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PU-PMMA-like HT (Heat-resistant clear)

Heat-treated state

Use for lamp lenses or parts near heat sources needing HDT above ~90 °C; slightly more brittle.

High cost $$$$

Values for the HT condition

Other PU-PMMA-like grades and fills

PU-PMMA-like is listed in 5 conditions; see the grade overview at PU-PMMA-like.

Compare all 5 grades and fillsHide
Grade · open for datasheetBest forYield MPaTensile MPaElong. %Hardness
Impact-modified / tough clear
Choose for snap-fits, thin walls or drop-tested transparent housings where full optical clarity is not required.42503576 Shore D
Mineral-filled rigid grade
Use for large flat opaque panels where dimensional stability matters more than transparency.—452.5—
Flame-retardant casting grade
Specify for electrical enclosure or lighting prototypes needing a flame rating; clarity is usually lost.5055685 Shore D
Tinted / pigmented
Use for smoked lenses, coloured light guides or self-coloured show parts, avoiding paint on transparent geometry.5562983 Shore D
HTThis page
Heat-resistant clear
Use for lamp lenses or parts near heat sources needing HDT above ~90 °C; slightly more brittle.6670586 Shore D

What is PU-PMMA-like HT?

PU-PMMA-like HT is PU-PMMA-like heat treated to HT — use for lamp lenses or parts near heat sources needing HDT above ~90 °C; slightly more brittle. PU-PMMA-like HT has a yield strength of 66 MPa (9.57 ksi) and a tensile strength of 70 MPa (10.2 ksi) — stronger than 111% of polyurethane grades. Elongation at break is 5% and the elastic modulus is 2.8 GPa (0.406 Msi). PU-PMMA-like HT has a density of 1.13 g/cm³ (0.0408 lb/in³), lighter than 55% of polyurethane grades. Its glass-transition temperature is 110°C (230 °F).

Advantages

  • High strength — 66 MPa (9.57 ksi), better than 111% of polyurethane grades
  • Polishes to a fine finish — 85/100, better than 98% of polyurethane grades
  • Stiff — 2.8 GPa (0.406 Msi), better than 95% of polyurethane grades
  • Good UV / weathering resistance — 55/100, better than 95% of polyurethane grades
  • High service temperature — 100°C (212 °F), better than 90% of polyurethane grades

Limitations

  • Low fracture toughness — 1.2 MPa·√m (1.09 ksi·√in), worse than 100% of polyurethane grades
  • Limited ductility — 5%, worse than 90% of polyurethane grades

PU-PMMA-like HT properties

Typical room-temperature values for PU-PMMA-like HT; 26 are specific to this condition. Other listed values are PU-PMMA-like reference data and may not represent this condition. Bars are the position among polyurethane grades.

Physical6

PU-PMMA-like HT has a density of 1.13 g/cm³ (0.0408 lb/in³), lighter than 55% of polyurethane grades. Its glass-transition temperature is 110°C (230 °F).

Density1.13 g/cm³0.04 lb/in³
Glass Transition (Tg)110°C230 °F
Water Absorption (24 h)0.35%
Water Absorption (Saturation)1.4%
Refractive Index1.5
Light Transmission88%

Mechanical15

PU-PMMA-like HT has a yield strength of 66 MPa (9.57 ksi) and a tensile strength of 70 MPa (10.2 ksi) — stronger than 111% of polyurethane grades. Elongation at break is 5% and the elastic modulus is 2.8 GPa (0.406 Msi).

Elastic (Young's) Modulus2.8 GPa0.41 Msi
Poisson's Ratio0.4
Tensile Strength (Ultimate)70 MPa10.2 ksi
Yield Strength (0.2% offset)66 MPa9.6 ksi
Elongation at Break5%
Compressive Strength95 MPa13.8 ksi
Compressive Modulus2.4 GPa0.35 Msi
Flexural Strength108 MPa15.7 ksi
Flexural Modulus2.9 GPa0.42 Msi
Shear Strength48 MPa7 ksi
Fracture Toughness (K_IC)1.2 MPa·√m1.1 ksi·√in
Izod Impact, Notched30 J/m0.56 ft·lbf/in
Hardness, Shore D86 Shore D
Hardness, Rockwell M92 HRM
Hardness, Rockwell R119 HRR

Thermal11

PU-PMMA-like HT is rated for continuous service to 100°C (212 °F). It conducts heat at 0.21 W/m·K (0.121 BTU/hr·ft·°F), better than 74% of polyurethane grades. Thermal expansion is 90 µm/m·K (50 µin/in·°F).

Thermal Conductivity0.21 W/m·K0.12 BTU/hr·ft·°F
Specific Heat Capacity1,600 J/kg·K0.38 BTU/lb·°F
Thermal Expansion (CTE, 20–100 °C)90 µm/m·K50 µin/in·°F
Max Service Temperature (continuous)100°C212 °F
Min Service Temperature-30°C-22 °F
Heat Deflection Temp. @ 0.45 MPa110°C230 °F
Heat Deflection Temp. @ 1.8 MPa90°C194 °F
Vicat Softening Point (B50)115°C239 °F
Flammability (UL 94)HB (standard clear grade, not UL-listed); V-0 only with dedicated FR casting grade
Limiting Oxygen Index20%
Max Service Temperature (short-term)100°C212 °F

Electrical6

PU-PMMA-like HT is an electrical insulator with a dielectric strength of 18 kV/mm (457.2 V/mil) and a resistivity of 1×10¹² Ω·m.

Electrical Resistivity1×10¹² Ω·m3.94×10¹⁹ µΩ·in
Dielectric Strength18 kV/mm457 V/mil
Dielectric Constant (1 MHz)3.5
Dissipation Factor (1 MHz)0.04
Volume Resistivity1×10¹⁴ Ω·cm
Surface Resistivity1×10¹⁴ Ω

Chemical & Environmental3

Corrosion resistance is very good (72/100), worse than 55% of polyurethane grades. UV resistance is good.

Corrosion ResistanceVery good72/100
UV / Weathering ResistanceGood55/100
Chemical Resistance SummaryGood against water, dilute acids/alkalis, aliphatic fuels and most oils; attacked or crazed by ketones, esters, chlorinated solvents, strong acids and hot alkali; alcohols and cleaning sprays can haze polished surfaces.

Sustainability4

Producing a kilogram of PU-PMMA-like HT takes about 105 MJ of energy and emits 5.2 kg of CO₂ — more than 64% of polyurethane grades. Typical recycled content is 0%.

Embodied Energy (primary production)105 MJ/kg45,142 BTU/lb
Embodied Carbon (primary production)5.2 kg CO₂/kg
Embodied Water220 L/kg26.4 gal/lb
Typical Recycled Content0%

Manufacturability7

PU-PMMA-like HT's machinability is good (58/100, worse than 52% of polyurethane grades); weldability not recommended (5/100); formability not recommended (8/100).

MachinabilityGood58/100
WeldabilityNot recommended5/100
Formability (cold)Not recommended8/100
PolishabilityExcellent85/100
Mold Shrinkage0.25%
Processing Melt Temperature (typ.)30°C86 °F
Mold Temperature (typ.)65°C149 °F

Values are nominal handbook figures for design screening. Confirm any required mill or lot documentation when quoting.

Working with PU-PMMA-like HT

Is PU-PMMA-like easy to machine?

Machines and drills easily with sharp carbide and low feed pressure; avoid heat build-up and stress-crazing near clear surfaces, and support thin walls to prevent chipping.

Can PU-PMMA-like be welded?

Thermoset — cannot be heat-welded; join with cyanoacrylate, two-part PU or acrylic-based structural adhesive.

Can PU-PMMA-like be formed, bent or molded?

Degas both components, vacuum-cast into a silicone mould at 25–40 °C resin temperature, demould after 20–60 min and oven post-cure 60–75 °C for 2–4 h to reach full Tg and clarity.

What surface finishes work on PU-PMMA-like?

Sand progressively to 2000–3000 grit then buff, or apply a clear PU/acrylic topcoat for optical gloss; can be dyed in the mix, vapour-polished only with caution, and takes primer/paint well.

PU-PMMA-like chemical composition (wt %)

Limits by weight percent from the governing specification, written the way the spec states them — a single maximum for impurities, a range for alloying elements, and the base element as balance. Nominal is the typical mid-range value.

ElementSpec limit (wt %)Nominal
aliphatic polyisocyanate (HDI/IPDI-basedaliphatic chemistry chosen for non-yellowing clarity40 – 5548
catalyst (organometallic/amine)0.01 – 0.50.1
UV absorber + HALSpresent in UV-stabilized variant0 – 1.50.5
degassing / flow additive0 – 10.3
pigment paste or mineral fillervariant-dependent; zero in clear default0 – 400
polyol blend (polyester/polyether polyoltypical mix ratio 100:90–100:110 by weight≥ 45 (balance)—

PU-PMMA-like HT — frequently asked

What is PU-PMMA-like HT used for?

PU-PMMA-like HT is typically used for lens prototypes, display cases, signage models and optical demonstration parts. In short: highest-gloss clear PU; acrylic look, no tooling; rigid transparent prototype resin.

What is the yield strength of PU-PMMA-like HT?

PU-PMMA-like HT has a typical yield strength of 66 MPa (9.57 ksi) and a tensile strength of 70 MPa (10.2 ksi) — stronger than 111% of polyurethane grades. Strength varies by condition: see the 5 listed tempers.

Is PU-PMMA-like HT easy to machine?

Reasonably — machinability is rated good (58/100, worse than 52% of polyurethane grades). Machines and drills easily with sharp carbide and low feed pressure; avoid heat build-up and stress-crazing near clear surfaces, and support thin walls to prevent chipping.

Can PU-PMMA-like HT be welded?

Not readily — weldability is rated not recommended (5/100). Thermoset — cannot be heat-welded; join with cyanoacrylate, two-part PU or acrylic-based structural adhesive.

What surface finishes work on PU-PMMA-like HT?

Sand progressively to 2000–3000 grit then buff, or apply a clear PU/acrylic topcoat for optical gloss; can be dyed in the mix, vapour-polished only with caution, and takes primer/paint well.

Can PU-PMMA-like HT be formed, bent or molded?

Degas both components, vacuum-cast into a silicone mould at 25–40 °C resin temperature, demould after 20–60 min and oven post-cure 60–75 °C for 2–4 h to reach full Tg and clarity.

What is the maximum service temperature of PU-PMMA-like HT?

PU-PMMA-like HT is rated for continuous use to about 100°C (212 °F), and briefly to 100°C. Strength falls off well before that limit — check the elevated-temperature data for load-bearing parts.

Sources

  1. PX223 / PX223HT clear polyurethane casting resin technical data — Axson Technologies (Sika) (2020)
  2. UPX 8400 / clear vacuum-casting PU resin data sheets — Huntsman Advanced Materials (2019)
  3. Hei-Cast series polyurethane casting resins — H&K / Hei-Cast (2021)
  4. ISO 527 / ISO 178 / ISO 75 plastics test methods — ISO (2019)
  5. Engineered Materials Handbook Vol. 2: Engineering Plastics — ASM International (1988)

Property data is compiled from published supplier and standards handbooks and normalised for comparison. Nothing on this page is a certification — request mill certs, CoC or material test reports with your order.