallisation, giving the best corrosion microstructure.

High cost $$$$

Values for the BQ condition

Other M5 tempers and conditions

M5 is listed in 5 conditions; see the grade overview at M5.

Compare all 5 conditionsHide
Condition · open for datasheetBest forYield MPaTensile MPaElong. %HardnessConductivity
BQThis page
Beta-quenched
Specify as a process intermediate: the beta quench refines the structure and homogenises Nb distribution before final cold tube reduction and recrystallisation, giving the best corrosion microstructure.31045028170 HB3 % IACS
RXADefault
Fully recrystallized annealed
Pick the fully recrystallized annealed state for PWR fuel cladding tubes: best corrosion, irradiation growth and creep behaviour with 30% elongation, at the lowest strength of 330 MPa yield.33047030165 HB3.1 % IACS
Partially recrystallized annealed
Use the partially recrystallized annealed state for spacer grid straps and some structural tubing, giving 420 MPa yield with more ductility and creep margin than the stress-relieved condition.42053020184 HB3.1 % IACS
Cold worked and stress-relief annealed
Choose cold worked and stress-relief annealed material for guide tubes and structural members needing 500 MPa yield at operating temperature, accepting lower ductility and creep resistance.50059015198 HB3.1 % IACS
Cold worked
Use only as an intermediate as-pilgered hollow, where strength peaks at 620 MPa yield / 700 MPa tensile with 8% elongation; residual stress and texture are unadjusted, so it is not a final delivery condition.620700821 HRC3 % IACS

What is M5-BQ?

M5-BQ is M5 heat treated to BQ — specify as a process intermediate: the beta quench refines the structure and homogenises Nb distribution before final cold tube reduction and recrystallisation, giving the best corrosion microstructure. M5-BQ has a yield strength of 310 MPa (45 ksi) and a tensile strength of 450 MPa (65.3 ksi) — weaker than 55% of refractory metal grades. Elongation at break is 28% and the elastic modulus is 99 GPa (14.4 Msi). M5-BQ has a density of 6.55 g/cm³ (0.237 lb/in³), lighter than 77% of refractory metal grades. It melts at 1,840°C (3,344 °F). RXA is the default condition FabDigit quotes; BQ is available on request or by drawing note.

Advantages

  • Ductile — tolerates forming and impact — 28%, better than 80% of refractory metal grades
  • Lightweight — 6.55 g/cm³ (0.237 lb/in³), better than 77% of refractory metal grades

Limitations

  • Low electrical conductivity — 3 % IACS, worse than 81% of refractory metal grades
  • Low stiffness — 99 GPa (14.4 Msi), worse than 79% of refractory metal grades

M5-BQ properties

Typical room-temperature values for M5-BQ; 22 are specific to this condition. Other listed values are M5 reference data and may not represent this condition. Bars are the position among refractory metal grades.

Physical3

M5-BQ has a density of 6.55 g/cm³ (0.237 lb/in³), lighter than 77% of refractory metal grades. It melts at 1,840°C (3,344 °F).

Density6.55 g/cm³0.24 lb/in³
Melting Point (Solidus)1,840°C3,344 °F
Liquidus Temperature1,860°C3,380 °F

Mechanical16

M5-BQ has a yield strength of 310 MPa (45 ksi) and a tensile strength of 450 MPa (65.3 ksi) — weaker than 55% of refractory metal grades. Elongation at break is 28% and the elastic modulus is 99 GPa (14.4 Msi).

Elastic (Young's) Modulus99 GPa14.4 Msi
Shear Modulus36 GPa5.2 Msi
Bulk Modulus100 GPa14.5 Msi
Poisson's Ratio0.35
Tensile Strength (Ultimate)450 MPa65.3 ksi
Yield Strength (0.2% offset)310 MPa45 ksi
Elongation at Break28%
Reduction in Area52%
Compressive Strength320 MPa46.4 ksi
Shear Strength280 MPa40.6 ksi
Fatigue Strength (Endurance Limit)190 MPa27.6 ksi
Fracture Toughness (K_IC)55 MPa·√m50.1 ksi·√in
Charpy V-Notch Impact (RT)32 J23.6 ft·lbf
Hardness, Brinell170 HB
Hardness, Rockwell B89 HRB
Hardness, Vickers180 HV

Thermal6

M5-BQ is rated for continuous service to 400°C (752 °F). It conducts heat at 17.5 W/m·K (10.1 BTU/hr·ft·°F), worse than 72% of refractory metal grades. Thermal expansion is 5.8 µm/m·K (3.22 µin/in·°F).

Thermal Conductivity17.5 W/m·K10.1 BTU/hr·ft·°F
Specific Heat Capacity285 J/kg·K0.07 BTU/lb·°F
Thermal Expansion (CTE, 20–100 °C)5.8 µm/m·K3.2 µin/in·°F
Latent Heat of Fusion153 J/g65.8 BTU/lb
Max Service Temperature (continuous)400°C752 °F
Min Service Temperature-196°C-321 °F

Electrical3

M5-BQ conducts electricity at 3 % IACS, worse than 81% of refractory metal grades.

Electrical Conductivity3 % IACS
Electrical Resistivity5.7×10⁻⁷ Ω·m22.4 µΩ·in
Magnetic Responsenon-magnetic

Chemical & Environmental3

Corrosion resistance is excellent (92/100), better than 86% of refractory metal grades.

Galvanic Potential (seawater, vs SCE)-0.3 V
Corrosion ResistanceExcellent92/100
Chemical Resistance Summary—

Sustainability4

Producing a kilogram of M5-BQ takes about 1,250 MJ of energy and emits 80 kg of CO₂ — more than 52% of refractory metal grades. Typical recycled content is 15%.

Embodied Energy (primary production)1,250 MJ/kg537,404 BTU/lb
Embodied Carbon (primary production)80 kg CO₂/kg
Embodied Water600 L/kg71.9 gal/lb
Typical Recycled Content15%

Manufacturability8

M5-BQ's machinability is poor (30/100, better than 54% of refractory metal grades); weldability very good (70/100); formability good (62/100).

MachinabilityPoor30/100
Machinability Rating (AISI 1212 = 100 %)25%
WeldabilityVery good70/100
Formability (cold)Good62/100
CastabilityPoor25/100
Brazeability / SolderabilityPoor30/100
PolishabilityVery good70/100
Anodizing Response—

Values are nominal handbook figures for design screening. Confirm any required mill or lot documentation when quoting.

Working with M5-BQ

Is M5 easy to machine?

Run low speed with heavy feed using sharp carbide tooling and ample water-based coolant. Chips form a combustible powder that must be collected separately; never grind or machine dry.

Can M5 be welded?

Use GTAW, electron-beam or laser welding (typical for end-plug closures) in a vacuum chamber or under full inert-gas shielding. Trace oxygen, nitrogen or hydrogen contamination causes embrittlement — an acceptable weld must stay bright silver.

Can M5 be formed, bent or molded?

Tube is made from extruded hollows by multi-pass cold pilgering with intermediate vacuum anneals. Room-temperature forming needs generous bend radii to avoid twin cracking and to control springback.

What surface finishes work on M5?

HNO3/HF pickling for decontamination followed by polishing is standard. The protective oxide forms in service, so plating and coatings are normally omitted; remove all fluoride residues.

M5 chemical composition (wt %)

Limits by weight percent from the governing specification, written the way the spec states them — a single maximum for impurities, a range for alloying elements, and the base element as balance. Nominal is the typical mid-range value.

ElementSpec limit (wt %)Nominal
Nbmain alloying element; forms β-Nb precipitates0.8 – 1.21
Osolid-solution strengthening, tightly controlled0.09 – 0.150.13
Fecontrolled trace addition0.02 – 0.060.04
Strace S improves creep resistance8×10⁻⁴ – 00
SnSn-free design (residual only)≤ 0.010.01
C≤ 0.020.01
N≤ 0.010
Hfnuclear grade: Hf removed to lower neutron absorption≤ 0.010.01
Cr≤ 0.020.01
Ni≤ 0.010
Zrbalance—

M5-BQ — frequently asked

What is M5-BQ used for?

M5-BQ is typically used for PWR fuel rod cladding, fuel assembly guide tubes, fuel rod end plugs, spacer grid strip and nuclear fuel assembly components. In short: lowest-corrosion Zr-Nb cladding; low in-reactor hydrogen pickup; high ductility, 30% elongation.

What is the yield strength of M5-BQ?

M5-BQ has a typical yield strength of 310 MPa (45 ksi) and a tensile strength of 450 MPa (65.3 ksi) — weaker than 55% of refractory metal grades. Strength varies by condition: see the 5 listed tempers.

Is M5-BQ easy to machine?

Not especially — machinability is rated poor (30/100, better than 54% of refractory metal grades). Run low speed with heavy feed using sharp carbide tooling and ample water-based coolant. Chips form a combustible powder that must be collected separately; never grind or machine dry.

Can M5-BQ be welded?

Yes — weldability is rated very good (70/100). Use GTAW, electron-beam or laser welding (typical for end-plug closures) in a vacuum chamber or under full inert-gas shielding. Trace oxygen, nitrogen or hydrogen contamination causes embrittlement — an acceptable weld must stay bright silver.

What surface finishes work on M5-BQ?

HNO3/HF pickling for decontamination followed by polishing is standard. The protective oxide forms in service, so plating and coatings are normally omitted; remove all fluoride residues.

Can M5-BQ be formed, bent or molded?

Tube is made from extruded hollows by multi-pass cold pilgering with intermediate vacuum anneals. Room-temperature forming needs generous bend radii to avoid twin cracking and to control springback.

What is the maximum service temperature of M5-BQ?

M5-BQ is rated for continuous use to about 400°C (752 °F). Strength falls off well before that limit — check the elevated-temperature data for load-bearing parts.

What is the difference between M5-RXA and M5-CW?

RXA is the default condition — pick the fully recrystallized annealed state for PWR fuel cladding tubes: best corrosion, irradiation growth and creep behaviour with 30% elongation, at the lowest strength of 330 MPa yield. CW: use only as an intermediate as-pilgered hollow, where strength peaks at 620 MPa yield / 700 MPa tensile with 8% elongation; residual stress and texture are unadjusted, so it is not a final delivery condition. Yield strength is 330 MPa in RXA versus 620 MPa in CW.

Sources

  1. ASTM B811 — Wrought Zirconium Alloy Seamless Tubes for Nuclear Reactor Fuel Cladding — ASTM International (2021)
  2. ASTM B350/B350M — Zirconium and Zirconium Alloy Ingots for Nuclear Application — ASTM International (2022)
  3. ASM Handbook Vol. 2 — Properties and Selection: Nonferrous Alloys (Zirconium) — ASM International (1990)
  4. Thermophysical Properties of Materials for Nuclear Engineering (Zr alloys) — IAEA (2008)
  5. M5 fuel cladding alloy technical publications — Framatome (AREVA NP) (2018)

Property data is compiled from published supplier and standards handbooks and normalised for comparison. Nothing on this page is a certification — request mill certs, CoC or material test reports with your order.