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BMI GR-PTFE

Additive grade

GR-PTFE = graphite / PTFE lubricated BMI

Self-lubricating high-temperature bushings, wear pads and seal rings running dry to about 230 °C.

High cost $$$$

Values for the GR-PTFE condition

Other BMI grades and fills

BMI is listed in 9 conditions; see the grade overview at BMI.

Compare all 9 grades and fillsHide
Grade · open for datasheetBest forYield MPaTensile MPaElong. %Hardness
Silica / mineral filled BMI
Pick for high-Tg encapsulation, chip-carrier and dimensionally stable insulating parts where CTE must approach that of metal/ceramic.—600.8—
GR-PTFEThis page
Graphite / PTFE lubricated BMI
Self-lubricating high-temperature bushings, wear pads and seal rings running dry to about 230 °C.—60188 Shore D
NEATDefault
Neat cured resin
Baseline cast/cured BMI used for property benchmarking, tooling resin, potting and small high-temperature parts.—722—
Low-viscosity RTM / infusion grade
Choose for resin transfer moulding or VARTM of thick high-temperature parts where injection viscosity below ~0.5 Pa·s at 120–140 °C is required.—752.2—
Toughened BMI
Pick when damage tolerance / CAI and hot-wet toughness matter (primary aerostructure prepreg) and a 20–40 °C Tg loss is acceptable.—823.5—
Chopped carbon-fiber BMI molding compound
For net-shape compression-molded brackets, fasteners, seals and bushing bodies at 200 °C+ where laminate lay-up is uneconomic.—1501—
Glass-fabric reinforced BMI laminate (~60 vol% E-glass)
Use for high-temperature electrically insulating structures, radomes, motor/generator parts and high-Tg PCB substrates (BT/BMI laminate).—4501.8—
Woven carbon-fabric/BMI laminate
Choose for drapeable, balanced-property high-temperature panels, ducts and hot tooling where UD tape is impractical.—8001.2—
Unidirectional carbon-fiber/BMI laminate
The main structural form of BMI: hot engine nacelles, missile/hypersonic skins, supersonic aircraft structure needing 180–230 °C service.—2,1001.5—

What is BMI GR-PTFE?

BMI GR-PTFE is BMI in the GR-PTFE grade — self-lubricating high-temperature bushings, wear pads and seal rings running dry to about 230 °C. BMI GR-PTFE has a tensile strength of 60 MPa (8.7 ksi), stronger than 68% of polymer grades. Elongation at break is 1% and the elastic modulus is 6.5 GPa (0.943 Msi). BMI GR-PTFE has a density of 1.55 g/cm³ (0.056 lb/in³), heavier than 91% of polymer grades. Its glass-transition temperature is 290°C (554 °F). NEAT is the default condition FabDigit quotes; GR-PTFE is available on request or by drawing note.

Advantages

  • Conducts heat well — 0.8 W/m·K (0.462 BTU/hr·ft·°F), better than 99% of polymer grades
  • Low, predictable mold shrinkage — 0.2%, better than 94% of polymer grades
  • High service temperature — 230°C (446 °F), better than 91% of polymer grades
  • Stiff — 6.5 GPa (0.943 Msi), better than 90% of polymer grades

Limitations

  • Limited ductility — 1%, worse than 98% of polymer grades
  • Difficult to weld — 0/100, worse than 98% of polymer grades
  • Limited formability — 5/100, worse than 95% of polymer grades
  • Low fracture toughness — 0.75 MPa·√m (0.683 ksi·√in), worse than 92% of polymer grades
  • Heavy — 1.55 g/cm³ (0.056 lb/in³), worse than 91% of polymer grades

BMI GR-PTFE properties

Typical room-temperature values for BMI GR-PTFE; 24 are specific to this condition. Other listed values are BMI reference data and may not represent this condition. Bars are the position among polymer grades.

Physical4

BMI GR-PTFE has a density of 1.55 g/cm³ (0.056 lb/in³), heavier than 91% of polymer grades. Its glass-transition temperature is 290°C (554 °F).

Density1.55 g/cm³0.06 lb/in³
Glass Transition (Tg)290°C554 °F
Water Absorption (24 h)0.35%
Water Absorption (Saturation)4%

Mechanical13

BMI GR-PTFE has a tensile strength of 60 MPa (8.7 ksi), stronger than 68% of polymer grades. Elongation at break is 1% and the elastic modulus is 6.5 GPa (0.943 Msi).

Elastic (Young's) Modulus6.5 GPa0.94 Msi
Shear Modulus1.5 GPa0.21 Msi
Poisson's Ratio0.35
Tensile Strength (Ultimate)60 MPa8.7 ksi
Elongation at Break1%
Compressive Strength210 MPa30.5 ksi
Compressive Modulus4.1 GPa0.59 Msi
Flexural Strength110 MPa16 ksi
Flexural Modulus6 GPa0.87 Msi
Shear Strength50 MPa7.3 ksi
Fracture Toughness (K_IC)0.75 MPa·√m0.68 ksi·√in
Izod Impact, Notched14 J/m0.26 ft·lbf/in
Hardness, Rockwell M110 HRM

Thermal10

BMI GR-PTFE is rated for continuous service to 230°C (446 °F). It conducts heat at 0.8 W/m·K (0.462 BTU/hr·ft·°F), better than 99% of polymer grades. Thermal expansion is 40 µm/m·K (22.2 µin/in·°F).

Thermal Conductivity0.8 W/m·K0.46 BTU/hr·ft·°F
Specific Heat Capacity1,150 J/kg·K0.27 BTU/lb·°F
Thermal Expansion (CTE, 20–100 °C)40 µm/m·K22.2 µin/in·°F
Max Service Temperature (continuous)230°C446 °F
Min Service Temperature-70°C-94 °F
Heat Deflection Temp. @ 0.45 MPa300°C572 °F
Heat Deflection Temp. @ 1.8 MPa285°C545 °F
Flammability (UL 94)V-0 (inherently flame retardant, low smoke; no halogen additive needed)
Limiting Oxygen Index48%
Max Service Temperature (short-term)300°C572 °F

Electrical7

BMI GR-PTFE is an electrical insulator with a dielectric strength of 20 kV/mm (508 V/mil) and a resistivity of 1,000,000 Ω·m.

Electrical Resistivity1,000,000 Ω·m3.94×10¹³ µΩ·in
Dielectric Strength20 kV/mm508 V/mil
Dielectric Constant (1 MHz)3.4
Dissipation Factor (1 MHz)0.008
Volume Resistivity1×10¹⁵ Ω·cm
Surface Resistivity1×10¹⁴ Ω
Comparative Tracking Index (CTI)200 V

Chemical & Environmental3

Corrosion resistance is excellent (88/100), better than 74% of polymer grades. UV resistance is fair.

Corrosion ResistanceExcellent88/100
UV / Weathering ResistanceFair35/100
Chemical Resistance SummaryVery good against fuels, hydraulic fluids (Skydrol), oils, aliphatic/aromatic solvents, dilute acids and salt spray; attacked by hot strong alkali and hot concentrated acids; primary amines and steam/hot-wet exposure degrade the imide network and depress hot-wet Tg; requires paint for outdoor UV.

Sustainability4

Producing a kilogram of BMI GR-PTFE takes about 190 MJ of energy and emits 9.5 kg of CO₂ — more than 88% of polymer grades. Typical recycled content is 0%.

Embodied Energy (primary production)190 MJ/kg81,685 BTU/lb
Embodied Carbon (primary production)9.5 kg CO₂/kg
Embodied Water300 L/kg35.9 gal/lb
Typical Recycled Content0%

Manufacturability7

BMI GR-PTFE's machinability is fair (45/100, worse than 78% of polymer grades); weldability not recommended (0/100); formability not recommended (5/100).

MachinabilityFair45/100
WeldabilityNot recommended0/100
Formability (cold)Not recommended5/100
PolishabilityGood60/100
Mold Shrinkage0.2%
Processing Melt Temperature (typ.)130°C266 °F
Mold Temperature (typ.)190°C374 °F

Values are nominal handbook figures for design screening. Confirm any required mill or lot documentation when quoting.

Working with BMI GR-PTFE

Is BMI easy to machine?

Machine fully cured and postcured stock with PCD or diamond-coated carbide, high speed / low feed, sharp tools and vacuum dust extraction; fiber-reinforced laminates are highly abrasive and prone to delamination on drill exit — use backing plates and dagger/brad drills, coolant mist to keep the surface below Tg.

Can BMI be welded?

Not weldable — thermoset network; join by high-temperature adhesive bonding (BMI or polyimide film adhesive), co-cure/co-bond, or mechanical fasteners with titanium/A286 hardware to match CTE.

Can BMI be formed, bent or molded?

Processed as prepreg (autoclave 177–191 °C / 0.6–0.7 MPa), RTM/VARTM, or compression molding; ALWAYS requires a freestanding postcure at 227–250 °C to develop full Tg; exotherm and volatile control matter in thick laminates, and low-humidity prepreg storage/out-time control is required.

What surface finishes work on BMI?

Sand/abrade and solvent-wipe or peel-ply then prime with a high-temperature epoxy/BMI primer; polyimide or silicone-modified topcoats for 200 °C+ service; UV protection needed outdoors; electroless/vapor-deposited metallization possible for EMI shielding.

BMI chemical composition (wt %)

Limits by weight percent from the governing specification, written the way the spec states them — a single maximum for impurities, a range for alloying elements, and the base element as balance. Nominal is the typical mid-range value.

ElementSpec limit (wt %)Nominal
4,4'-bismaleimidodiphenylmethane (BDM/MDmain maleimide monomer; other backbones (BPA-BMI, m-phenylene-BMI, eutectic monomer blends) used to lower melt point50 – 7565
o,o'-diallylbisphenol A (DABA) co-reactaEne/Diels-Alder co-monomer; also aromatic diamine, bisallyl or vinyl co-reactants20 – 4533
toughener (thermoplastic PES/PEI, CTBN, only in toughened prepreg grades; lowers Tg0 – 150
catalyst / inhibitor / processing aidsfree-radical initiator, hydroquinone-type inhibitor, release/flow aids0.1 – 20.5
carbon fiber (structural laminate gradesvol% in UD prepreg laminate; not in neat resin0 – 6860
glass fiber (electrical / radome grades)vol% in woven-glass laminate0 – 6560

BMI GR-PTFE — frequently asked

What is BMI GR-PTFE used for?

BMI GR-PTFE is typically used for aerospace composite structures, engine nacelle components and high-temp printed circuit substrates. In short: between epoxy and polyimide; 230 °C service matrix; postcure is mandatory.

What is the tensile strength of BMI GR-PTFE?

BMI GR-PTFE has a typical tensile strength of 60 MPa (8.7 ksi) — stronger than 68% of polymer grades. Strength varies by condition: see the 9 listed tempers.

Is BMI GR-PTFE easy to machine?

Reasonably — machinability is rated fair (45/100, worse than 78% of polymer grades). Machine fully cured and postcured stock with PCD or diamond-coated carbide, high speed / low feed, sharp tools and vacuum dust extraction; fiber-reinforced laminates are highly abrasive and prone to delamination on drill exit — use backing plates and dagger/brad drills, coolant mist to keep the surface below Tg.

Can BMI GR-PTFE be welded?

Not readily — weldability is rated not recommended (0/100). Not weldable — thermoset network; join by high-temperature adhesive bonding (BMI or polyimide film adhesive), co-cure/co-bond, or mechanical fasteners with titanium/A286 hardware to match CTE.

What surface finishes work on BMI GR-PTFE?

Sand/abrade and solvent-wipe or peel-ply then prime with a high-temperature epoxy/BMI primer; polyimide or silicone-modified topcoats for 200 °C+ service; UV protection needed outdoors; electroless/vapor-deposited metallization possible for EMI shielding.

Can BMI GR-PTFE be formed, bent or molded?

Processed as prepreg (autoclave 177–191 °C / 0.6–0.7 MPa), RTM/VARTM, or compression molding; ALWAYS requires a freestanding postcure at 227–250 °C to develop full Tg; exotherm and volatile control matter in thick laminates, and low-humidity prepreg storage/out-time control is required.

What is the maximum service temperature of BMI GR-PTFE?

BMI GR-PTFE is rated for continuous use to about 230°C (446 °F), and briefly to 300°C. Strength falls off well before that limit — check the elevated-temperature data for load-bearing parts.

Sources

  1. CYCOM 5250-4 / 5250-4RTM BMI prepreg and resin data sheets — Solvay Composite Materials (formerly Cytec) (2022)
  2. MATRIMID / bismaleimide resin technical data — Huntsman Advanced Materials (2019)
  3. ASM Handbook Vol. 21: Composites — Bismaleimide resins — ASM International (2001)
  4. Engineered Materials Handbook Vol. 2: Engineering Plastics — ASM International (1988)
  5. CAMPUS / high-temperature thermoset property compilations — CAMPUS Plastics (2023)

Property data is compiled from published supplier and standards handbooks and normalised for comparison. Nothing on this page is a certification — request mill certs, CoC or material test reports with your order.