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Cobalt-Chrome Alloy F1537 Alloy 3-ANN (Annealed)

Heat-treated state

ASTM F1537 Alloy 3 · UNS R31539

Softest condition — choose for subsequent forging, deep machining or when maximum ductility is needed.

High cost $$$$

Values for the ANN condition

Other F1537 Alloy 3 tempers and conditions

F1537 Alloy 3 is listed in 3 conditions; see the grade overview at F1537 Alloy 3.

Compare all 3 conditionsHide
Condition · open for datasheetBest forYield MPaTensile MPaElong. %HardnessConductivity
ANNThis page
Annealed
Softest condition — choose for subsequent forging, deep machining or when maximum ductility is needed.6001,0003228 HRC—
HWDefault
Hot Worked
Standard mill supply for forged implant components — balanced strength, ductility and machinability.9301,2802036 HRC—
Warm Worked
Highest strength and fatigue life — chosen for machined-from-bar hip stems and other high-cycle load-bearing parts.1,3001,5501845 HRC—

What is F1537 Alloy 3-ANN?

F1537 Alloy 3-ANN is F1537 Alloy 3 heat treated to ANN — softest condition — choose for subsequent forging, deep machining or when maximum ductility is needed. F1537 Alloy 3-ANN has a yield strength of 600 MPa (87 ksi) and a tensile strength of 1,000 MPa (145 ksi) — stronger than 52% of cobalt-chrome alloy grades. Elongation at break is 32% and the elastic modulus is 230 GPa (33.4 Msi). F1537 Alloy 3-ANN has a density of 8.3 g/cm³ (0.3 lb/in³), lighter than 80% of cobalt-chrome alloy grades. It melts at 1,330°C (2,426 °F). HW is the default condition FabDigit quotes; ANN is available on request or by drawing note.

Advantages

  • Tough — resists crack growth — 85 MPa·√m (77.4 ksi·√in), better than 95% of cobalt-chrome alloy grades
  • Good corrosion resistance — 90/100, better than 95% of cobalt-chrome alloy grades
  • Polishes to a fine finish — 92/100, better than 93% of cobalt-chrome alloy grades
  • Forms and bends easily — 35/100, better than 86% of cobalt-chrome alloy grades
  • Ductile — tolerates forming and impact — 32%, better than 85% of cobalt-chrome alloy grades

F1537 Alloy 3-ANN properties

Typical room-temperature values for F1537 Alloy 3-ANN; 17 are specific to this condition. Other listed values are F1537 Alloy 3 reference data and may not represent this condition. Bars are the position among cobalt-chrome alloy grades.

Physical3

F1537 Alloy 3-ANN has a density of 8.3 g/cm³ (0.3 lb/in³), lighter than 80% of cobalt-chrome alloy grades. It melts at 1,330°C (2,426 °F).

Density8.3 g/cm³0.3 lb/in³
Melting Point (Solidus)1,330°C2,426 °F
Liquidus Temperature1,400°C2,552 °F

Mechanical14

F1537 Alloy 3-ANN has a yield strength of 600 MPa (87 ksi) and a tensile strength of 1,000 MPa (145 ksi) — stronger than 52% of cobalt-chrome alloy grades. Elongation at break is 32% and the elastic modulus is 230 GPa (33.4 Msi).

Elastic (Young's) Modulus230 GPa33.4 Msi
Shear Modulus89 GPa12.9 Msi
Bulk Modulus185 GPa26.8 Msi
Poisson's Ratio0.29
Tensile Strength (Ultimate)1,000 MPa145 ksi
Yield Strength (0.2% offset)600 MPa87 ksi
Elongation at Break32%
Reduction in Area35%
Shear Strength600 MPa87 ksi
Fatigue Strength (Endurance Limit)480 MPa69.6 ksi
Fracture Toughness (K_IC)85 MPa·√m77.4 ksi·√in
Hardness, Brinell275 HB
Hardness, Rockwell C28 HRC
Hardness, Vickers285 HV

Thermal6

F1537 Alloy 3-ANN is rated for continuous service to 600°C (1,112 °F). It conducts heat at 14 W/m·K (8.09 BTU/hr·ft·°F), worse than 55% of cobalt-chrome alloy grades. Thermal expansion is 12.3 µm/m·K (6.83 µin/in·°F).

Thermal Conductivity14 W/m·K8.1 BTU/hr·ft·°F
Specific Heat Capacity450 J/kg·K0.11 BTU/lb·°F
Thermal Expansion (CTE, 20–100 °C)12.3 µm/m·K6.8 µin/in·°F
Latent Heat of Fusion275 J/g118 BTU/lb
Max Service Temperature (continuous)600°C1,112 °F
Min Service Temperature-196°C-321 °F

Electrical3

F1537 Alloy 3-ANN conducts electricity at 2 % IACS, better than 79% of cobalt-chrome alloy grades.

Electrical Conductivity2 % IACS
Electrical Resistivity8.8×10⁻⁷ Ω·m34.6 µΩ·in
Magnetic Responsenon-magnetic

Chemical & Environmental3

Corrosion resistance is excellent (90/100), better than 95% of cobalt-chrome alloy grades.

Galvanic Potential (seawater, vs SCE)-0.25 V
Corrosion ResistanceExcellent90/100
Chemical Resistance SummaryExcellent in body fluids, saline and most chloride media thanks to a Cr-Mo passive film; resists crevice and pitting attack far better than 316L. Attacked by hot reducing acids (HCl, H2SO4) and by strongly oxidising halide media.

Sustainability4

Producing a kilogram of F1537 Alloy 3-ANN takes about 170 MJ of energy and emits 12 kg of CO₂ — more than 63% of cobalt-chrome alloy grades. Typical recycled content is 20%.

Embodied Energy (primary production)170 MJ/kg73,087 BTU/lb
Embodied Carbon (primary production)12 kg CO₂/kg
Embodied Water350 L/kg41.9 gal/lb
Typical Recycled Content20%

Manufacturability7

F1537 Alloy 3-ANN's machinability is poor (15/100, better than 79% of cobalt-chrome alloy grades); weldability fair (35/100); formability fair (35/100).

MachinabilityPoor15/100
Machinability Rating (AISI 1212 = 100 %)12%
WeldabilityFair35/100
Formability (cold)Fair35/100
Brazeability / SolderabilityFair40/100
PolishabilityExcellent92/100
Anodizing Responsen/a — cobalt alloy is not anodized; surfaces are passivated (ASTM F86) or electropolished

Values are nominal handbook figures for design screening. Confirm any required mill or lot documentation when quoting.

Working with F1537 Alloy 3-ANN

Is F1537 Alloy 3 easy to machine?

Very difficult: use rigid setups, sharp coated carbide or ceramic inserts, low speed / heavy positive feed and flood coolant to avoid the severe work-hardened skin; grinding and EDM are common alternatives.

Can F1537 Alloy 3 be welded?

Not recommended for load-bearing joints — high carbon promotes carbide precipitation and hot cracking; if unavoidable use low-heat-input laser or electron-beam welding with matched filler and post-weld solution anneal.

Can F1537 Alloy 3 be formed, bent or molded?

Shape by hot forging (≈1100–1180 °C) or warm working; cold forming is impractical because of the extremely high work-hardening rate.

What surface finishes work on F1537 Alloy 3?

Not anodizable — finish by grinding, mirror polishing of bearing surfaces (Ra < 0.02 µm), electropolishing, then passivation per ASTM F86; porous coatings applied by plasma spray or sintered beads.

F1537 Alloy 3 chemical composition (wt %)

Limits by weight percent from the governing specification, written the way the spec states them — a single maximum for impurities, a range for alloying elements, and the base element as balance. Nominal is the typical mid-range value.

ElementSpec limit (wt %)Nominal
Cr26 – 3028
Mo5 – 76
Chigh-carbon type, forms M23C6 carbides0.15 – 0.350.25
Larare-earth addition producing the dispersed oxide phase0.03 – 0.140.08
Ni≤ 1—
Fe≤ 0.75—
Si≤ 1—
Mn≤ 1—
N≤ 0.25—
Cobalance—

F1537 Alloy 3-ANN — frequently asked

What is F1537 Alloy 3-ANN used for?

F1537 Alloy 3-ANN is typically used for orthopedic implant stems, joint replacement components, knee femoral components, modular hip necks and tapers, spinal rods and connectors and trauma fixation hardware. In short: dispersion-strengthened implant grade; improved implant fatigue strength; very low machinability rating.

What is the yield strength of F1537 Alloy 3-ANN?

F1537 Alloy 3-ANN has a typical yield strength of 600 MPa (87 ksi) and a tensile strength of 1,000 MPa (145 ksi) — stronger than 52% of cobalt-chrome alloy grades. Strength varies by condition: see the 3 listed tempers.

Is F1537 Alloy 3-ANN easy to machine?

Not especially — machinability is rated poor (15/100, better than 79% of cobalt-chrome alloy grades). Very difficult: use rigid setups, sharp coated carbide or ceramic inserts, low speed / heavy positive feed and flood coolant to avoid the severe work-hardened skin; grinding and EDM are common alternatives.

Can F1537 Alloy 3-ANN be welded?

With care — weldability is rated fair (35/100). Not recommended for load-bearing joints — high carbon promotes carbide precipitation and hot cracking; if unavoidable use low-heat-input laser or electron-beam welding with matched filler and post-weld solution anneal.

What surface finishes work on F1537 Alloy 3-ANN?

Not anodizable — finish by grinding, mirror polishing of bearing surfaces (Ra < 0.02 µm), electropolishing, then passivation per ASTM F86; porous coatings applied by plasma spray or sintered beads.

Can F1537 Alloy 3-ANN be formed, bent or molded?

Shape by hot forging (≈1100–1180 °C) or warm working; cold forming is impractical because of the extremely high work-hardening rate.

What is the maximum service temperature of F1537 Alloy 3-ANN?

F1537 Alloy 3-ANN is rated for continuous use to about 600°C (1,112 °F). Strength falls off well before that limit — check the elevated-temperature data for load-bearing parts.

What is the difference between F1537 Alloy 3-HW and F1537 Alloy 3-WW?

HW is the default condition — standard mill supply for forged implant components — balanced strength, ductility and machinability. WW: highest strength and fatigue life — chosen for machined-from-bar hip stems and other high-cycle load-bearing parts. Yield strength is 930 MPa in HW versus 1,300 MPa in WW.

Sources

  1. ASTM F1537 Standard Specification for Wrought Cobalt-28Chromium-6Molybdenum Alloys for Surgical Implants (UNS R31537, R31538, R31539) — ASTM International (2020)
  2. ASTM F86 Standard Practice for Surface Preparation and Marking of Metallic Surgical Implants — ASTM International (2021)
  3. ASM Handbook Vol.23: Materials for Medical Devices — ASM International (2012)
  4. ASM Handbook Vol.2: Properties and Selection — Nonferrous Alloys and Special-Purpose Materials (Cobalt alloys) — ASM International (1990)
  5. Wrought Co-28Cr-6Mo medical bar datasheets (Carpenter/Sandvik/Villares type) — various mills (2023)

Property data is compiled from published supplier and standards handbooks and normalised for comparison. Nothing on this page is a certification — request mill certs, CoC or material test reports with your order.