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PEEK · grade · default condition

PEEK Unfilled

Properties of the Unfilled condition, compared with the other PEEK grades.

Pick for maximum toughness, elongation and electrical insulation, or when machining thin/complex parts from rod and plate.

What is PEEK Unfilled?

PEEK Unfilled is PEEK in the Unfilled grade — pick for maximum toughness, elongation and electrical insulation, or when machining thin/complex parts from rod and plate. PEEK Unfilled has a yield strength of 100 MPa (14.5 ksi) and a tensile strength of 100 MPa (14.5 ksi) — stronger than 95% of polymer grades. Elongation at break is 35% and the elastic modulus is 3.7 GPa (0.537 Msi). PEEK Unfilled has a density of 1.3 g/cm³ (0.047 lb/in³), heavier than 69% of polymer grades. Its glass-transition temperature is 143°C (289 °F).

Advantages

  • High strength — 100 MPa (14.5 ksi), better than 95% of polymer grades
  • High service temperature — 250°C (482 °F), better than 94% of polymer grades
  • Stiff — 3.7 GPa (0.537 Msi), better than 83% of polymer grades
  • Good corrosion resistance — 90/100, better than 81% of polymer grades
  • Tough — resists crack growth — 3.5 MPa·√m (3.19 ksi·√in), better than 80% of polymer grades

Limitations

  • High embodied carbon — 15 kg CO₂/kg, worse than 97% of polymer grades

PEEK Unfilled properties

Typical room-temperature values for PEEK Unfilled — 12 properties are specific to this condition; the rest are grade-level values shared by every PEEK grade. Each bar shows where the value sits among the polymer grades in FabDigit's library — further right is higher.

Physical5

PEEK Unfilled has a density of 1.3 g/cm³ (0.047 lb/in³), heavier than 69% of polymer grades. Its glass-transition temperature is 143°C (289 °F).

Density1.3 g/cm³0.05 lb/in³
Melting Temperature (Tm)343°C649 °F
Glass Transition (Tg)143°C289 °F
Water Absorption (24 h)0.12%
Water Absorption (Saturation)0.45%

Mechanical17

PEEK Unfilled has a yield strength of 100 MPa (14.5 ksi) and a tensile strength of 100 MPa (14.5 ksi) — stronger than 95% of polymer grades. Elongation at break is 35% and the elastic modulus is 3.7 GPa (0.537 Msi).

Elastic (Young's) Modulus3.7 GPa0.54 Msi
Shear Modulus1.3 GPa0.19 Msi
Bulk Modulus6 GPa0.87 Msi
Poisson's Ratio0.4
Tensile Strength (Ultimate)100 MPa14.5 ksi
Yield Strength (0.2% offset)100 MPa14.5 ksi
Elongation at Break35%
Compressive Strength130 MPa18.9 ksi
Compressive Modulus3.6 GPa0.52 Msi
Flexural Strength165 MPa23.9 ksi
Flexural Modulus4 GPa0.58 Msi
Shear Strength55 MPa8 ksi
Fracture Toughness (K_IC)3.5 MPa·√m3.2 ksi·√in
Izod Impact, Notched80 J/m1.5 ft·lbf/in
Hardness, Shore D86 Shore D
Hardness, Rockwell M99 HRM
Hardness, Rockwell R126 HRR

Thermal11

PEEK Unfilled is rated for continuous service to 250°C (482 °F). It conducts heat at 0.25 W/m·K (0.144 BTU/hr·ft·°F), better than 71% of polymer grades. Thermal expansion is 47 µm/m·K (26.1 µin/in·°F).

Thermal Conductivity0.25 W/m·K0.14 BTU/hr·ft·°F
Specific Heat Capacity1,340 J/kg·K0.32 BTU/lb·°F
Thermal Expansion (CTE, 20–100 °C)47 µm/m·K26.1 µin/in·°F
Max Service Temperature (continuous)250°C482 °F
Min Service Temperature-60°C-76 °F
Heat Deflection Temp. @ 0.45 MPa315°C599 °F
Heat Deflection Temp. @ 1.8 MPa152°C306 °F
Vicat Softening Point (B50)315°C599 °F
Flammability (UL 94)V-0 at 1.45 mm (also 5VA in thicker sections for some grades), inherently flame retardant with very low smoke
Limiting Oxygen Index35%
Max Service Temperature (short-term)300°C572 °F

Electrical7

PEEK Unfilled is an electrical insulator with a dielectric strength of 21 kV/mm (533.4 V/mil) and a resistivity of 1×10¹⁴ Ω·m.

Electrical Resistivity1×10¹⁴ Ω·m3.94×10²¹ µΩ·in
Dielectric Strength21 kV/mm533 V/mil
Dielectric Constant (1 MHz)3.2
Dissipation Factor (1 MHz)0.003
Volume Resistivity1×10¹⁶ Ω·cm
Surface Resistivity1×10¹⁵ Ω
Comparative Tracking Index (CTI)150 V

Chemical & Environmental3

Corrosion resistance is excellent (90/100), better than 81% of polymer grades. UV resistance is fair.

Corrosion ResistanceExcellent90/100
UV / Weathering ResistanceFair45/100
Chemical Resistance SummaryOutstanding resistance to water/steam (repeated autoclaving), hydraulic fluids, fuels, oils, most acids, bases and organic solvents; attacked by concentrated sulfuric and nitric acid, some halogenated/sulfonated acids, and swells in molten alkali metals; stress-crack resistant in most media

Sustainability4

Producing a kilogram of PEEK Unfilled takes about 290 MJ of energy and emits 15 kg of CO₂ — more than 95% of polymer grades. Typical recycled content is 0%.

Embodied Energy (primary production)290 MJ/kg124,678 BTU/lb
Embodied Carbon (primary production)15 kg CO₂/kg
Embodied Water450 L/kg53.9 gal/lb
Typical Recycled Content0%

Manufacturability8

PEEK Unfilled's machinability is very good (70/100, better than 73% of polymer grades); weldability fair (45/100); formability poor (30/100).

MachinabilityVery good70/100
WeldabilityFair45/100
Formability (cold)Poor30/100
PolishabilityVery good70/100
Mold Shrinkage1.2%
Melt Flow Rate3 g/10 min
Processing Melt Temperature (typ.)380°C716 °F
Mold Temperature (typ.)180°C356 °F

Common Calculations5

Specific Strength (UTS / density)calculated77 kN·m/kg
Specific Stiffness (E / density)calculated2.8 MN·m/kg
Modulus of Resiliencecalculated1,351 kJ/m³
Thermal Diffusivitycalculated0.1 mm²/s
Thermal Shock Resistance Indexcalculated0

Values are nominal handbook figures for design screening. Certified mill or lot data ships with every FabDigit order on request.

Other PEEK grades and fills

PEEK is also supplied in 12 other conditions. The full side-by-side table is on the PEEK overview.

Working with PEEK Unfilled

Is PEEK easy to machine?

Machines cleanly with sharp carbide (polished flutes, positive rake) and air/flood cooling; glass- and carbon-filled grades are abrasive and want diamond-coated tooling, and thick machined parts should be annealed before finish cuts to avoid stress cracking.

Can PEEK be welded?

Joins by ultrasonic, laser, hot-plate, spin and infrared welding at 380–400 °C interface temperature; no solvent bonding — adhesive joints need plasma or abrasive surface activation.

Can PEEK be formed, bent or molded?

Inject at 360–400 °C melt with 170–200 °C mold for full crystallinity; resin must be dried (150 °C, 3 h), runners/gates generous, and slow crystallising thin sections may need post-mold annealing.

What surface finishes work on PEEK?

Can be machined-to-finish, bead-blasted, laser-marked or plasma treated for printing/metallising; not paintable without primer and not anodizable — parts are usually left natural tan or supplied in black.

PEEK chemical composition (wt %)

Limits by weight percent from the governing specification, written the way the spec states them — a single maximum for impurities, a range for alloying elements, and the base element as balance. Nominal is the typical mid-range value.

ElementSpec limit (wt %)Nominal
glass fiberGF variants only (chopped E-glass, sized for PAEK)10 – 4030
carbon fiberCF variants only (PAN-based chopped fiber)10 – 4030
PTFEbearing / lubricated variants5 – 1510
graphitebearing variants5 – 1010
carbon blackblack / ESD variants1 – 153
poly(oxy-1,4-phenylene-oxy-1,4-phenyleneUnfilled grade; polymerised from 4,4'-difluorobenzophenone + hydroquinone in diphenyl sulfonebalance

PEEK Unfilled — frequently asked

What is PEEK Unfilled used for?

PEEK Unfilled is typically used for spinal fusion implants, aerospace seals and back-up rings, downhole oil and gas seals, semiconductor wafer handling fixtures, bearings, bushings and wear pads and compressor valve plates. In short: ultra-performance plastic.

What is the yield strength of PEEK Unfilled?

PEEK Unfilled has a typical yield strength of 100 MPa (14.5 ksi) and a tensile strength of 100 MPa (14.5 ksi) — stronger than 95% of polymer grades. Strength varies by condition: see the 13 listed tempers.

Is PEEK Unfilled easy to machine?

Yes — machinability is rated very good (70/100, better than 73% of polymer grades). Machines cleanly with sharp carbide (polished flutes, positive rake) and air/flood cooling; glass- and carbon-filled grades are abrasive and want diamond-coated tooling, and thick machined parts should be annealed before finish cuts to avoid stress cracking.

Can PEEK Unfilled be welded?

With care — weldability is rated fair (45/100). Joins by ultrasonic, laser, hot-plate, spin and infrared welding at 380–400 °C interface temperature; no solvent bonding — adhesive joints need plasma or abrasive surface activation.

What surface finishes work on PEEK Unfilled?

Can be machined-to-finish, bead-blasted, laser-marked or plasma treated for printing/metallising; not paintable without primer and not anodizable — parts are usually left natural tan or supplied in black.

Can PEEK Unfilled be formed, bent or molded?

Inject at 360–400 °C melt with 170–200 °C mold for full crystallinity; resin must be dried (150 °C, 3 h), runners/gates generous, and slow crystallising thin sections may need post-mold annealing.

What is the maximum service temperature of PEEK Unfilled?

PEEK Unfilled is rated for continuous use to about 250°C (482 °F), and briefly to 300°C. Strength falls off well before that limit — check the elevated-temperature data for load-bearing parts.

What is the difference between PEEK Virgin and PEEK-CF30?

Virgin is the default condition — specify when full lot traceability and no reprocessed content are required (semiconductor, aerospace, medical). CF30: pick for highest strength/stiffness-to-weight, low CTE, better heat dissipation and static-dissipative behaviour. Yield strength is 100 MPa in Virgin versus 225 MPa in CF30.

Can FabDigit make parts in PEEK Unfilled?

Yes — PEEK Unfilled is available for CNC machining, sheet metal, injection molding and 3D printing with instant online pricing. Upload a STEP file to get a price and a DFM check.

Sources

  1. VICTREX PEEK 450G / 450GL30 / 450CA30 / 450FC30 product datasheetsVictrex plc (2023)
  2. KetaSpire PEEK design & processing guideSolvay Specialty Polymers (2022)
  3. TECAPEEK stock shape property tablesEnsinger GmbH (2023)
  4. CAMPUS plastics multipoint data for PEEK gradesCWFG / CAMPUS (2024)
  5. ASM Engineered Materials Handbook: Engineering PlasticsASM International (1988)
  6. ISO 527 / ISO 178 / ISO 75 / ISO 180 test methods; ASTM D638, D790, D648ISO / ASTM (2019)

Property data is compiled from published supplier and standards handbooks and normalised for comparison. Nothing on this page is a certification — request mill certs, CoC or material test reports with your order.