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CEM-3 HF (Halogen-free)

Grade

Pick the phosphorus/ATH flame-retarded halogen-free version when EU export or customer specifications cap bromine and chlorine at 900 ppm each.

Premium cost $$$

Values for the HF condition

Other CEM-3 grades and fills

CEM-3 is listed in 3 conditions; see the grade overview at CEM-3.

Compare all 3 grades and fillsHide
Grade · open for datasheetBest forYield MPaTensile MPaElong. %Hardness
HFThis page
Halogen-free
Pick the phosphorus/ATH flame-retarded halogen-free version when EU export or customer specifications cap bromine and chlorine at 900 ppm each.—1551.4106 HRM
High-CTI
Pick for AC mains boards and appliance control boards where CTI ≥ 600 V allows reduced creepage distance under IEC 60664 material group I; glass transition stays at 130 °C.—1551.5104 HRM
High-Tg
Choose the Tg ≈150 °C epoxy system for lead-free reflow at 260 °C or higher operating temperature, where z-axis expansion must be kept under control.—1651.4107 HRM

What is CEM-3 HF?

CEM-3 HF is CEM-3 in the HF grade — pick the phosphorus/ATH flame-retarded halogen-free version when EU export or customer specifications cap bromine and chlorine at 900 ppm each. CEM-3 HF has a tensile strength of 155 MPa (22.5 ksi), weaker than 56% of composite grades. Elongation at break is 1.4% and the elastic modulus is 15.5 GPa (2.25 Msi). CEM-3 HF has a density of 1.9 g/cm³ (0.0686 lb/in³), heavier than 72% of composite grades. Its glass-transition temperature is 135°C (275 °F).

Limitations

  • Hard to polish — 25/100, worse than 76% of composite grades

CEM-3 HF properties

Typical room-temperature values for CEM-3 HF; 21 are specific to this condition. Other listed values are CEM-3 reference data and may not represent this condition. Bars are the position among composite grades.

Physical4

CEM-3 HF has a density of 1.9 g/cm³ (0.0686 lb/in³), heavier than 72% of composite grades. Its glass-transition temperature is 135°C (275 °F).

Density1.9 g/cm³0.07 lb/in³
Glass Transition (Tg)135°C275 °F
Water Absorption (24 h)0.25%
Water Absorption (Saturation)0.45%

Mechanical11

CEM-3 HF has a tensile strength of 155 MPa (22.5 ksi), weaker than 56% of composite grades. Elongation at break is 1.4% and the elastic modulus is 15.5 GPa (2.25 Msi).

Elastic (Young's) Modulus15.5 GPa2.2 Msi
Shear Modulus5.5 GPa0.8 Msi
Poisson's Ratio0.19
Tensile Strength (Ultimate)155 MPa22.5 ksi
Elongation at Break1.4%
Compressive Strength320 MPa46.4 ksi
Flexural Strength290 MPa42.1 ksi
Flexural Modulus16 GPa2.3 Msi
Shear Strength88 MPa12.8 ksi
Izod Impact, Notched280 J/m5.2 ft·lbf/in
Hardness, Rockwell M106 HRM

Thermal8

CEM-3 HF is rated for continuous service to 130°C (266 °F). It conducts heat at 0.42 W/m·K (0.243 BTU/hr·ft·°F), better than 56% of composite grades. Thermal expansion is 16 µm/m·K (8.89 µin/in·°F).

Thermal Conductivity0.42 W/m·K0.24 BTU/hr·ft·°F
Specific Heat Capacity1,100 J/kg·K0.26 BTU/lb·°F
Thermal Expansion (CTE, 20–100 °C)16 µm/m·K8.9 µin/in·°F
Max Service Temperature (continuous)130°C266 °F
Min Service Temperature-55°C-67 °F
Flammability (UL 94)V-0 IEC 61249-2-21
Limiting Oxygen Index34%
Max Service Temperature (short-term)260°C500 °F

Electrical7

CEM-3 HF is an electrical insulator with a dielectric strength of 32 kV/mm (812.8 V/mil) and a resistivity of 1×10¹² Ω·m.

Electrical Resistivity1×10¹² Ω·m3.94×10¹⁹ µΩ·in
Dielectric Strength32 kV/mm813 V/mil
Dielectric Constant (1 MHz)4.7
Dissipation Factor (1 MHz)0.022
Volume Resistivity1×10¹⁴ Ω·cm
Surface Resistivity1×10¹³ Ω
Comparative Tracking Index (CTI)200 V

Chemical & Environmental3

Corrosion resistance is very good (84/100), better than 59% of composite grades. UV resistance is fair.

Corrosion ResistanceVery good84/100
UV / Weathering ResistanceFair40/100
Chemical Resistance Summary—

Sustainability4

Producing a kilogram of CEM-3 HF takes about 110 MJ of energy and emits 6.5 kg of CO₂ — less than 60% of composite grades. Typical recycled content is 0%.

Embodied Energy (primary production)110 MJ/kg47,292 BTU/lb
Embodied Carbon (primary production)6.5 kg CO₂/kg
Embodied Water200 L/kg24 gal/lb
Typical Recycled Content0%

Manufacturability2

CEM-3 HF's machinability is good (58/100, better than 72% of composite grades).

MachinabilityGood58/100
PolishabilityPoor25/100

Values are nominal handbook figures for design screening. Confirm any required mill or lot documentation when quoting.

Working with CEM-3 HF

Is CEM-3 easy to machine?

Can be punched after preheating to 40–60 °C and drilled at high speed with lower drill wear than FR-4. Use carbide tooling with vacuum extraction to control glass dust and prevent delamination.

Can CEM-3 be welded?

Thermoset laminate — not weldable; join with epoxy adhesive or mechanical fasteners.

Can CEM-3 be formed, bent or molded?

Pressed from prepreg at 170–180 °C under 2–4 MPa. The cured board cannot be re-formed; only flat cutting operations apply.

What surface finishes work on CEM-3?

Standard PCB route: electroless copper and plating, screen-printed green solder mask, then HASL, OSP or ENIG. Bake boards at 105–120 °C before soldering to drive off moisture and prevent blistering.

CEM-3 chemical composition (wt %)

Limits by weight percent from the governing specification, written the way the spec states them — a single maximum for impurities, a range for alloying elements, and the base element as balance. Nominal is the typical mid-range value.

ElementSpec limit (wt %)Nominal
epoxy resin (brominated/FR)Flame-retardant epoxy matrix with curing agent28 – 4034
non-woven E-glass mat (core)core glass mat30 – 4538
woven E-glass cloth (surface plies)top and bottom surface glass cloth12 – 2518
filler (ATH / silica / TiO2)Flame-retardant filler; white boards contain TiO22 – 158
copper foil (clad grades only)18-70 um electrodeposited copper foil, clad laminates only0 – 120

CEM-3 HF — frequently asked

What is CEM-3 HF used for?

CEM-3 HF is typically used for double-sided PCB substrates, cost-sensitive electronic assemblies and general insulating boards. In short: lower-cost FR-4 substitute; easier drilling than FR-4; glass-mat core composite.

What is the tensile strength of CEM-3 HF?

CEM-3 HF has a typical tensile strength of 155 MPa (22.5 ksi) — weaker than 56% of composite grades. Strength varies by condition: see the 3 listed tempers.

Is CEM-3 HF easy to machine?

Reasonably — machinability is rated good (58/100, better than 72% of composite grades). Can be punched after preheating to 40–60 °C and drilled at high speed with lower drill wear than FR-4. Use carbide tooling with vacuum extraction to control glass dust and prevent delamination.

Can CEM-3 HF be welded?

Thermoset laminate — not weldable; join with epoxy adhesive or mechanical fasteners.

What surface finishes work on CEM-3 HF?

Standard PCB route: electroless copper and plating, screen-printed green solder mask, then HASL, OSP or ENIG. Bake boards at 105–120 °C before soldering to drive off moisture and prevent blistering.

Can CEM-3 HF be formed, bent or molded?

Pressed from prepreg at 170–180 °C under 2–4 MPa. The cured board cannot be re-formed; only flat cutting operations apply.

What is the maximum service temperature of CEM-3 HF?

CEM-3 HF is rated for continuous use to about 130°C (266 °F), and briefly to 260°C. Strength falls off well before that limit — check the elevated-temperature data for load-bearing parts.

Sources

  1. IPC-4101 Specification for Base Materials for Rigid and Multilayer Printed Boards — IPC (2021)
  2. NEMA LI 1 Industrial Laminated Thermosetting Products — NEMA (1998)
  3. IEC 61249-2-21 (halogen-free base material requirements) — IEC (2003)
  4. Printed Circuits Handbook — base material properties — McGraw-Hill (2016)

Property data is compiled from published supplier and standards handbooks and normalised for comparison. Nothing on this page is a certification — request mill certs, CoC or material test reports with your order.