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FR-3 HF

Grade

ASTM D709 Grade FR-3

HF = halogen-free flame-retardant FR-3

Choose for RoHS-plus/halogen-free customer specifications (Br+Cl each < 900 ppm) at a small price premium.

Premium cost $$$

Values for the HF condition

Other FR-3 grades and fills

FR-3 is listed in 3 conditions; see the grade overview at FR-3.

Compare all 3 grades and fillsHide
Grade · open for datasheetBest forYield MPaTensile MPaElong. %Hardness
Cold-punch grade
Pick when boards up to ~1.6 mm must be punched on unheated tooling in high-volume consumer production.—851.4100 HRM
HFThis page
Halogen-free flame-retardant FR-3
Choose for RoHS-plus/halogen-free customer specifications (Br+Cl each < 900 ppm) at a small price premium.—901.2103 HRM
Hot-punch grade
Pick for thicker sheet or the crispest hole edges; requires preheated blanks/dies but gives higher rigidity and Tg.—1051.1110 HRM

What is FR-3 HF?

FR-3 HF is FR-3 in the HF grade — choose for RoHS-plus/halogen-free customer specifications (Br+Cl each < 900 ppm) at a small price premium. FR-3 HF has a tensile strength of 90 MPa (13.1 ksi), weaker than 72% of composite grades. Elongation at break is 1.2% and the elastic modulus is 8.8 GPa (1.28 Msi). FR-3 HF has a density of 1.45 g/cm³ (0.0524 lb/in³), lighter than 59% of composite grades. Its glass-transition temperature is 115°C (239 °F).

Advantages

  • Easy to machine — 80/100, better than 85% of composite grades

Limitations

  • Limited service temperature — 105°C (221 °F), worse than 90% of composite grades
  • Hard to polish — 20/100, worse than 90% of composite grades
  • Degrades in UV without stabilisers — 25/100, worse than 86% of composite grades

FR-3 HF properties

Typical room-temperature values for FR-3 HF; 17 are specific to this condition. Other listed values are FR-3 reference data and may not represent this condition. Bars are the position among composite grades.

Physical4

FR-3 HF has a density of 1.45 g/cm³ (0.0524 lb/in³), lighter than 59% of composite grades. Its glass-transition temperature is 115°C (239 °F).

Density1.45 g/cm³0.05 lb/in³
Glass Transition (Tg)115°C239 °F
Water Absorption (24 h)0.7%
Water Absorption (Saturation)1.6%

Mechanical10

FR-3 HF has a tensile strength of 90 MPa (13.1 ksi), weaker than 72% of composite grades. Elongation at break is 1.2% and the elastic modulus is 8.8 GPa (1.28 Msi).

Elastic (Young's) Modulus8.8 GPa1.3 Msi
Poisson's Ratio0.2
Tensile Strength (Ultimate)90 MPa13.1 ksi
Elongation at Break1.2%
Compressive Strength240 MPa34.8 ksi
Flexural Strength145 MPa21 ksi
Flexural Modulus8.8 GPa1.3 Msi
Shear Strength82 MPa11.9 ksi
Izod Impact, Notched33 J/m0.62 ft·lbf/in
Hardness, Rockwell M103 HRM

Thermal8

FR-3 HF is rated for continuous service to 105°C (221 °F). It conducts heat at 0.29 W/m·K (0.168 BTU/hr·ft·°F), worse than 70% of composite grades. Thermal expansion is 20 µm/m·K (11.1 µin/in·°F).

Thermal Conductivity0.29 W/m·K0.17 BTU/hr·ft·°F
Specific Heat Capacity1,300 J/kg·K0.31 BTU/lb·°F
Thermal Expansion (CTE, 20–100 °C)20 µm/m·K11.1 µin/in·°F
Max Service Temperature (continuous)105°C221 °F
Min Service Temperature-50°C-58 °F
Flammability (UL 94)V-0, halogen-free (Br < 900 ppm, Cl < 900 ppm)
Limiting Oxygen Index32%
Max Service Temperature (short-term)150°C302 °F

Electrical7

FR-3 HF is an electrical insulator with a dielectric strength of 18 kV/mm (457.2 V/mil) and a resistivity of 5×10¹⁰ Ω·m.

Electrical Resistivity5×10¹⁰ Ω·m1.97×10¹⁸ µΩ·in
Dielectric Strength18 kV/mm457 V/mil
Dielectric Constant (1 MHz)4.7
Dissipation Factor (1 MHz)0.035
Volume Resistivity1×10¹³ Ω·cm
Surface Resistivity1×10¹² Ω
Comparative Tracking Index (CTI)200 V

Chemical & Environmental3

Corrosion resistance is good (68/100), worse than 69% of composite grades. UV resistance is poor.

Corrosion ResistanceGood68/100
UV / Weathering ResistancePoor25/100
Chemical Resistance SummaryGood resistance to mineral oils, aliphatic solvents, weak acids and common fluxes; attacked by strong acids/alkalis, hot water and polar solvents (acetone, chlorinated) that swell the epoxy and wick into the paper core.

Sustainability2

Producing a kilogram of FR-3 HF takes about 90 MJ of energy and emits 5 kg of CO₂ — less than 75% of composite grades.

Embodied Energy (primary production)90 MJ/kg38,693 BTU/lb
Embodied Carbon (primary production)5 kg CO₂/kg

Manufacturability2

FR-3 HF's machinability is very good (80/100, better than 85% of composite grades).

MachinabilityVery good80/100
PolishabilityPoor20/100

Values are nominal handbook figures for design screening. Confirm any required mill or lot documentation when quoting.

Working with FR-3 HF

Is FR-3 easy to machine?

Drills, routs and shears easily but the cured epoxy/paper is mildly abrasive — use carbide tools, high speed and vacuum dust extraction; edges fuzz if feeds are too low.

Can FR-3 be welded?

Not weldable; join by bonding with epoxy adhesive or by mechanical fastening/riveting.

Can FR-3 be formed, bent or molded?

Supplied as a fully cured thermoset laminate — it cannot be reformed; blanking and holes are made by cold or hot punching (hot punch 60–100 °C for thicker sheet) or by routing.

What surface finishes work on FR-3?

Cut edges should be sealed or varnished to limit moisture wicking into the paper core; clad grades take standard etch, HASL/OSP and solder mask, though bath temperatures must be kept moderate.

FR-3 chemical composition (wt %)

Limits by weight percent from the governing specification, written the way the spec states them — a single maximum for impurities, a range for alloying elements, and the base element as balance. Nominal is the typical mid-range value.

ElementSpec limit (wt %)Nominal
cellulose (kraft) paper reinforcementmultiple plies of resin-impregnated paper45 – 6055
brominated flame retardant (TBBPA-based)absent in halogen-free HF variant2 – 64
inorganic fillers / curing agents0 – 52
copper foil (clad grades only)18–70 µm electrodeposited foil, one or both faces0 – 150
epoxy resin binderoften DGEBA cured with dicy/novolac; may be phenolic-modified≥ 35 (balance)—

FR-3 HF — frequently asked

What is FR-3 HF used for?

FR-3 HF is typically used for single/double-sided PCBs, punched electrical insulation parts and terminal strips. In short: punchable epoxy-paper substrate; stronger than FR-2; cheaper than glass-epoxy FR-4.

What is the tensile strength of FR-3 HF?

FR-3 HF has a typical tensile strength of 90 MPa (13.1 ksi) — weaker than 72% of composite grades. Strength varies by condition: see the 3 listed tempers.

Is FR-3 HF easy to machine?

Yes — machinability is rated very good (80/100, better than 85% of composite grades). Drills, routs and shears easily but the cured epoxy/paper is mildly abrasive — use carbide tools, high speed and vacuum dust extraction; edges fuzz if feeds are too low.

Can FR-3 HF be welded?

Not weldable; join by bonding with epoxy adhesive or by mechanical fastening/riveting.

What surface finishes work on FR-3 HF?

Cut edges should be sealed or varnished to limit moisture wicking into the paper core; clad grades take standard etch, HASL/OSP and solder mask, though bath temperatures must be kept moderate.

Can FR-3 HF be formed, bent or molded?

Supplied as a fully cured thermoset laminate — it cannot be reformed; blanking and holes are made by cold or hot punching (hot punch 60–100 °C for thicker sheet) or by routing.

What is the maximum service temperature of FR-3 HF?

FR-3 HF is rated for continuous use to about 105°C (221 °F), and briefly to 150°C. Strength falls off well before that limit — check the elevated-temperature data for load-bearing parts.

Sources

  1. ASTM D709 — Standard Specification for Laminated Thermosetting Materials — ASTM International (2017)
  2. NEMA LI 1 — Industrial Laminated Thermosetting Products — NEMA (1998)
  3. UL 94 / UL 796 flammability and PCB material requirements — UL Solutions (2023)
  4. IPC-TM-650 test methods for laminate electrical and physical properties — IPC (2022)
  5. Paper-based copper clad laminate (FR-1/FR-2/FR-3) datasheets — Kingboard / Shengyi (2023)
  6. Printed Circuits Handbook — base material properties — McGraw-Hill (2016)

Property data is compiled from published supplier and standards handbooks and normalised for comparison. Nothing on this page is a certification — request mill certs, CoC or material test reports with your order.