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Cobalt-Chrome Alloy F1537 Alloy 1-ANN (Annealed)

Heat-treated state · default condition

ASTM F1537 Alloy 1 · UNS R31537 · ISO 5832-12 Alloy 1

Most commonly stocked raw bar condition: maximum ductility for subsequent forging, machining or forming of implant components.

High cost $$$$

Values for the ANN condition

Other F1537 Alloy 1 tempers and conditions

F1537 Alloy 1 is listed in 3 conditions; see the grade overview at F1537 Alloy 1.

Compare all 3 conditionsHide
Condition · open for datasheetBest forYield MPaTensile MPaElong. %HardnessConductivity
ANNDefaultThis page
Annealed
Most commonly stocked raw bar condition: maximum ductility for subsequent forging, machining or forming of implant components.6101,0003529 HRC—
Hot Worked
Choose for near-net-shape forgings (stems, knee components) needing higher strength than annealed with still-good ductility.8501,2002235 HRC—
Warm Worked
Highest-strength condition of Alloy 1 — pick for slender, highly loaded implants (femoral stems, spinal rods) where fatigue strength governs.1,0501,4001842 HRC—

What is F1537 Alloy 1-ANN?

F1537 Alloy 1-ANN is F1537 Alloy 1 heat treated to ANN — most commonly stocked raw bar condition: maximum ductility for subsequent forging, machining or forming of implant components. F1537 Alloy 1-ANN has a yield strength of 610 MPa (88.5 ksi) and a tensile strength of 1,000 MPa (145 ksi) — stronger than 58% of cobalt-chrome alloy grades. Elongation at break is 35% and the elastic modulus is 230 GPa (33.4 Msi). F1537 Alloy 1-ANN has a density of 8.3 g/cm³ (0.3 lb/in³), lighter than 80% of cobalt-chrome alloy grades. It melts at 1,330°C (2,426 °F).

Advantages

  • Good corrosion resistance — 92/100, better than 100% of cobalt-chrome alloy grades
  • Tough — resists crack growth — 100 MPa·√m (91 ksi·√in), better than 97% of cobalt-chrome alloy grades
  • Polishes to a fine finish — 92/100, better than 93% of cobalt-chrome alloy grades
  • Forms and bends easily — 35/100, better than 86% of cobalt-chrome alloy grades
  • Ductile — tolerates forming and impact — 35%, better than 85% of cobalt-chrome alloy grades

F1537 Alloy 1-ANN properties

Typical room-temperature values for F1537 Alloy 1-ANN; 18 are specific to this condition. Other listed values are F1537 Alloy 1 reference data and may not represent this condition. Bars are the position among cobalt-chrome alloy grades.

Physical3

F1537 Alloy 1-ANN has a density of 8.3 g/cm³ (0.3 lb/in³), lighter than 80% of cobalt-chrome alloy grades. It melts at 1,330°C (2,426 °F).

Density8.3 g/cm³0.3 lb/in³
Melting Point (Solidus)1,330°C2,426 °F
Liquidus Temperature1,400°C2,552 °F

Mechanical16

F1537 Alloy 1-ANN has a yield strength of 610 MPa (88.5 ksi) and a tensile strength of 1,000 MPa (145 ksi) — stronger than 58% of cobalt-chrome alloy grades. Elongation at break is 35% and the elastic modulus is 230 GPa (33.4 Msi).

Elastic (Young's) Modulus230 GPa33.4 Msi
Shear Modulus90 GPa13.1 Msi
Bulk Modulus185 GPa26.8 Msi
Poisson's Ratio0.3
Tensile Strength (Ultimate)1,000 MPa145 ksi
Yield Strength (0.2% offset)610 MPa88.5 ksi
Elongation at Break35%
Reduction in Area45%
Compressive Strength1,200 MPa174 ksi
Shear Strength620 MPa89.9 ksi
Fatigue Strength (Endurance Limit)500 MPa72.5 ksi
Fracture Toughness (K_IC)100 MPa·√m91 ksi·√in
Charpy V-Notch Impact (RT)70 J51.6 ft·lbf
Hardness, Brinell285 HB
Hardness, Rockwell C29 HRC
Hardness, Vickers300 HV

Thermal6

F1537 Alloy 1-ANN is rated for continuous service to 600°C (1,112 °F). It conducts heat at 14 W/m·K (8.09 BTU/hr·ft·°F), worse than 55% of cobalt-chrome alloy grades. Thermal expansion is 12.3 µm/m·K (6.83 µin/in·°F).

Thermal Conductivity14 W/m·K8.1 BTU/hr·ft·°F
Specific Heat Capacity450 J/kg·K0.11 BTU/lb·°F
Thermal Expansion (CTE, 20–100 °C)12.3 µm/m·K6.8 µin/in·°F
Latent Heat of Fusion275 J/g118 BTU/lb
Max Service Temperature (continuous)600°C1,112 °F
Min Service Temperature-196°C-321 °F

Electrical3

F1537 Alloy 1-ANN conducts electricity at 1.9 % IACS, worse than 52% of cobalt-chrome alloy grades.

Electrical Conductivity1.9 % IACS
Electrical Resistivity9.1×10⁻⁷ Ω·m35.8 µΩ·in
Magnetic Responsenon-magnetic

Chemical & Environmental3

Corrosion resistance is excellent (92/100), better than 100% of cobalt-chrome alloy grades.

Galvanic Potential (seawater, vs SCE)-0.25 V
Corrosion ResistanceExcellent92/100
Chemical Resistance SummaryExcellent in body fluids, chloride solutions and dilute acids thanks to a Cr₂O₃/Mo passive film; resists crevice and pitting attack better than 316L; attacked by hot concentrated HCl, HF and strongly reducing acids.

Sustainability4

Producing a kilogram of F1537 Alloy 1-ANN takes about 210 MJ of energy and emits 14 kg of CO₂ — more than 80% of cobalt-chrome alloy grades. Typical recycled content is 20%.

Embodied Energy (primary production)210 MJ/kg90,284 BTU/lb
Embodied Carbon (primary production)14 kg CO₂/kg
Embodied Water500 L/kg59.9 gal/lb
Typical Recycled Content20%

Manufacturability8

F1537 Alloy 1-ANN's machinability is not recommended (14/100, better than 71% of cobalt-chrome alloy grades); weldability good (55/100); formability fair (35/100).

MachinabilityNot recommended14/100
Machinability Rating (AISI 1212 = 100 %)14%
WeldabilityGood55/100
Formability (cold)Fair35/100
CastabilityGood60/100
Brazeability / SolderabilityFair40/100
PolishabilityExcellent92/100
Anodizing Responsen/a — cobalt alloy; surfaces are electropolished, passivated (ASTM F86) or nitrided rather than anodized

Common Calculations5

Specific Strength (UTS / density)calculated120 kN·m/kg
Specific Stiffness (E / density)calculated27.7 MN·m/kg
Modulus of Resiliencecalculated809 kJ/m³
Thermal Diffusivitycalculated3.7 mm²/s
Thermal Shock Resistance Indexcalculated5

Values are nominal handbook figures for design screening. Confirm any required mill or lot documentation when quoting.

Working with F1537 Alloy 1-ANN

Is F1537 Alloy 1 easy to machine?

Very difficult: rigid setups, sharp positive-rake carbide or ceramic tools, low speed / heavy feed and flood coolant to avoid work-hardened glaze; grinding and EDM are common for finish features.

Can F1537 Alloy 1 be welded?

Low carbon content makes it the most weldable F1537 alloy — GTAW or laser/electron-beam with matching filler, clean argon shielding, low heat input; post-weld solution anneal restores ductility.

Can F1537 Alloy 1 be formed, bent or molded?

Cold formability is poor due to the very high work-hardening rate; forge or upset hot (≈1050–1180 °C) or warm work below recrystallisation to raise strength, with intermediate anneals.

What surface finishes work on F1537 Alloy 1?

Not anodizable; electropolish, passivate per ASTM F86, and mirror-polish bearing surfaces (Ra < 0.05 µm); porous or HA coatings can be applied for bone ingrowth.

F1537 Alloy 1 chemical composition (wt %)

Limits by weight percent from the governing specification, written the way the spec states them — a single maximum for impurities, a range for alloying elements, and the base element as balance. Nominal is the typical mid-range value.

ElementSpec limit (wt %)Nominal
Cr26 – 3028
Mo5 – 76
Ni≤ 10.3
Fe≤ 0.750.3
CAlloy 1 = low carbon≤ 0.140.05
Si≤ 10.5
Mn≤ 10.5
N≤ 0.250.15
Cobalance, nominally ~62–64 %balance—

F1537 Alloy 1-ANN — frequently asked

What is F1537 Alloy 1-ANN used for?

F1537 Alloy 1-ANN is typically used for hip and knee implant components, trauma fixation devices, bone plates and screws, spinal rods and connectors, modular implant connectors and dental frameworks. In short: most weldable F1537 alloy; highest ductility Co-Cr-Mo; low-carbon implant grade.

What is the yield strength of F1537 Alloy 1-ANN?

F1537 Alloy 1-ANN has a typical yield strength of 610 MPa (88.5 ksi) and a tensile strength of 1,000 MPa (145 ksi) — stronger than 58% of cobalt-chrome alloy grades. Strength varies by condition: see the 3 listed tempers.

Is F1537 Alloy 1-ANN easy to machine?

Not especially — machinability is rated not recommended (14/100, better than 71% of cobalt-chrome alloy grades). Very difficult: rigid setups, sharp positive-rake carbide or ceramic tools, low speed / heavy feed and flood coolant to avoid work-hardened glaze; grinding and EDM are common for finish features.

Can F1537 Alloy 1-ANN be welded?

Yes — weldability is rated good (55/100). Low carbon content makes it the most weldable F1537 alloy — GTAW or laser/electron-beam with matching filler, clean argon shielding, low heat input; post-weld solution anneal restores ductility.

What surface finishes work on F1537 Alloy 1-ANN?

Not anodizable; electropolish, passivate per ASTM F86, and mirror-polish bearing surfaces (Ra < 0.05 µm); porous or HA coatings can be applied for bone ingrowth.

Can F1537 Alloy 1-ANN be formed, bent or molded?

Cold formability is poor due to the very high work-hardening rate; forge or upset hot (≈1050–1180 °C) or warm work below recrystallisation to raise strength, with intermediate anneals.

What is the maximum service temperature of F1537 Alloy 1-ANN?

F1537 Alloy 1-ANN is rated for continuous use to about 600°C (1,112 °F). Strength falls off well before that limit — check the elevated-temperature data for load-bearing parts.

What is the difference between F1537 Alloy 1-ANN and F1537 Alloy 1-WW?

ANN is the default condition — most commonly stocked raw bar condition: maximum ductility for subsequent forging, machining or forming of implant components. WW: highest-strength condition of Alloy 1 — pick for slender, highly loaded implants (femoral stems, spinal rods) where fatigue strength governs. Yield strength is 610 MPa in ANN versus 1,050 MPa in WW.

Sources

  1. ASTM F1537 — Standard Specification for Wrought Cobalt-28Chromium-6Molybdenum Alloys for Surgical Implants (UNS R31537, R31538, R31539) — ASTM International (2020)
  2. ISO 5832-12 — Implants for surgery, metallic materials, Part 12: Wrought cobalt-chromium-molybdenum alloy — ISO (2019)
  3. ASM Handbook Vol.23 — Materials for Medical Devices — ASM International (2012)
  4. ASM Handbook Vol.2 — Properties and Selection: Nonferrous Alloys and Special-Purpose Materials — ASM International (1990)
  5. Medical-grade Co-28Cr-6Mo bar datasheets (Carpenter, Sandvik, VDM) — various producers (2023)

Property data is compiled from published supplier and standards handbooks and normalised for comparison. Nothing on this page is a certification — request mill certs, CoC or material test reports with your order.