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Polyurea FR (Flame-retardant grade)

Flame-retardant grade

Specify for tunnel, mine, marine and transit linings that must meet UL 94 V-0 or ASTM E84 Class A flame-spread requirements.

Premium cost $$$

Values for the FR condition

Other Polyurea grades and fills

Polyurea is listed in 8 conditions; see the grade overview at Polyurea.

Compare all 8 grades and fillsHide
Grade · open for datasheetBest forYield MPaTensile MPaElong. %Hardness
Soft / high-elongation grade
Choose for crack-bridging waterproofing, expansion joints and geomembranes where movement accommodation matters more than hardness.—1260035 Shore D
Polyurea–polyurethane hybrid
Lower-cost blend with slightly longer gel time and better wetting/levelling; accepts modest moisture but is less hydrolysis- and heat-resistant than pure polyurea.—1432045 Shore D
Slow-set hand-applied / cartridge grade
Use for repairs, detail work, joints and small areas where heated plural-component spray equipment is impractical.—1435045 Shore D
FRThis page
Flame-retardant grade
Specify for tunnel, mine, marine and transit linings that must meet UL 94 V-0 or ASTM E84 Class A flame-spread requirements.—1525052 Shore D
AROMDefault
Aromatic pure polyurea
Default workhorse for tank, secondary-containment, truck-bed and waterproofing linings where colour stability is not required.—1838050 Shore D
Aliphatic polyurea
Pick for exposed architectural, stadium, deck and topcoat work where gloss and colour must be retained outdoors.—2030055 Shore D
Mineral / glass-flake reinforced lining grade
Filled or glass-flake versions for tank bottoms, FGD and immersion service needing lower permeation, higher stiffness and less shrinkage.—208070 Shore D
High-hardness / rigid grade
Use for abrasion-dominated service — mining chutes, slurry pipe, hopper and dredge linings — where stiffness beats elongation.—2612065 Shore D

What is Polyurea FR?

Polyurea FR is Polyurea in the FR grade — specify for tunnel, mine, marine and transit linings that must meet UL 94 V-0 or ASTM E84 Class A flame-spread requirements. Polyurea FR has a tensile strength of 15 MPa (2.18 ksi), weaker than 81% of polyurethane grades. Elongation at break is 250% and the elastic modulus is 0.08 GPa (0.0116 Msi). Polyurea FR has a density of 1.15 g/cm³ (0.0415 lb/in³), heavier than 62% of polyurethane grades. Its glass-transition temperature is -55°C (-67 °F). AROM is the default condition FabDigit quotes; FR is available on request or by drawing note.

Advantages

  • High service temperature — 110°C (230 °F), better than 95% of polyurethane grades
  • Good corrosion resistance — 85/100, better than 95% of polyurethane grades
  • Ductile — tolerates forming and impact — 250%, better than 86% of polyurethane grades
  • Good UV / weathering resistance — 35/100, better than 83% of polyurethane grades

Limitations

  • Hard to polish — 20/100, worse than 97% of polyurethane grades
  • Difficult to machine — 28/100, worse than 81% of polyurethane grades
  • Absorbs moisture — dry before molding — 0.7%, worse than 81% of polyurethane grades

Polyurea FR properties

Typical room-temperature values for Polyurea FR; 19 are specific to this condition. Other listed values are Polyurea reference data and may not represent this condition. Bars are the position among polyurethane grades.

Physical4

Polyurea FR has a density of 1.15 g/cm³ (0.0415 lb/in³), heavier than 62% of polyurethane grades. Its glass-transition temperature is -55°C (-67 °F).

Density1.15 g/cm³0.04 lb/in³
Glass Transition (Tg)-55°C-67 °F
Water Absorption (24 h)0.7%
Water Absorption (Saturation)2.5%

Mechanical11

Polyurea FR has a tensile strength of 15 MPa (2.18 ksi), weaker than 81% of polyurethane grades. Elongation at break is 250% and the elastic modulus is 0.08 GPa (0.0116 Msi).

Elastic (Young's) Modulus0.08 GPa0.01 Msi
Poisson's Ratio0.45
Tensile Strength (Ultimate)15 MPa2.2 ksi
Elongation at Break250%
Compressive Strength24 MPa3.5 ksi
Flexural Modulus0.1 GPa0.01 Msi
Shear Strength9 MPa1.3 ksi
Hardness, Shore A95 Shore A
Hardness, Shore D52 Shore D
Tear Strength55 kN/m314 lbf/in
Compression Set (22 h, 70 °C)28%

Thermal8

Polyurea FR is rated for continuous service to 110°C (230 °F). It conducts heat at 0.22 W/m·K (0.127 BTU/hr·ft·°F), better than 83% of polyurethane grades. Thermal expansion is 130 µm/m·K (72.2 µin/in·°F).

Thermal Conductivity0.22 W/m·K0.13 BTU/hr·ft·°F
Specific Heat Capacity1,700 J/kg·K0.41 BTU/lb·°F
Thermal Expansion (CTE, 20–100 °C)130 µm/m·K72.2 µin/in·°F
Max Service Temperature (continuous)110°C230 °F
Min Service Temperature-40°C-40 °F
Flammability (UL 94)V-0 at typical 2–3 mm lining thickness
Limiting Oxygen Index30%
Max Service Temperature (short-term)180°C356 °F

Electrical4

Polyurea FR is an electrical insulator with a dielectric strength of 20 kV/mm (508 V/mil) and a resistivity of 1×10¹⁰ Ω·m.

Electrical Resistivity1×10¹⁰ Ω·m3.94×10¹⁷ µΩ·in
Dielectric Strength20 kV/mm508 V/mil
Dielectric Constant (1 MHz)4
Volume Resistivity1×10¹³ Ω·cm

Chemical & Environmental3

Corrosion resistance is excellent (85/100), better than 95% of polyurethane grades. UV resistance is fair.

Corrosion ResistanceExcellent85/100
UV / Weathering ResistanceFair35/100
Chemical Resistance SummaryExcellent against water, seawater, dilute acids and alkalis, salts, hydraulic fluid and most fuels/oils; good hydrolytic stability. Attacked by strong oxidising acids, concentrated caustic at temperature, chlorinated solvents, ketones and hot aromatic solvents; aromatic grades chalk under sunlight without a topcoat.

Sustainability4

Producing a kilogram of Polyurea FR takes about 105 MJ of energy and emits 5.2 kg of CO₂ — more than 64% of polyurethane grades. Typical recycled content is 0%.

Embodied Energy (primary production)105 MJ/kg45,142 BTU/lb
Embodied Carbon (primary production)5.2 kg CO₂/kg
Embodied Water250 L/kg30 gal/lb
Typical Recycled Content0%

Manufacturability3

Polyurea FR's machinability is poor (28/100, worse than 81% of polyurethane grades); weldability not recommended (5/100).

MachinabilityPoor28/100
WeldabilityNot recommended5/100
PolishabilityPoor20/100

Values are nominal handbook figures for design screening. Confirm any required mill or lot documentation when quoting.

Working with Polyurea FR

Is Polyurea easy to machine?

Cured film is trimmed with sharp knives, hot knives or water-jet; conventional machining smears and drags, and thermosets cannot be re-melted.

Can Polyurea be welded?

Not weldable — repairs are made by abrading, solvent/tie-coat priming and re-spraying fresh polyurea within the recoat window.

Can Polyurea be formed, bent or molded?

Applied by heated (60–75 °C) plural-component 1:1 impingement spray at 14–24 MPa, gel 3–15 s and tack-free under a minute; also cast or RIM-moulded for parts.

What surface finishes work on Polyurea?

Surface prep (SSPC-SP10 blast on steel, CSP-3 on concrete) plus epoxy primer governs adhesion; aromatic films need an aliphatic polyurea or PU topcoat for colour retention.

Polyurea chemical composition (wt %)

Limits by weight percent from the governing specification, written the way the spec states them — a single maximum for impurities, a range for alloying elements, and the base element as balance. Nominal is the typical mid-range value.

ElementSpec limit (wt %)Nominal
MDI-based isocyanate quasi-prepolymer (Atypically polymeric/modified MDI, NCO ~15–16%40 – 5550
amine-terminated polyether resin (ATPE, polyoxypropylene diamine/triamine, MW 2000–500030 – 4538
aromatic diamine chain extender (DETDA /sets hard-segment content and hardness5 – 159
pigment, UV stabiliser, adhesion promotegrade-dependent additives0 – 83

Polyurea FR — frequently asked

What is Polyurea FR used for?

Polyurea FR is typically used for protective spray coatings, truck bed liners, waterproofing membranes and blast-mitigation linings. In short: fastest-curing protective lining; tougher than sprayed polyurethane; cures in seconds, walk-on quickly.

What is the tensile strength of Polyurea FR?

Polyurea FR has a typical tensile strength of 15 MPa (2.18 ksi) — weaker than 81% of polyurethane grades. Strength varies by condition: see the 8 listed tempers.

Is Polyurea FR easy to machine?

Not especially — machinability is rated poor (28/100, worse than 81% of polyurethane grades). Cured film is trimmed with sharp knives, hot knives or water-jet; conventional machining smears and drags, and thermosets cannot be re-melted.

Can Polyurea FR be welded?

Not readily — weldability is rated not recommended (5/100). Not weldable — repairs are made by abrading, solvent/tie-coat priming and re-spraying fresh polyurea within the recoat window.

What surface finishes work on Polyurea FR?

Surface prep (SSPC-SP10 blast on steel, CSP-3 on concrete) plus epoxy primer governs adhesion; aromatic films need an aliphatic polyurea or PU topcoat for colour retention.

Can Polyurea FR be formed, bent or molded?

Applied by heated (60–75 °C) plural-component 1:1 impingement spray at 14–24 MPa, gel 3–15 s and tack-free under a minute; also cast or RIM-moulded for parts.

What is the maximum service temperature of Polyurea FR?

Polyurea FR is rated for continuous use to about 110°C (230 °F), and briefly to 180°C. Strength falls off well before that limit — check the elevated-temperature data for load-bearing parts.

Sources

  1. ASTM D412 — Tension Properties of Vulcanized Rubber and Thermoplastic Elastomers — ASTM International (2021)
  2. ASTM D624 — Tear Strength of Conventional Vulcanized Rubber and TPE — ASTM International (2020)
  3. ASTM D2240 — Rubber Property, Durometer Hardness — ASTM International (2021)
  4. NSF/ANSI 61 — Drinking Water System Components — NSF International (2023)
  5. Polyurea Development Association (PDA) technical bulletins and applicator guidance — PDA (2022)
  6. Aromatic and aliphatic spray polyurea system datasheets (isocyanate prepolymer / ATPE resin suppliers) — Huntsman, Covestro, VersaFlex, SPI (2023)

Property data is compiled from published supplier and standards handbooks and normalised for comparison. Nothing on this page is a certification — request mill certs, CoC or material test reports with your order.