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BMI Tough

Grade

Tough = toughened BMI

Pick when damage tolerance / CAI and hot-wet toughness matter (primary aerostructure prepreg) and a 20–40 °C Tg loss is acceptable.

High cost $$$$

Values for the Tough condition

Other BMI grades and fills

BMI is listed in 9 conditions; see the grade overview at BMI.

Compare all 9 grades and fillsHide
Grade · open for datasheetBest forYield MPaTensile MPaElong. %Hardness
Silica / mineral filled BMI
Pick for high-Tg encapsulation, chip-carrier and dimensionally stable insulating parts where CTE must approach that of metal/ceramic.—600.8—
Graphite / PTFE lubricated BMI
Self-lubricating high-temperature bushings, wear pads and seal rings running dry to about 230 °C.—60188 Shore D
NEATDefault
Neat cured resin
Baseline cast/cured BMI used for property benchmarking, tooling resin, potting and small high-temperature parts.—722—
Low-viscosity RTM / infusion grade
Choose for resin transfer moulding or VARTM of thick high-temperature parts where injection viscosity below ~0.5 Pa·s at 120–140 °C is required.—752.2—
ToughThis page
Toughened BMI
Pick when damage tolerance / CAI and hot-wet toughness matter (primary aerostructure prepreg) and a 20–40 °C Tg loss is acceptable.—823.5—
Chopped carbon-fiber BMI molding compound
For net-shape compression-molded brackets, fasteners, seals and bushing bodies at 200 °C+ where laminate lay-up is uneconomic.—1501—
Glass-fabric reinforced BMI laminate (~60 vol% E-glass)
Use for high-temperature electrically insulating structures, radomes, motor/generator parts and high-Tg PCB substrates (BT/BMI laminate).—4501.8—
Woven carbon-fabric/BMI laminate
Choose for drapeable, balanced-property high-temperature panels, ducts and hot tooling where UD tape is impractical.—8001.2—
Unidirectional carbon-fiber/BMI laminate
The main structural form of BMI: hot engine nacelles, missile/hypersonic skins, supersonic aircraft structure needing 180–230 °C service.—2,1001.5—

What is BMI Tough?

BMI Tough is BMI in the Tough grade — pick when damage tolerance / CAI and hot-wet toughness matter (primary aerostructure prepreg) and a 20–40 °C Tg loss is acceptable. BMI Tough has a tensile strength of 82 MPa (11.9 ksi), stronger than 84% of polymer grades. Elongation at break is 3.5% and the elastic modulus is 3.6 GPa (0.522 Msi). BMI Tough has a density of 1.28 g/cm³ (0.0462 lb/in³), heavier than 67% of polymer grades. Its glass-transition temperature is 265°C (509 °F). NEAT is the default condition FabDigit quotes; Tough is available on request or by drawing note.

Advantages

  • High service temperature — 205°C (401 °F), better than 88% of polymer grades
  • Stiff — 3.6 GPa (0.522 Msi), better than 84% of polymer grades
  • Low, predictable mold shrinkage — 0.4%, better than 82% of polymer grades

Limitations

  • Difficult to weld — 0/100, worse than 98% of polymer grades
  • Limited formability — 5/100, worse than 95% of polymer grades
  • High embodied carbon — 9.5 kg CO₂/kg, worse than 89% of polymer grades
  • Limited ductility — 3.5%, worse than 79% of polymer grades

BMI Tough properties

Typical room-temperature values for BMI Tough; 11 are specific to this condition. Other listed values are BMI reference data and may not represent this condition. Bars are the position among polymer grades.

Physical4

BMI Tough has a density of 1.28 g/cm³ (0.0462 lb/in³), heavier than 67% of polymer grades. Its glass-transition temperature is 265°C (509 °F).

Density1.28 g/cm³0.05 lb/in³
Glass Transition (Tg)265°C509 °F
Water Absorption (24 h)0.35%
Water Absorption (Saturation)4%

Mechanical13

BMI Tough has a tensile strength of 82 MPa (11.9 ksi), stronger than 84% of polymer grades. Elongation at break is 3.5% and the elastic modulus is 3.6 GPa (0.522 Msi).

Elastic (Young's) Modulus3.6 GPa0.52 Msi
Shear Modulus1.5 GPa0.21 Msi
Poisson's Ratio0.35
Tensile Strength (Ultimate)82 MPa11.9 ksi
Elongation at Break3.5%
Compressive Strength200 MPa29 ksi
Compressive Modulus4.1 GPa0.59 Msi
Flexural Strength135 MPa19.6 ksi
Flexural Modulus3.7 GPa0.54 Msi
Shear Strength55 MPa8 ksi
Fracture Toughness (K_IC)1.5 MPa·√m1.4 ksi·√in
Izod Impact, Notched45 J/m0.84 ft·lbf/in
Hardness, Rockwell M115 HRM

Thermal10

BMI Tough is rated for continuous service to 205°C (401 °F). It conducts heat at 0.21 W/m·K (0.121 BTU/hr·ft·°F), better than 55% of polymer grades. Thermal expansion is 40 µm/m·K (22.2 µin/in·°F).

Thermal Conductivity0.21 W/m·K0.12 BTU/hr·ft·°F
Specific Heat Capacity1,150 J/kg·K0.27 BTU/lb·°F
Thermal Expansion (CTE, 20–100 °C)40 µm/m·K22.2 µin/in·°F
Max Service Temperature (continuous)205°C401 °F
Min Service Temperature-70°C-94 °F
Heat Deflection Temp. @ 0.45 MPa300°C572 °F
Heat Deflection Temp. @ 1.8 MPa280°C536 °F
Flammability (UL 94)V-0 (inherently flame retardant, low smoke; no halogen additive needed)
Limiting Oxygen Index38%
Max Service Temperature (short-term)300°C572 °F

Electrical7

BMI Tough is an electrical insulator with a dielectric strength of 20 kV/mm (508 V/mil) and a resistivity of 1×10¹³ Ω·m.

Electrical Resistivity1×10¹³ Ω·m3.94×10²⁰ µΩ·in
Dielectric Strength20 kV/mm508 V/mil
Dielectric Constant (1 MHz)3.4
Dissipation Factor (1 MHz)0.008
Volume Resistivity1×10¹⁵ Ω·cm
Surface Resistivity1×10¹⁴ Ω
Comparative Tracking Index (CTI)200 V

Chemical & Environmental3

Corrosion resistance is excellent (85/100), better than 65% of polymer grades. UV resistance is fair.

Corrosion ResistanceExcellent85/100
UV / Weathering ResistanceFair35/100
Chemical Resistance SummaryVery good against fuels, hydraulic fluids (Skydrol), oils, aliphatic/aromatic solvents, dilute acids and salt spray; attacked by hot strong alkali and hot concentrated acids; primary amines and steam/hot-wet exposure degrade the imide network and depress hot-wet Tg; requires paint for outdoor UV.

Sustainability4

Producing a kilogram of BMI Tough takes about 190 MJ of energy and emits 9.5 kg of CO₂ — more than 88% of polymer grades. Typical recycled content is 0%.

Embodied Energy (primary production)190 MJ/kg81,685 BTU/lb
Embodied Carbon (primary production)9.5 kg CO₂/kg
Embodied Water300 L/kg35.9 gal/lb
Typical Recycled Content0%

Manufacturability7

BMI Tough's machinability is good (55/100, worse than 64% of polymer grades); weldability not recommended (0/100); formability not recommended (5/100).

MachinabilityGood55/100
WeldabilityNot recommended0/100
Formability (cold)Not recommended5/100
PolishabilityGood60/100
Mold Shrinkage0.4%
Processing Melt Temperature (typ.)130°C266 °F
Mold Temperature (typ.)190°C374 °F

Values are nominal handbook figures for design screening. Confirm any required mill or lot documentation when quoting.

Working with BMI Tough

Is BMI easy to machine?

Machine fully cured and postcured stock with PCD or diamond-coated carbide, high speed / low feed, sharp tools and vacuum dust extraction; fiber-reinforced laminates are highly abrasive and prone to delamination on drill exit — use backing plates and dagger/brad drills, coolant mist to keep the surface below Tg.

Can BMI be welded?

Not weldable — thermoset network; join by high-temperature adhesive bonding (BMI or polyimide film adhesive), co-cure/co-bond, or mechanical fasteners with titanium/A286 hardware to match CTE.

Can BMI be formed, bent or molded?

Processed as prepreg (autoclave 177–191 °C / 0.6–0.7 MPa), RTM/VARTM, or compression molding; ALWAYS requires a freestanding postcure at 227–250 °C to develop full Tg; exotherm and volatile control matter in thick laminates, and low-humidity prepreg storage/out-time control is required.

What surface finishes work on BMI?

Sand/abrade and solvent-wipe or peel-ply then prime with a high-temperature epoxy/BMI primer; polyimide or silicone-modified topcoats for 200 °C+ service; UV protection needed outdoors; electroless/vapor-deposited metallization possible for EMI shielding.

BMI chemical composition (wt %)

Limits by weight percent from the governing specification, written the way the spec states them — a single maximum for impurities, a range for alloying elements, and the base element as balance. Nominal is the typical mid-range value.

ElementSpec limit (wt %)Nominal
4,4'-bismaleimidodiphenylmethane (BDM/MDmain maleimide monomer; other backbones (BPA-BMI, m-phenylene-BMI, eutectic monomer blends) used to lower melt point50 – 7565
o,o'-diallylbisphenol A (DABA) co-reactaEne/Diels-Alder co-monomer; also aromatic diamine, bisallyl or vinyl co-reactants20 – 4533
toughener (thermoplastic PES/PEI, CTBN, only in toughened prepreg grades; lowers Tg0 – 150
catalyst / inhibitor / processing aidsfree-radical initiator, hydroquinone-type inhibitor, release/flow aids0.1 – 20.5
carbon fiber (structural laminate gradesvol% in UD prepreg laminate; not in neat resin0 – 6860
glass fiber (electrical / radome grades)vol% in woven-glass laminate0 – 6560

BMI Tough — frequently asked

What is BMI Tough used for?

BMI Tough is typically used for aerospace composite structures, engine nacelle components and high-temp printed circuit substrates. In short: between epoxy and polyimide; 230 °C service matrix; postcure is mandatory.

What is the tensile strength of BMI Tough?

BMI Tough has a typical tensile strength of 82 MPa (11.9 ksi) — stronger than 84% of polymer grades. Strength varies by condition: see the 9 listed tempers.

Is BMI Tough easy to machine?

Reasonably — machinability is rated good (55/100, worse than 64% of polymer grades). Machine fully cured and postcured stock with PCD or diamond-coated carbide, high speed / low feed, sharp tools and vacuum dust extraction; fiber-reinforced laminates are highly abrasive and prone to delamination on drill exit — use backing plates and dagger/brad drills, coolant mist to keep the surface below Tg.

Can BMI Tough be welded?

Not readily — weldability is rated not recommended (0/100). Not weldable — thermoset network; join by high-temperature adhesive bonding (BMI or polyimide film adhesive), co-cure/co-bond, or mechanical fasteners with titanium/A286 hardware to match CTE.

What surface finishes work on BMI Tough?

Sand/abrade and solvent-wipe or peel-ply then prime with a high-temperature epoxy/BMI primer; polyimide or silicone-modified topcoats for 200 °C+ service; UV protection needed outdoors; electroless/vapor-deposited metallization possible for EMI shielding.

Can BMI Tough be formed, bent or molded?

Processed as prepreg (autoclave 177–191 °C / 0.6–0.7 MPa), RTM/VARTM, or compression molding; ALWAYS requires a freestanding postcure at 227–250 °C to develop full Tg; exotherm and volatile control matter in thick laminates, and low-humidity prepreg storage/out-time control is required.

What is the maximum service temperature of BMI Tough?

BMI Tough is rated for continuous use to about 205°C (401 °F), and briefly to 300°C. Strength falls off well before that limit — check the elevated-temperature data for load-bearing parts.

Sources

  1. CYCOM 5250-4 / 5250-4RTM BMI prepreg and resin data sheets — Solvay Composite Materials (formerly Cytec) (2022)
  2. MATRIMID / bismaleimide resin technical data — Huntsman Advanced Materials (2019)
  3. ASM Handbook Vol. 21: Composites — Bismaleimide resins — ASM International (2001)
  4. Engineered Materials Handbook Vol. 2: Engineering Plastics — ASM International (1988)
  5. CAMPUS / high-temperature thermoset property compilations — CAMPUS Plastics (2023)

Property data is compiled from published supplier and standards handbooks and normalised for comparison. Nothing on this page is a certification — request mill certs, CoC or material test reports with your order.