FabDigit

Silicon Nitride

also Sintered Silicon Nitride

Silicon Nitride (Si₃N₄) is a covalent nitride ceramic supplied to ASTM F2094 and GB/T 26315 in sintered, HIPed, hot-pressed (HPSN), reaction-bonded (RBSN/SRBSN), C935 and high-thermal-conductivity (HTC) grades.

High cost $$$$

Reference datasheet — Silicon Nitride is not in the instant-quote catalog. Upload your part and an engineer will quote it in this grade or suggest the closest stocked equivalent.

Values for the Sintered condition

Silicon Nitride tempers and conditions

Silicon Nitride is supplied in 6 conditions, soft to hard. Sintered is the default FabDigit quotes; the values on this page are for it.

Compare all 6 conditionsHide
Condition · open for datasheetBest forYield MPaTensile MPaElong. %HardnessConductivity
Reaction-bonded silicon nitride
Low-cost, near-zero-shrinkage porous grade for large refractory shapes, thermocouple sheaths, riser tubes and molten-aluminium hardware where strength is secondary.160900 HV12 W/m·K
Sintered reaction-bonded silicon nitride
Route that starts from cheap Si powder and then densifies; gives near-SSN properties with less shrinkage and lower raw-material cost for larger parts.40001,450 HV40 W/m·K
SinteredDefault
pressureless / gas-pressure sintered Si3N4 (SSN)
Standard dense grade for general structural, wear and high-temperature parts; best cost/performance for complex near-net shapes.4501,500 HV25 W/m·K
Hot isostatic pressed
Pick when defect-free, fully dense material is required — bearing balls/rollers, high-cycle-fatigue and highly stressed parts.5501,600 HV30 W/m·K
Uniaxially hot-pressed Si3N4
Choose for the highest strength in simple plate/blank geometries (cutting inserts, tooling); shapes limited and properties slightly anisotropic.55001,650 HV30 W/m·K
High-thermal-conductivity Si3N4 substrate grade
Y2O3-based, low-oxygen, coarse-β-grain grade for AMB power-module substrates: 70–100 W/m·K with substrate-grade strength and toughness.1,450 HV90 W/m·K

Supply forms, finishes and certifications

Ways Silicon Nitride is supplied — form, process route, surface or paperwork — without a datasheet of their own. The property values above apply.

OptionWhat it isType
C935
Dense Si₃N₄Certification

What is Silicon Nitride?

Silicon Nitride (Si₃N₄) is a covalent nitride ceramic supplied to ASTM F2094 and GB/T 26315 in sintered, HIPed, hot-pressed (HPSN), reaction-bonded (RBSN/SRBSN), C935 and high-thermal-conductivity (HTC) grades. It combines 450 MPa tensile strength, a 310 GPa modulus and good thermal-shock and rolling-contact fatigue behaviour, which makes it the standard choice for hybrid bearing balls, turbocharger rotors and glow plugs. Thermal conductivity is only 25 W/m·K, service is capped at 1200 °C, and fired parts require diamond grinding (machinability score 5), so unit cost is high. Silicon carbide is the alternative when heat spreading or hardness dominates. Silicon Nitride has a density of 3.22 g/cm³ (0.116 lb/in³), lighter than 71% of ceramic grades. It melts at 1,900°C (3,452 °F). Silicon Nitride has a tensile strength of 450 MPa (65.3 ksi), stronger than 76% of ceramic grades. Elongation at break is 0% and the elastic modulus is 310 GPa (45 Msi).

What is Silicon Nitride used for?

  • Hybrid bearing balls and rollers
  • Hot rolling bearings
  • Turbocharger rotors
  • Diesel glow plugs
  • Cutting tool inserts for cast iron
  • Welding locator pins and molten aluminum riser tubes
  • AMB power module substrates

Advantages

  • Polishes to a fine finish — 92/100, better than 89% of ceramic grades
  • Good corrosion resistance — 92/100, better than 88% of ceramic grades

Silicon Nitride properties

Typical room-temperature values for Silicon Nitride-Sintered; bars are the position among ceramic grades.

Physical4

Silicon Nitride has a density of 3.22 g/cm³ (0.116 lb/in³), lighter than 71% of ceramic grades. It melts at 1,900°C (3,452 °F).

Density3.22 g/cm³0.12 lb/in³
Melting Point (Solidus)1,900°C3,452 °F
Light Transmission0%
Porosity0.5%

Mechanical12

Silicon Nitride has a tensile strength of 450 MPa (65.3 ksi), stronger than 76% of ceramic grades. Elongation at break is 0% and the elastic modulus is 310 GPa (45 Msi).

Elastic (Young's) Modulus310 GPa45 Msi
Shear Modulus122 GPa17.7 Msi
Bulk Modulus222 GPa32.2 Msi
Poisson's Ratio0.27
Tensile Strength (Ultimate)450 MPa65.3 ksi
Elongation at Break0%
Compressive Strength3,000 MPa435 ksi
Flexural Strength800 MPa116 ksi
Fracture Toughness (K_IC)6.5 MPa·√m5.9 ksi·√in
Hardness, Vickers1,500 HV
Hardness, Knoop1,500 HK
Hardness, Mohs9

Thermal5

Silicon Nitride is rated for continuous service to 1,200°C (2,192 °F). It conducts heat at 25 W/m·K (14.4 BTU/hr·ft·°F), better than 55% of ceramic grades. Thermal expansion is 3.2 µm/m·K (1.78 µin/in·°F).

Thermal Conductivity25 W/m·K14.4 BTU/hr·ft·°F
Specific Heat Capacity700 J/kg·K0.17 BTU/lb·°F
Thermal Expansion (CTE, 20–100 °C)3.2 µm/m·K1.8 µin/in·°F
Max Service Temperature (continuous)1,200°C2,192 °F
Min Service Temperature-269°C-452 °F

Electrical5

Silicon Nitride is an electrical insulator with a dielectric strength of 15 kV/mm (381 V/mil) and a resistivity of 1×10¹² Ω·m.

Electrical Resistivity1×10¹² Ω·m3.94×10¹⁹ µΩ·in
Dielectric Strength15 kV/mm381 V/mil
Dielectric Constant (1 MHz)8
Dissipation Factor (1 MHz)0.001
Volume Resistivity1×10¹⁴ Ω·cm

Chemical & Environmental2

Corrosion resistance is excellent (92/100), better than 88% of ceramic grades.

Corrosion ResistanceExcellent92/100
Chemical Resistance SummaryInert to most acids (including hot H2SO4, HCl, HNO3), organics, molten Al and Zn, and to steam; attacked by HF and hot concentrated NaOH/KOH; oxidizes slowly in air above ~1000 °C forming a protective SiO2 layer; grain-boundary glass phase is the usual point of chemical attack.

Sustainability4

Producing a kilogram of Silicon Nitride takes about 170 MJ of energy and emits 12 kg of CO₂ — more than 59% of ceramic grades. Typical recycled content is 0%.

Embodied Energy (primary production)170 MJ/kg73,087 BTU/lb
Embodied Carbon (primary production)12 kg CO₂/kg
Embodied Water220 L/kg26.4 gal/lb
Typical Recycled Content0%

Manufacturability3

Silicon Nitride's machinability is not recommended (5/100, worse than 59% of ceramic grades).

MachinabilityNot recommended5/100
PolishabilityExcellent92/100
Sintering / Firing Temperature1,750°C3,182 °F

Common Calculations4

Specific Strength (UTS / density)calculated140 kN·m/kg
Specific Stiffness (E / density)calculated96.3 MN·m/kg
Thermal Diffusivitycalculated11.1 mm²/s
Thermal Shock Resistance Indexcalculated11

Values are nominal handbook figures for design screening. Certified mill or lot data ships with every FabDigit order on request.

Strength versus weight in the ceramic family

Yield strength against density for every ceramic grade FabDigit runs. Silicon Nitride is highlighted; hover a dot for its name, or open the interactive family chart.

501002005001,000234567Density (g/cm³)Yield strength (MPa) — log scaleSilicon Nitride

Working with Silicon Nitride

Is Silicon Nitride easy to machine?

Green/bisque machining with carbide tooling is the economical route; after sintering only diamond grinding, lapping and laser/ultrasonic machining work (electrically insulating, so no EDM).

Can Silicon Nitride be welded?

Not weldable — join by active-metal brazing (Ti-containing Ag-Cu), metallization + soldering, glass sealing or mechanical shrink-fit; AMB copper bonding is standard for substrates.

Can Silicon Nitride be formed, bent or molded?

Formed as a powder compact: uniaxial/isostatic pressing, injection moulding, slip/tape casting or extrusion, then sintered at 1650–1850 °C under N2 overpressure with ~15–18 % linear shrinkage (RBSN routes are near net shape).

Silicon Nitride chemical composition (wt %)

Limits by weight percent from the governing specification, written the way the spec states them — a single maximum for impurities, a range for alloying elements, and the base element as balance. Nominal is the typical mid-range value.

ElementSpec limit (wt %)Nominal
Y2O3primary sintering aid (rare-earth oxide; may be substituted by Yb2O3/La2O3)0 – 84
Al2O3co-additive; forms grain-boundary glass, lowers thermal conductivity0 – 52
MgOalternative aid, mainly in hot-pressed grades0 – 30
SiO2surface oxide on powder, part of the glass phase0.5 – 2.51.2
Feimpurity0 – 0.20.05
Si3N4predominantly β-Si3N4 after sintering≥ 88 (balance)

What surface finishes work on Silicon Nitride?

Diamond lapping and polishing give Ra < 0.01 µm on bearing surfaces; CVD/PVD coatings, metallization or lapped-and-honed seal faces are common — no anodizing/plating without prior metallization.

Equivalent designations

Standards and trade names that resolve to Silicon Nitride in FabDigit's catalog. Equivalence is nominal — check the exact specification when certification matters.

Trade names
Sintered Silicon Nitride
Similar grades
F2094GB/T 26315

How much does Silicon Nitride cost?

Silicon Nitride is a high-cost ceramic ($$$$), pricier than about 98% of the materials FabDigit quotes. Part price depends far more on geometry, tolerance and quantity than on the raw stock — upload a CAD file for a live quote.

Silicon Nitride — frequently asked

What is Silicon Nitride used for?

Silicon Nitride is typically used for hybrid bearing balls and rollers, hot rolling bearings, turbocharger rotors, diesel glow plugs, cutting tool inserts for cast iron and welding locator pins and molten aluminum riser tubes. In short: high-toughness silicon nitride.

What is the tensile strength of Silicon Nitride?

Silicon Nitride has a typical tensile strength of 450 MPa (65.3 ksi) — stronger than 76% of ceramic grades. Strength varies by condition: see the 6 listed tempers.

Is Silicon Nitride easy to machine?

Not especially — machinability is rated not recommended (5/100, worse than 59% of ceramic grades). Green/bisque machining with carbide tooling is the economical route; after sintering only diamond grinding, lapping and laser/ultrasonic machining work (electrically insulating, so no EDM).

Can Silicon Nitride be welded?

Not weldable — join by active-metal brazing (Ti-containing Ag-Cu), metallization + soldering, glass sealing or mechanical shrink-fit; AMB copper bonding is standard for substrates.

What surface finishes work on Silicon Nitride?

Diamond lapping and polishing give Ra < 0.01 µm on bearing surfaces; CVD/PVD coatings, metallization or lapped-and-honed seal faces are common — no anodizing/plating without prior metallization.

Can Silicon Nitride be formed, bent or molded?

Formed as a powder compact: uniaxial/isostatic pressing, injection moulding, slip/tape casting or extrusion, then sintered at 1650–1850 °C under N2 overpressure with ~15–18 % linear shrinkage (RBSN routes are near net shape).

What is the maximum service temperature of Silicon Nitride?

Silicon Nitride is rated for continuous use to about 1,200°C (2,192 °F). Strength falls off well before that limit — check the elevated-temperature data for load-bearing parts.

How much does Silicon Nitride cost?

Silicon Nitride is a high-cost ceramic ($$$$), pricier than about 98% of the materials FabDigit quotes. Part price depends far more on geometry, tolerance and quantity than on the raw stock — upload a CAD file for a live quote.

Sources

  1. ASM Engineered Materials Handbook, Vol. 4: Ceramics and Glasses — ASM International (1991)
  2. ISO 26602 — Fine ceramics: Silicon nitride materials for rolling bearing balls and rollers — ISO (2017)
  3. ASTM C1161 / C1421 — Flexural strength and fracture toughness of advanced ceramics — ASTM (2018)
  4. Silicon Nitride (Si3N4) material property sheets — CoorsTek (2023)
  5. Fine Ceramics — Silicon Nitride SN series — Kyocera (2023)
  6. SL200B / high-thermal-conductivity Si3N4 substrate data — CeramTec / Rogers curamik (2022)

Property data is compiled from published supplier and standards handbooks and normalised for comparison; hardness values on non-Brinell scales are converted approximately for charting only. Manufacturability limits are FabDigit quote-engine defaults and may be relaxed by engineering review. Nothing on this page is a certification — request mill certs, CoC or material test reports with your order.